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A broad fundamental understanding of the mechanisms underlying the phenomenology of supercooled liquids has remained elusive, despite decades of intense exploration. When supercooled beneath its characteristic melting temperature, a liquid…

Soft Condensed Matter · Physics 2016-11-10 Nicholas B. Weingartner , Chris Pueblo , Flavio S. Nogueira , K. F. Kelton , Zohar Nussinov

We numerically study dynamical properties of the one-component Gaussian Core Model in the supercooled states. We find that nucleation is suppressed as density increases. Concomitantly the system exhibits glassy slow dynamics characterized…

Soft Condensed Matter · Physics 2015-05-19 Atsushi Ikeda , Kunimasa Miyazaki

The dynamic slowdown in glass-forming liquids remains a central topic in condensed matter science. Here, we report a theoretical investigation of the microscopic origin of the slowdown in amorphous silica, a prototypical strong glass former…

Soft Condensed Matter · Physics 2026-05-27 Shubham Kumar , Zhiye Tang , Shinji Saito

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

Statistical Mechanics · Physics 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

Using Monte Carlo simulations we study the dynamics of three-dimensional Ising models with nearest-, next-nearest-, and four-spin (plaquette) interactions. During coarsening, such models develop growing energy barriers, which leads to very…

Statistical Mechanics · Physics 2009-10-31 A. Lipowski , D. Johnston , D. Espriu

The viscous slowing down of supercooled liquids that leads to glass formation can be considered as a classical, and is assuredly a thoroughly studied, example of a "jamming process". In this review, we stress the distinctive features…

Statistical Mechanics · Physics 2007-05-23 G. Tarjus , D. Kivelson

Diffusivity, a measure for how rapidly a fluid self-mixes, shows an intimate, but seemingly fragmented, connection to thermodynamics. On one hand, the "configurational" contribution to entropy (related to the number of mechanically-stable…

Statistical Mechanics · Physics 2007-05-23 Jeetain Mittal , Jeffrey R. Errington , Thomas M. Truskett

Advances in high-precision dielectric spectroscopy has enabled access to non-linear susceptibilities of polar molecular liquids. The observed non-monotonic behavior has been claimed to provide strong support for theories of dynamic arrest…

Soft Condensed Matter · Physics 2021-07-07 Thomas Speck

Experimental studies of the glassy slowdown in molecular liquids indicate that the high-temperature activation energy $E_{\infty}$ of glass-forming liquids is directly related to their glass transition temperature $T_{\text{g}}$. To further…

Soft Condensed Matter · Physics 2021-03-02 L. Hecht , R. Horstmann , B. Liebchen , M. Vogel

State-of-the-art techniques for simulating deeply supercooled liquids require a high degree of size polydispersity to be effective. While these techniques have enabled great insight into the microscopic dynamics near the glass transition,…

Soft Condensed Matter · Physics 2023-08-10 Ilian Pihlajamaa , Corentin C. L. Laudicina , Liesbeth M. C. Janssen

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

The slowing down of molecular dynamics when approaching the glass transition generally proceeds much stronger than expected for thermally activated motions. This strange phenomenon can be formally ascribed to a temperature-dependent…

Soft Condensed Matter · Physics 2013-11-28 Th. Bauer , P. Lunkenheimer , A. Loidl

We use computer simulations to study the relaxation dynamics of a model for oil-in-water microemulsion droplets linked with telechelic polymers. This system exhibits both gel and glass phases and we show that the competition between these…

Soft Condensed Matter · Physics 2015-05-29 Pinaki Chaudhuri , Pablo I. Hurtado , Ludovic Berthier , Walter Kob

It is experimentally shown that, depending on the carrier-concentration of the system $n$, the dynamics of electron-glasses either \textit{slows down }with increasing temperature or it is \textit{independent} of it. This also correlates…

Strongly Correlated Electrons · Physics 2007-11-28 Z. Ovadyahu

In this third and final paper of a series, elastic properties of numerically simulated isotropic packings of spherical beads assembled by different procedures and subjected to a varying confining pressure P are investigated. In addition P,…

Disordered Systems and Neural Networks · Physics 2016-09-08 Ivana Agnolin , Jean-Noël Roux

We present a model for glassy dynamics in supercooled liquid mixtures. Given the relaxation behavior of individual supercooled liquids, the model predicts the relaxation times of their mixtures as temperature is decreased. The model is…

Statistical Mechanics · Physics 2019-09-11 Shachi Katira , Juan P. Garrahan , Kranthi K. Mandadapu

We consider the problem of slow activation dynamics in glassy systems undergoing a random first order phase transition. Using an effective potential approach to supercooled liquids, we determine the spectrum of activation barriers for…

Disordered Systems and Neural Networks · Physics 2013-05-29 Maxim Dzero , Joerg Schmalian , Peter G. Wolynes

Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, T_{g}, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for…

Disordered Systems and Neural Networks · Physics 2024-04-24 Joseph B. Schlenoff , Khalil Akkaoui

We use computer simulations to study the cooling rate dependence of the stability and energetics of model glasses created at constant pressure conditions and compare the results with glasses formed at constant volume conditions. To examine…

Soft Condensed Matter · Physics 2016-12-21 Hannah Staley , Elijah Flenner , Grzegorz Szamel

We present a consistent picture of the respective role of density and temperature in the viscous slowing down of glassforming liquids and polymers. Specifically, based in part upon a new analysis of simulation and experimental data on…

Soft Condensed Matter · Physics 2009-11-10 G. Tarjus , D. Kivelson , S. Mossa , C. Alba-Simionesco
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