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Related papers: Imaging charge-migration in chiral molecules using…

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Technological advancements in generation of ultrafast and intense laser pulses have enabled the real-time observation and control of charge migration in molecules on their natural timescale, which ranges from few femtoseconds to several…

Optics · Physics 2025-02-25 Sucharita Giri

Chirality is ubiquitous in nature and of fundamental importance in science. The present work focuses on understanding the conditions required to modify the chirality during ultrafast electronic motion by bringing enantiomers…

Chemical Physics · Physics 2021-01-04 Sucharita Giri , Alexandra Maxi Dudzinski , Jean Christophe Tremblay , Gopal Dixit

Molecular chirality is a key design property for many technologies including bioresponsive imaging, circularly polarized light detection and emission, molecular motors and switches. Imaging and manipulating the primary steps of transient…

Metal-corroles are macrocycle organic molecules with numerous practical applications. In particular, copper corroles exhibit an interesting saddled geometry, which has attracted significant attention from theoreticians and experimentalists…

Chemical Physics · Physics 2022-10-03 Sucharita Giri , Jean Christophe Tremblay , Gopal Dixit

Recently developed circularly polarized X-ray light sources can probe ultrafast chiral electronic and nuclear dynamics through spatially localized resonant core transitions. We present simulations of time-resolved circular dichroism (TRCD)…

Chemical Physics · Physics 2017-02-08 Jérémy R. Rouxel , Markus Kowalewski , Shaul Mukamel

Electron transmission through chiral molecules induced by circularly polarized light can be very different for mirror-image structures, a peculiar fact given that the electronic energy spectra of the systems are identical. We propose that…

Chemical Physics · Physics 2009-11-13 Spiros S. Skourtis , David N. Beratan , Ron Naaman , Abraham Nitzan , David H. Waldeck

Diffraction imaging of non-equilibrium dynamics at atomic resolution is becoming possible with X-ray free-electron lasers. However, there are unresolved problems with applying this method to objects that are confined in only one dimension.…

Strongly Correlated Electrons · Physics 2018-02-19 Kenneth R. Beyerlein

Time-resolved ultrafast x-ray scattering is an emerging approach to probe the temporally evolving electronic charge distribution in real-space and in real-time. In this contribution, time-resolved ultrafast x-ray scattering from an…

Atomic Physics · Physics 2015-06-18 Gopal Dixit , Robin Santra

A general scenario for electronic charge migration in finite samples illuminated by an intense laser pulse is given. Microscopic calculations for neon clusters under strong short pulses as produced by X-ray free-electron laser sources…

Atomic and Molecular Clusters · Physics 2009-04-30 Christian Gnodtke , Ulf Saalmann , Jan M. Rost

Using a quantum electrodynamic framework, we calculate the off-resonant scattering of a broad-band X-ray pulse from a sample initially prepared in an arbitrary superposition of electronic states. The signal consists of single-particle…

Chemical Physics · Physics 2015-06-19 Kochise Bennett , Jason D. Biggs , Yu Zhang , Konstantin E. Dorfman , Shaul Mukamel

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

Major advances in X-ray sources including the development of circularly polarized and orbital angular momentum pulses make it possible to probe matter chirality at unprecedented energy regimes and with Angstr\"om and femtosecond…

Chemical Physics · Physics 2022-09-20 Jeremy R. Rouxel , Shaul Mukamel

Based on the similarity of paraxial diffraction and dispersion mathematical descriptions, the temporal imaging of optical pulses combines linear dispersive filters and quadratic phase modulations operating as time lenses. We consider…

The chiral source and its mechanism in the molecular system are of great significance in many fields. In this work, we proposed visualized methods to investigate physical mechanism of chiral molecule, where the electric and magnetic…

Chemical Physics · Physics 2019-05-29 Jingang Wang , Xiangtao Chen , Jizhe Song , Xijiao Mu , Mengtao Sun

We present a set-up for time-resolved X-ray diffraction based on a short pulse, laser-driven plasma X-ray source. The employed modular design provides high flexibility to adapt the set-up to the specific requirements (e.g. X-ray optics,…

Imaging the quantum motion of electrons not only in real-time, but also in real-space is essential to understand for example bond breaking and formation in molecules, and charge migration in peptides and biological systems. Time-resolved…

Atomic Physics · Physics 2012-07-20 Gopal Dixit , Oriol Vendrell , Robin Santra

Enantioselective interactions of chiral molecules include distinct absorptions to opposite-handed circularly polarized light, known as chiral absorption. Traditionally, chiral absorption has been primarily attributed to electric dipole and…

Optics · Physics 2024-06-03 Hanwei Wang , Yang Zhao

We present time-resolved X-ray diffraction measurements using advanced timing schemes that provide high temporal resolution while also maintaining a high flux in the X-ray probe beam. The method employs patterned probe pulse sequences that…

We propose an approach to probe coherent spin-state dynamics of molecules using circularly polarized hard x-ray pulses. For the dynamically aligned nitric oxide molecules in a coherent superposition spin-orbit coupled electronic state that…

Optics · Physics 2024-01-02 Xiaoyu Mi , Ming Zhang , Zheng Li

We develop photoelectron interferometry based on laser-assisted extreme ultraviolet ionization for flexible and robust control of photoelectron circular dichroism in randomly oriented chiral molecules. A comb of XUV photons ionizes a sample…

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