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We describe an algorithm for using a quantum computer to calculate mean values of observables and the partition function of a quantum system. Our algorithm includes two sub-algorithms. The first sub-algorithm is for calculating, with…

Quantum Physics · Physics 2010-11-10 Robert R. Tucci

It is often difficult to quantitatively determine if a new molecular simulation algorithm or software properly implements sampling of the desired thermodynamic ensemble. We present some simple statistical analysis procedures to allow…

Statistical Mechanics · Physics 2013-03-04 Michael R. Shirts

In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

In this work, we propose a theory of temperature estimation of quantum systems, which is applicable in the regime of non-negligible prior temperature uncertainty and limited measurement data. In this regime the problem of establishing a…

We formulate thermodynamics of economic systems in terms of an arbitrary probability distribution for a conserved economic quantity. As in statistical physics, thermodynamic macroeconomic variables emerge as the mean value of microeconomic…

Statistical Finance · Quantitative Finance 2011-05-26 H. Quevedo , M. N. Quevedo

Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e. the wavefunction, of an isolated system which is determined to calculate molecular properties and to…

Statistical Mechanics · Physics 2011-03-17 Barbara Fresch , Giorgio J. Moro

Traditional thermodynamics governs the behaviour of large systems that evolve between states of thermal equilibrium. For these large systems, the mean values of thermodynamic quantities (such as work, heat and entropy) provide a good…

Statistical Mechanics · Physics 2019-05-01 Andrew J. P. Garner

Quantum measurement is ultimately a physical process, resulting from an interaction between the measured system and a measuring apparatus. Considering the physical process of measurement within a thermodynamic context naturally raises the…

Quantum Physics · Physics 2021-12-09 M. Hamed Mohammady

A short introduction on quantum thermodynamics is given and three new topics are discussed: 1) Maximal work extraction from a finite quantum system. The thermodynamic prediction fails and a new, general result is derived, the ``ergotropy''.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. E. Allahverdyan , R. Balian , Th. M. Nieuwenhuizen

Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…

Quantum Physics · Physics 2024-02-28 Lucas Chibebe Céleri , Łukasz Rudnicki

A system responding to a stochastic driving signal can be interpreted as computing, by means of its dynamics, an implicit model of the environmental variables. The system's state retains information about past environmental fluctuations,…

Statistical Mechanics · Physics 2012-10-09 Susanne Still , David A. Sivak , Anthony J. Bell , Gavin E. Crooks

Thermodynamics could be seen as an expression of physics at a high epistemic level. As such, its potential as an inductive bias to help machine learning procedures attain accurate and credible predictions has been recently realized in many…

Machine Learning · Computer Science 2023-05-29 Elias Cueto , Francisco Chinesta

Consider a statistical model with an epistemic restriction such that, unlike in classical mechanics, the allowed distribution of positions is fundamentally restricted by the form of an underlying momentum field. Assume an agent (observer)…

Quantum Physics · Physics 2020-05-15 Agung Budiyono

For a quantum system undergoing a unitary process work is commonly defined based on the Two Projective Measurement (TPM) protocol which measures the energies of the system before and after the process. However, it is well known that…

Quantum Physics · Physics 2017-11-22 P. Solinas , H. J. D. Miller , J. Anders

The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of…

Quantum Physics · Physics 2022-01-05 Gianluca Francica

How should one define thermodynamic quantities (internal energy, work, heat, etc.) for quantum systems coupled to their environments strongly? We examine three (classically equivalent) definitions of a quantum system's internal energy under…

Thermodynamic length is a path function that generalizes the notion of length to the surface of thermodynamic states. Here, we show how to measure thermodynamic length in far-from-equilibrium single molecule experiments using the work…

Statistical Mechanics · Physics 2014-05-27 Edward H. Feng , Gavin E. Crooks

The mean square displacement $\langle\left(x(t)-x(0)\right)^2\rangle$ of the position $x$ of a free particle of mass $m$ at thermal equilibrium is evaluated quantum mechanically. An analytical expression is obtained which shows an initial…

Quantum Physics · Physics 2021-12-22 Roberto Marquardt

An analysis of the thermodynamic behavior of quantum systems can be performed from a geometrical perspective investigating the structure of the state space. We have developed such an analysis for nonextensive thermostatistical frameworks,…

Statistical Mechanics · Physics 2009-11-11 M. Portesi , A. Plastino , F. Pennini

Of indisputable relevance for non-equilibrium thermodynamics, fluctuations theorems have been generalized to the framework of quantum thermodynamics, with the notion of work playing a key role in such contexts. The typical approach consists…

Quantum Physics · Physics 2023-06-28 Thales Augusto Barbosa Pinto Silva , Renato Moreira Angelo