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By means of quantum mechanics and quantum electrodynamics applied to coupled harmonic Drude oscillators, we study the interaction between two neutral atoms or molecules subject to a uniform static electric field. Our focus is to understand…

Chemical Physics · Physics 2022-03-16 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

We develop a quantum embedding method that enables accurate and efficient treatment of interactions between molecules and an environment, while explicitly including many-body correlations. The molecule is composed of classical nuclei and…

Chemical Physics · Physics 2023-03-30 Matej Ditte , Matteo Barborini , Leonardo Medrano Sandonas , Alexandre Tkatchenko

We develop an approach to investigate the non-perturbative dynamics of quantum field theories, in which specific vacuum field fluctuations are treated as the low-energy dynamical degrees of freedom, while all other vacuum field…

High Energy Physics - Lattice · Physics 2010-05-12 R. Millo , P. Faccioli , L. Scorzato

Controlling interactions between cold molecules using external fields can elucidate the role of quantum mechanics in molecular collisions. We create a new experimental platform in which ultracold rubidium atoms and cold ammonia molecules…

Atomic Physics · Physics 2011-05-24 L. P. Parazzoli , N. J. Fitch , P. S. Zuchowski , J. M. Hutson , H. J. Lewandowski

This series of papers has two broader aims: 1) Construct a theory for multi-partite open quantum systems comprising several layers of structure with self-consistent back-actions. Develop the graded influence action formalism…

High Energy Physics - Theory · Physics 2025-05-27 Jen-Tsung Hsiang , Bei-Lok Hu

This report provides a brief review of recently developed extended framework for fundamental physics, designated as Quantum Field Mechanics and including causally complete and intrinsically unified theory of explicitly emerging elementary…

General Physics · Physics 2007-05-23 Andrei P. Kirilyuk

The theory of the strong interactions, Quantum Chromodynamics (QCD), has been addressed by a variety of non-perturbative techniques over the decades since its introduction. We have investigated Hamiltonian formulations with different…

High Energy Physics - Theory · Physics 2007-05-23 J. P. Vary , T. J. Fields J. R. Spence , H. W. L. Naus , H. J. Pirner , K. S. Gupta

The quantum Drude oscillator (QDO) is an efficient yet accurate coarse-grained approach that has been widely used to model electronic and optical response properties of atoms and molecules, as well as polarization and dispersion…

Quantum-mechanically-driven charge polarization and charge transfer are ubiquitous in biomolecular systems, controlling reaction rates, allosteric interactions, ligand-protein binding, membrane transport, and dynamically-driven structural…

Chemical Physics · Physics 2021-06-09 Susan R. Atlas

Quantum stochastic differential equations have been used to describe the dynamics of an atom interacting with the electromagnetic field via absorption/emission processes. Here, by using the full quantum stochastic Schroedinger equation…

Quantum Physics · Physics 2009-10-31 Alberto Barchielli , Giancarlo Lupieri

Conventional quantum chemical solvation theories are based on the mean-field embedding approximation. That is, the electronic wavefunction is calculated in the presence of the mean field of the environment. In this paper a direct quantum…

Chemical Physics · Physics 2009-11-13 Takeshi Yamamoto

We apply the ideas of effective field theory to nonrelativistic quantum mechanics. Utilizing an artificial boundary of ignorance as a calculational tool, we develop the effective theory using boundary conditions to encode short-ranged…

Atomic Physics · Physics 2022-06-13 David M. Jacobs , Matthew Jankowski

Non-covalent interactions are a key ingredient to determine the structure, stability, and dynamics of materials, molecules, and biological complexes. However, accurately capturing these interactions is a complex quantum many-body problem,…

Quantum Physics · Physics 2023-10-27 Matthieu Sarkis , Alessio Fallani , Alexandre Tkatchenko

An analytic approach to the electron transport phenomena in molecular devices is presented. Analyzed devices are composed of organic molecules attached to the two semi-infinite electrodes. Molecular system is described within the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kamil Walczak

We present a quaternion inspired formalism specifically developed to evaluate the intensity of the electrical current that traverses a single molecule connected to two semi-infinite electrodes as the applied external bias is varied. The…

Mesoscale and Nanoscale Physics · Physics 2012-01-18 Augusto C. L. Moreira , Celso P. de Melo

Molecular dynamics with electronic friction (MDEF) approach can describe nonadiabatic effects accurately at metal surfaces in the weak nonadiabatic limit. That being said, MDEF treats nuclear motion classically, such that the nuclear…

Chemical Physics · Physics 2024-04-09 Rui-Hao Bi , Wenjie Dou

Electronic polarization and dispersion are decisive actors in determining interaction energies between molecules. These interactions have a particularly profound effect on excitation energies of molecules in complex environments, especially…

Chemical Physics · Physics 2024-12-13 Thomas P. Fay , Nicolas Ferré , Miquel Huix-Rotllant

We present an efficient method for rigorous quantum calculations of cross sections for atom-molecule reactive scattering in the presence of a dc electric field. The wavefunction of the reaction complex is expanded in an overcomplete set of…

Chemical Physics · Physics 2026-05-07 Timur V. Tscherbul , Roman V. Krems

Stochastic perturbation of two-level atoms strongly driven by a coherent light field is analyzed by the quantum trajectory method. A new method is developed for calculating the resonance fluorescence spectra from numerical simulations. It…

Quantum Physics · Physics 2009-11-07 A. Karpati , P. Adam , W. Gawlik , B. Lobodzinski , J. Janszky

Electric field-assisted chemistry has attracted much attention in recent years, particularly in the context of oriented external electric fields for controlling molecular structure and reactivity. Such fields have been explored in a wide…

Chemical Physics · Physics 2026-05-08 Duc Anh Lai , Devin A. Matthews
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