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Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not…

Determining the level of chemical complexity within dense starless and gravitationally bound prestellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We…

Astrophysics of Galaxies · Physics 2021-04-28 Samantha Scibelli , Yancy Shirley , Anton Vasyunin , Ralf Launhardt

Thanks to the advent of sensitive and broad bandwidth instrumentation, complex organic molecules (COMs) have been found in a wide variety of interstellar environments, not only in our Galaxy but also in external galaxies up to a redshift of…

Astrophysics of Galaxies · Physics 2025-03-24 Izaskun Jimenez-Serra , Claudio Codella , Arnaud Belloche

The solid-state C$_2$H$_2$ chemistry in interstellar H$_2$O-rich ice has been proposed to explain astronomically observed complex organic molecules (COMs), including ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH),…

Astrophysics of Galaxies · Physics 2024-05-14 K. -J. Chuang , C. Jäger , J. C. Santos , Th. Henning

Using the recently-commissioned Submillimeter Array (SMA), we have detected several complex organic molecules, including (CH3)2O, C2H5OH, C2H5CN, and tentatively CH2CDCN, toward the protostellar hot cores of IRAS 16293-2422 at…

Astrophysics · Physics 2014-10-13 H. -C. Huang , Y. -J. Kuan , S. B. Charnley , N. Hirano , S. Takakuwa , T. L. Bourke

Complex organic molecules (COMs) have been identified in different environments in star- forming regions. Laboratory studies show that COMs form in the solid state, on icy grains, typically following a non-energetic (atom-addition) or…

Astrophysics of Galaxies · Physics 2017-05-23 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared…

Earth and Planetary Astrophysics · Physics 2010-11-02 J. Crovisier , N. Biver , D. Bockelée-Morvan , J. Boissier , P. Colom , D. C. Lis

Molecular oxygen, O$_2$, was recently detected in comet 67P by the ROSINA instrument on board the Rosetta spacecraft with a surprisingly high abundance of 4 % relative to H$_2$O, making O$_2$ the fourth most abundant in comet 67P. Other…

Astrophysics of Galaxies · Physics 2018-09-12 Vianney Taquet , Kenji Furuya , Catherine Walsh , Ewine F. van Dishoeck

We report the first extragalactic detection of the complex organic molecules (COMs) dimethyl ether (CH$_3$OCH$_3$) and methyl formate (CH$_3$OCHO) with the Atacama Large Millimeter/submillimeter Array (ALMA). These COMs together with their…

We have complemented existing observations of HI absorption with new observations of HCO$^+$, C$_2$H, HCN, and HNC absorption from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in…

Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in…

The relation between ice composition in the nucleus of comet 67P/Churyumov-Gerasimenko on the one hand and relative abundances of volatiles in the coma on the other hand is important for the interpretation of density measurements in the…

Earth and Planetary Astrophysics · Physics 2023-05-26 Matthias Laeuter , Tobias Kramer , Martin Rubin , Kathrin Altwegg

Cometary dust particles are best preserved remnants of the matter present at the onset of the formation of the Solar System. Space missions, telescopic observations and laboratory analyses advanced the knowledge on the properties of…

Earth and Planetary Astrophysics · Physics 2023-05-08 Cecile Engrand , Jérémie Lasue , Diane H. Wooden , Mike E. Zolensky

Over 200 molecules have been detected in multiple extraterrestrial environments, including glycolaldehyde (C2(H2O)2, GLA), a two-carbon sugar precursor that has been detected in regions of the interstellar medium. Its recent in situ…

Earth and Planetary Astrophysics · Physics 2020-11-18 Nicolle E. B. Zellner , Vanessa P. McCaffrey , Jayden H. E. Butler

Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity is poorly constrained in the early evolution of hot cores. Using the Atacama Large…

Astrophysics of Galaxies · Physics 2019-11-27 T. Csengeri , A. Belloche , S. Bontemps , F. Wyrowski , K. M. Menten , L. Bouscasse

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

Astrophysics of Galaxies · Physics 2020-08-19 Mihwa Jin , Robin T. Garrod

We review recent studies of organic molecule formation in dense molecular clouds and in comets. We summarise the known organic inventories of molecular clouds and recent comets, particularly Hale-Bopp. The principal chemical formation…

Astrophysics · Physics 2009-11-06 S. B. Charnley , S. D. Rodgers , Y-J. Kuan , H-C. Huang

We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions…

Astrophysics of Galaxies · Physics 2020-09-09 A. Coletta , F. Fontani , V. M. Rivilla , C. Mininni , L. Colzi , Á. Sánchez-Monge , M. T. Beltrán

The outer Galaxy is an environment with metallicity lower than the Solar one. Because of this, the formation and survival of molecules in star-forming regions located in the inner and outer Galaxy is expected to be different. To gain…

Astrophysics of Galaxies · Physics 2022-04-27 F. Fontani , L. Colzi , L. Bizzocchi , V. M. Rivilla , D. Elia , M. T. Beltrán , P. Caselli , L. Magrini , A. Sánchez-Monge , L. Testi , D. Romano

Interstellar complex organic molecules (COMs) in solar-like young stellar objects (YSOs), particularly within protostellar disks, are of significant interest due to their potential connection to prebiotic chemistry in emerging planetary…