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Related papers: Stress-Induced Phase Transitions in Nanoscale CuIn…

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Using the Landau-Ginzburg-Devonshire approach, we study stress-induced transformations of polarization switching in ferrielectric CuInP2S6 nanoparticles for three different shapes: a disk, a sphere, and a needle. Semiconducting properties…

Nanoscale ferroelectric 2D materials offer unique opportunity to investigate curvature and strain effects on materials functionalities. Among these, CuInP2S6 (CIPS) has attracted tremendous research interest in recent years due to…

Strain-induced transitions of polarization reversal in thin films of a ferrielectric CuInP$_2$S$_6$ (CIPS) with ideally-conductive electrodes is explored using the Landau-Ginzburg-Devonshire (LGD) approach with an eighth-order free energy…

Using Landau-Ginzburg-Devonshire (LGD) phenomenological approach we analyze the bending-induced re-distribution of electric polarization and field, elastic stresses and strains inside ultrathin layers of van der Waals ferrielectrics. We…

2D layered ferroelectric materials such as CuInP$_2$S6 (CIPS) are promising candidates for novel and high-performance photocatalysts, owning to their ultrathin layer thickness, strong interlayer coupling, and intrinsic spontaneous…

Materials Science · Physics 2023-01-26 Fanyi Kong , Lei Zhang , Tianze Cong , Zhiwei Wu , Kun Liu , Changsen Sun , Lujun Pan , Dawei Li

CuInP2S6 (CIPS) is an emerging layered material that exhibits ferrielectric ordering well above room temperature (Curie temperature TC ~ 315 K). When synthesized with Cu deficiencies, CIPS spontaneously segregates into CuInP2S6 and…

Materials Science · Physics 2021-11-02 Rahul Rao , Ryan Selhorst , Benjamin S. Conner , Michael A. Susner

Ferroelectricity in van der Waals (vdW) layered material has attracted a great deal of interest recently. CuInP$_2$S$_6$ (CIPS), the only vdW layered material whose ferroelectricity in the bulk was demonstrated by direct polarization…

Materials Science · Physics 2023-09-20 Jinyuan Yao , Yongtao Liu , Shaoqing Ding , Yanglin Zhu , Zhiqiang Mao , Sergei V. Kalinin , Ying Liu

Layered multi-ferroic materials exhibit a variety of functional properties that can be tuned by varying the temperature and pressure. As-synthesized CuInP$_2$S$_6$ is a layered material that displays ferrielectric behavior at room…

Materials Science · Physics 2022-01-05 Rahul Rao , Benjamin S. Conner , Ryan Selhorst , Michael A. Susner

The low-dimensional ferroelectrics, ferrielectrics and antiferroelectrics are of urgent scientific interest due to their unusual polar, piezoelectric, electrocaloric and pyroelectric properties. The strain engineering and strain control of…

The interest in ferroelectric van der Waals crystals arises from the potential to realize ultrathin ferroic systems owing to the reduced surface energy of these materials and the layered structure that allows for exfoliation. Here, we…

Using the Landau-Ginzburg-Devonshire phenomenological approach we explore the strain-polarization coupling in the low-dimensional van der Waals ferrielectrics. We evolve the analytical model of the piezoelectric susceptibility of the…

Using first-principles calculations we model the out-of-plane switching of local dipoles in CuInP$_2$S$_6$ (CIPS) that are largely induced by Cu off-centering. Previously, a coherent switching of polarization via a quadruple-well potential…

Materials Science · Physics 2023-06-23 N. Sivadas , Bobby G. Sumpter , P. Ganesh

General approach for consideration of primary ferroic (ferroelectric, ferromagnetic, ferroelastic) nanoparticles phase transitions was proposed in phenomenological theory framework. The surface stress, order parameter gradient, striction as…

Materials Science · Physics 2009-11-13 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

In this paper we study the size effects of the ferroelectric nanotube and nanowire phase diagrams and polar properties allowing for radial stress and depolarization field influence. The approximate analytical expression for the…

Materials Science · Physics 2009-05-09 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

Using the Landau-Ginzburg-Devonshire approach, we study screening-induced phase transitions in core-shell ferroic nanoparticles for three different shapes: an oblate disk, a sphere, and a prolate needle. The nanoparticle is made of a…

Two dimensional ferroic materials exhibit a variety of functional properties that can be tuned by temperature and pressure. CuInP2S6 is a layered material that is ferrielectric at room temperature and whose properties are a result of the…

Materials Science · Physics 2023-06-14 R. Rao , B. S. Conner , J. Jiang , R. Pachter , M. A. Susner

Interlayer stacking order has recently emerged as a unique degree of freedom to control crystal symmetry and physical properties in two-dimensional van der Waals (vdW) materials and heterostructures. By tuning the layer stacking pattern,…

Layered magnetic transition-metal thiophosphate NiPS3 has unique two-dimensional (2D) magnetic properties and electronic behavior. The electronic band structure and corresponding magnetic state are expected to sensitive to the interlayer…

Strongly Correlated Electrons · Physics 2020-09-30 Xiaoli Ma , Yimeng Wang , Yunyu Yin , Binbin Yue , Jianhong Dai , Jianting Ji , Feng Jin , Fang Hong , Jian-Tao Wang , Qingming Zhang , Xiaohui Yu

CuInP2S6 (CIPS) is an emerging layered ferroelectric material with a TC above room temperature. When synthesized with Cu deficiencies (i.e., Cu1-xIn1+x/3P2S6), the material segregates into CIPS and In4/3P2S6 (IPS) self-assembled…

Van der Waals (vdW) layered materials have rather weaker interlayer bonding than the intra-layer bonding, therefore the exfoliation along the stacking direction enables the achievement of monolayer or few layers vdW materials with emerging…

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