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Hybrid Lead halide perovskites, despite having unique intrinsic properties with the possibility of flexible synthesis and device fabrication, still suffer from two fundamental issues, i.e. stability in external environment and toxicity due…

Materials Science · Physics 2018-05-16 Jiban Kangsabanik , Vipinraj Sugathan , Anuradha Yadav , Aswani Yella , Aftab Alam

In this work, we present large-scale electron-correlated computations on various conformers of B$_{12}$H$_{12}$ and B$_{12}$H$_{6}$ clusters, to understand the reasons behind the high stability of di-anion icosahedron ($I_{h}$) and…

Chemical Physics · Physics 2022-01-03 Pritam Bhattacharyya , Ihsan Boustani , Alok Shukla

One of the main challenges for perovskite solar cells (PSC) is their stability, due to environment-induced perovskite decomposition. The resulting decomposition compounds are mobile and may, therefore, react with charge carrier extraction…

Applied Physics · Physics 2019-09-30 Svetlana Sirotinskaya , Roland Schmechel , Niels Benson

Iodide elpasolites (or double perovskites, A2B'B"I6, B' = M+, B" = M3+) are predicted to be promising alternatives to lead-based perovskite semiconductors for photovoltaic and optoelectronic applications, but no iodide elpasolite has ever…

Materials Science · Physics 2023-12-13 Kyle T. Kluherz , Sebastian T. Mergelsberg , James J. De Yoreo , Daniel R. Gamelin

Extended defects such as stacking faults and anti-site domain boundaries can perturb the band edges in Cu$_2$ZnSnS$_4$ and Cu$_2$ZnSnSe$_4$, acting as a weak electron barrier or a source for electron capture, respectively. In order to find…

Materials Science · Physics 2019-01-23 Ji-Sang Park , Sunghyun Kim , Aron Walsh

Solar energy is rapidly becoming a robust renewable energy source to conventional finite resources such as fossil fuels. It is harvested using interconnected photovoltaic panels, typically built with crystalline silicon cells, i.e.…

Computer Vision and Pattern Recognition · Computer Science 2024-03-12 Booy Vitas Faassen , Jorge Serrano , Paul D. Rosero-Montalvo

Practical device architectures are proposed here for the implementation of three-terminal heterojunction bipolar transistor solar cells (3T-HBTSCs). These photovoltaic devices, which have a potential efficiency similar to that of…

Applied Physics · Physics 2019-04-30 Pablo G. Linares , Elisa Antolín , Antonio Martí

We examine the structural properties of free standing II-VI and III-V semiconductors at the monolayer limit within first principle density functional theory calculations. A non-polar buckled structure was found to be favoured over a polar…

Mesoscale and Nanoscale Physics · Physics 2018-01-17 Poonam Kumari , Saikat Debnath , Priya Mahadevan

Organic-inorganic hybrids may offer material properties not available from their inorganic components. However, they are typically less stable and disordered. Long-term stability study of the hybrid materials, over the anticipated lifespan…

The binary Bi-chalchogenides, Bi2Ch3, are widely regarded as model examples of a recently discovered new form of quantum matter, the three-dimensional topological insulator (TI) [1-4]. These compounds host a single spin-helical surface…

Chalcogenide perovskites are an emerging class of photovoltaic absorbers offering stable, lead-free structures and promising optoelectronic properties. To date, the literature on chalcogenide perovskites has focused primarily on fully…

Materials Science · Physics 2026-04-09 Ruiqi Wu , JJ Acton , Shirui Wang , Alex Ganose

The prospect of achieving fault-tolerant quantum computing with semiconductor spin qubits in Si/SiGe heterostructures relies on the integration of a large number of identical devices, a feat achievable through a scalable (Bi)CMOS…

Various ternary chalcogenide systems and their properties are one of the hot topics for researchers nowadays. In this article, one of the ternary chalcogenide compounds, CdTl2Te4 is studied including its electronic structures and optical…

Materials Science · Physics 2020-05-11 Aditya Dey

Next-generation low-cost semiconductors such as halide perovskites exhibit optoelectronic properties dominated by nanoscale variations in their structure, composition and photophysics. While microscopy provides a proxy for ultimate device…

Nuclear radiation detectors play a crucial role in fields such as nuclear safety and medical imaging. The core of their performance lies in the selection of detection materials. Semiconductor detectors have become a hot topic in current…

Materials Science · Physics 2025-04-15 Linlin Liu , Zuanquan Chen , Wensi Yang , Sen Zhang , Jiaqi Zhu

The stability of atomic intercalated carbon $K_{4}$ crystals, XC$_{2}$ (X=H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ga, Ge, As, Se, Br, Rb or Sr) is evaluated by geometry optimization and frozen phonon analysis based on…

Materials Science · Physics 2011-03-23 Masahiro Itoh , Seiichi Takami , Yoshiyuki Kawazoe , Tadafumi Adschiri

Silver-based chalcohalide anti-perovskites (CAP), Ag$_{3}$BC (B = S, Se; C = Cl, Br, I), represent an emerging family of energy materials with intriguing optoelectronic, vibrational and ionic transport properties. However, the structural…

A thorough consideration of the relation between the lattice parameters of 185 binary and ternary spinel compounds, on one side, and ionic radii and electronegativities of the constituting ions, on the other side, allowed for establishing a…

Materials Science · Physics 2014-05-20 M. G. Brik , A. Suchocki , A. Kamińska

Polar materials have recently attracted significant interest due to their rich multifunctional properties. The chalcogenide polar semiconductor Cu1-xMn1+ySiTe3 (Cu-deficient) is an emerging multiferroic system in which electric polarization…

Organic-inorganic halide perovskite solar cells have recently attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. The reduction from three- to two-dimension (2D) promises an…

Materials Science · Physics 2018-07-24 Rahul Singh , Prashant Singh , Ganesh Balasubramanian