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Using radio observations with the Green Bank Telescope, evidence has now been found for a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based on additional observations of an ongoing, large-scale,…

We decompose the observed 7.7 $\mu$m polycyclic aromatic hydrocarbon (PAH) emission complexes in a large sample of over 7000 mid-infrared spectra of the interstellar medium (ISM) using spectral cubes observed with the Spitzer/IRS-SL…

Astrophysics of Galaxies · Physics 2017-03-22 D. J. Stock , E. Peeters

We present the synthesis and laboratory rotational spectroscopy of the 7-ring polycyclic aromatic hydrocarbon (PAH) cyanocoronene (C$_{24}$H$_{11}$CN) using a laser-ablation assisted cavity-enhanced Fourier transform microwave spectrometer.…

Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a…

Astrophysics of Galaxies · Physics 2009-04-22 C. Joblin , O. Berne , A. Simon , G. Mulas

We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the…

The infrared (IR) emission of polycyclic aromatic hydrocarbons (PAHs) permeates our universe; astronomers have detected the IR signatures of PAHs around many interstellar objects. The IR emission of interstellar PAHs differs from their…

Astrophysics of Galaxies · Physics 2018-10-05 Cameron J. Mackie , Tao Chen , Alessandra Candian , Timothy J. Lee , Alexander G. G. M. Tielens

In order to find out capable chemical evolution step from astronomically created organic in interstellar space to biological organic on the earth, infrared spectrum of nitrogen substituted carbon pentagon-hexagon coupled polycyclic aromatic…

Chemical Physics · Physics 2016-03-11 Norio Ota

Using a large collection of near-infrared spectra (2.5-5.4 um) of Galactic HII regions and HII region-like objects, we perform a systematic investigation of the astronomical polycyclic aromatic hydrocarbon (PAH) features. 36 objects were…

Astrophysics of Galaxies · Physics 2015-06-18 Tamami I. Mori , Takashi Onaka , Itsuki Sakon , Daisuke Ishihara , Takashi Shimonishi , Ryou Ohsawa , Aaron C. Bell

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in astrophysical environments, as revealed by their pronounced emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $\mu$m commonly ascribed to the C--H and C--C vibrational modes.…

Astrophysics of Galaxies · Physics 2017-07-19 Han Zhang , Charles M. Telesco , Thiem Hoang , Aigen Li , Eric Pantin , Christopher M. Wright , Dan Li , Peter Barnes

Polycyclic aromatic hydrocarbon (PAH) molecules, as revealed by the distinctive set of emission bands at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m characteristic of their vibrational modes, are abundant and widespread throughout the…

Astrophysics of Galaxies · Physics 2020-03-25 Aigen Li

There exists a number of astronomical spectral phenomena that have remained unidentified after decades of extensive observations. The diffuse interstellar bands, the 220 nm feature, unidentified infrared emission bands, extended red…

Astrophysics of Galaxies · Physics 2021-08-11 Sun Kwok

We report the detection of the polycyclic aromatic hydrocarbon (PAH) 1H-cyclopent[cd]indene (c-C11H8) in TMC-1 with the QUI- JOTE line survey. We detected 22 independent lines corresponding to 88 rotational transitions with quantum numbers…

Astrophysics of Galaxies · Physics 2026-02-02 R. Fuentetaja , C. Cabezas , M. Agúndez , B. Tercero , N. Marcelino , P. de Vicente , J. Cernicharo

We present an overview of the GOTHAM (GBT Observations of TMC-1: Hunting Aromatic Molecules) Large Program on the Green Bank Telescope. This and a related program were launched to explore the depth and breadth of aromatic chemistry in the…

The rich molecular structures of polycyclic aromatic hydrocarbons -- essentially planar flakes of fused benzene rings -- and their fullerene cousins are revealed through their vibrational and electronic spectra.

Astrophysics of Galaxies · Physics 2019-08-19 A. Candian , J. Zhen , A. G. G. M. Tielens

Interstellar infrared observation shows featured spectrum due to polycyclic aromatic hydrocarbon (PAH)at wavelength 3.3,6.2,7.6,7.8,8.6,and 11.3 micrometer,which are ubiquitously observed in many astronomical dust clouds and galaxies. Our…

Astrophysics of Galaxies · Physics 2018-08-06 Norio Ota

The 11.3 $\mu$m emission feature is a prominent member of the family of unidentified infrared emission (UIE) bands and is frequently attributed to out-of-plane bending modes of polycyclic aromatic hydrocarbon (PAH) molecules. We have…

Solar and Stellar Astrophysics · Physics 2015-07-15 SeyedAbdolreza Sadjadi , Yong Zhang , Sun Kwok

Polycyclic aromatic hydrocarbon (PAH) ions are crucial intermediates in interstellar chemistry and may play a key role in the infrared emission features observed in space. Here, we investigate the infrared spectra of the indenyl…

Polycyclic aromatic hydrocarbons (PAHs) are responsible for a variety of near- and mid-infrared spectral features in Galactic and extragalactic sources. A feature at 1.05 $\mu$m arising from electronic transitions in PAH cations is…

Astrophysics of Galaxies · Physics 2026-03-25 Dennis Lee , Brandon S. Hensley , Tzu-Ching Chang , Olivier Doré

Recurrent fluorescence (RF) is an important relaxation mechanism in polycyclic aromatic hydrocarbons (PAHs), which could stabilize them and contribute to the production of aromatic infrared bands that are observed in the infrared spectra of…

Chemical Physics · Physics 2026-04-01 Damien Borja , Florent Calvo , Pascal Parneix , Cyril Falvo

A combined mid-IR spectrum of five colliding-wind, massive, dust-producing Population I Wolf-Rayet (WR) binaries shows a wealth of absorption and emission details coming from the circumstellar dust envelopes, as well as from the…

Solar and Stellar Astrophysics · Physics 2017-04-19 S. V. Marchenko , A. F. J. Moffat