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Related papers: Dual-Cone Variational Calculation of the 2-Electro…

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We propose a refined scheme of deriving an effective low-energy Hamiltonian for materials with strong electronic Coulomb correlations beyond density functional theory (DFT). By tracing out the electronic states away from the target degrees…

Strongly Correlated Electrons · Physics 2017-08-09 Motoaki Hirayama , Takashi Miyake , Masatoshi Imada , Silke Biermann

Kohn-Sham density functional theory calculations using conventional diagonalization based methods become increasingly expensive as temperature increases due to the need to compute increasing numbers of partially occupied states. We present…

Chemical Physics · Physics 2022-03-23 Qimen Xu , Xin Jing , Boqin Zhang , John E. Pask , Phanish Suryanarayana

Conductance, on-site and inter-site charge fluctuations and spin correlations in the system of two side-coupled quantum dots are calculated using the Wilson's numerical renormalization group (NRG) technique. We also show spectral density…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Rok Zitko , Janez Bonca

A summary is presented of the properties of the coefficient matrices formed by expanding the two-body reduced density matrix in a complete set of two-electron wave functions. Calculating the relationship between the many electron wave…

Quantum Physics · Physics 2022-03-02 Nicholas Cox

The recently developed Doubles Connected Moments (DCM) expansion offers a tractable approach for computing correlation energy, exhibiting an noniterative O(N^6) scaling with system size N. Benchmark calculations on a set of molecules…

Chemical Physics · Physics 2026-05-12 Chongxiao Zhao , Wenjie Dou

A recently developed density functional method, within Hohenberg-Kohn-Sham framework, is used for faithful description of atoms, molecules in Cartesian coordinate grid, by using an LCAO-MO ansatz. Classical Coulomb potential is obtained by…

Chemical Physics · Physics 2013-07-16 Amlan K. Roy

The variational determination of the two-particle density matrix is an interesting, but not yet fully explored technique that allows to obtain ground-state properties of a quantum many-body system without reference to an $N$-particle wave…

Strongly Correlated Electrons · Physics 2012-05-22 Brecht Verstichel , Helen van Aggelen , Ward Poelmans , Dimitri Van Neck

Empirically correlated density matrices of N-electron systems are investigated. Exact closed-form expressions are derived for the one- and two-electron reduced density matrices from a general pairwise correlated wave function. Approximate…

Chemical Physics · Physics 2008-02-19 Sebastien Ragot , Pierre J. Becker

In this paper we present a new approach how to extract polarization-dependent exchange-correlation energy densities for two-dimensional systems from reference densities and energies of quantum dots provided by exact diagonalization.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Andreas Wensauer , Ulrich Rössler

The ground state energy of a many-electron system can be approximated by an variational approach in which the total energy of the system is minimized with respect to one and two-body reduced density matrices (RDM) instead of many-electron…

Optimization and Control · Mathematics 2017-09-01 Yongfeng Li , Zaiwen Wen , Chao Yang , Yaxiang Yuan

We present high-precision non-relativistic variational calculations of bound vibrational-rotational state energies for the $H_2^+$ and $D_2^+$ molecular ions in each of the lowest electronic states of $\Sigma_g$, $\Sigma_u$, and $\Pi_u$…

Atomic Physics · Physics 2007-05-23 J. M. Taylor , Zong-Chao Yan , A. Dalgarno , J. F. Babb

We introduce the transcorrelated Density Matrix Renormalization Group (tcDMRG) theory for the efficient approximation of the energy for strongly correlated systems. tcDMRG encodes the wave function as a product of a fixed Jastrow or…

Strongly Correlated Electrons · Physics 2020-11-13 Alberto Baiardi , Markus Reiher

A new scheme of first-principles computation for strongly correlated electron systems is proposed. This scheme starts from the local-density approximation (LDA) at high-energy band structure, while the low-energy effective Hamiltonian is…

Materials Science · Physics 2007-05-23 Yoshiki Imai , Igor V. Solovyev , Masatoshi Imada

We construct the complementary short-range correlation relativistic local-density-approximation functional to be used in relativistic range-separated density-functional theory based on a Dirac-Coulomb Hamiltonian in the no-pair…

Chemical Physics · Physics 2021-05-26 Julien Paquier , Julien Toulouse

Extensive variational computations are reported for the ground state energy of the non-relativistic two-electron atom. Several different sets of basis functions were systematically explored, starting with the original scheme of Hylleraas.…

Atomic Physics · Physics 2009-11-07 Charles Schwartz

In this work we introduce the Dual Boson Diagrammatic Monte Carlo technique for strongly interacting electronic systems. This method combines the strength of dynamical mean-filed theory for non-perturbative description of local correlations…

Strongly Correlated Electrons · Physics 2020-11-06 M. Vandelli , V. Harkov , E. A. Stepanov , J. Gukelberger , E. Kozik , A. Rubio , A. I. Lichtenstein

The ground state phase diagram of two-dimensional electrons in high magnetic field is studied by the density matrix renormalization group (DMRG) method. The low energy excitations and pair correlation functions in Landau levels of N=0,1,2…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Naokazu Shibata , Daijiro Yoshioka

The reduced density matrix (RDM) plays a key role in quantum entanglement and measurement, as it allows the extraction of almost all physical quantities related to the reduced degrees of freedom. However, restricted by the degrees of…

Quantum Physics · Physics 2025-03-27 Bin-Bin Mao , Yi-Ming Ding , Zhe Wang , Shijie Hu , Zheng Yan

Classical shadow tomography provides a randomized scheme for approximating the quantum state and its properties at reduced computational cost with applications in quantum computing. In this Letter we present an algorithm for realizing fewer…

Quantum Physics · Physics 2023-12-20 Irma Avdic , David A. Mazziotti

We compute the energy levels of a 2D Hydrogen atom when a constant magnetic field is applied. With the help of a mixed-basis variational method and a genera lization of virial theorem, which consists in scaling the wave function, we…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Ramiro Pino , Victor M. Villalba
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