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Application of Jarzynski nonequilibrium work relation to free energy calculation is limited by the very slow convergence of the estimate when dissipation is high. We present a novel perturbation protocol able to improve the convergence of…

Statistical Mechanics · Physics 2008-01-03 Ognjen Perisic , Hui Lu

The partition function and free energy of a quantum many-body system determine its physical properties in thermal equilibrium. Here we study the computational complexity of approximating these quantities for $n$-qubit local Hamiltonians.…

Quantum Physics · Physics 2023-09-22 Sergey Bravyi , Anirban Chowdhury , David Gosset , Pawel Wocjan

Molecular dynamics simulations of a quasi-harmonic solid are conducted to elucidate the meaning of temperature fluctuations in canonical systems and validate a well-known but frequently contested equation predicting the mean square of such…

Statistical Mechanics · Physics 2016-12-01 J. Hickman , Y. Mishin

We present a method, based on characterizing efficiency fluctuations, to asses the performance of nanoscale thermoelectric junctions. This method accounts for effects typically arising in small junctions, namely, stochasticity in the…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Massimiliano Esposito , Maicol A. Ochoa , Michael Galperin

We use quantum estimation theory to derive a thermodynamic uncertainty relation in Markovian open quantum systems, which bounds the fluctuation of continuous measurements. The derived quantum thermodynamic uncertainty relation holds for…

Statistical Mechanics · Physics 2020-07-30 Yoshihiko Hasegawa

The relation between the distribution of work performed on a classical system by an external force switched on an arbitrary timescale, and the corresponding equilibrium free energy difference, is generalized to quantum systems. Using the…

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

The quantum critical regime marks a zone in the phase diagram where quantum fluctuation around the critical point plays a significant role at finite temperatures. While it is of great physical interest, simulation of the quantum critical…

Quantum Physics · Physics 2023-08-09 Zhi-Quan Shi , Xu-Dan Xie , Dan-Bo Zhang

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

Quantum computers are appealing for their ability to solve some tasks much faster than their classical counterparts. It was shown in [Aspuru-Guzik et al., Science 309, 1704 (2005)] that they, if available, would be able to perform the full…

Quantum Physics · Physics 2010-11-19 Libor Veis , Jiří Pittner

Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

We illustrate recent results concerning the validity of the work fluctuation theorem in open quantum systems [M. Campisi, P. Talkner, and P. H\"{a}nggi, Phys. Rev. Lett. {\bf 102}, 210401 (2009)], by applying them to a solvable model of an…

Statistical Mechanics · Physics 2009-09-14 Michele Campisi , Peter Talkner , Peter Hänggi

The computation of dynamical response functions is central to many problems in condensed matter physics. Owing to the rapid growth of quantum correlations following a quench, classical methods face significant challenges even if an…

Quantum Physics · Physics 2025-05-09 Esther Cruz , Dominik S. Wild , Mari Carmen Bañuls , J. Ignacio Cirac

Stochastic dynamics in the energy representation is employed as a method to study non-equilibrium Brownian-like systems. It is shown that the equation of motion for the energy of such systems can be taken in the form of the Langevin…

Statistical Mechanics · Physics 2015-05-18 Bohdan I. Lev , Alexei D. Kiselev

We use the quantum Brownian model to derive the uncertainty relation for a quantum open system. We examine how the fluctuations of a quantum system evolve after it is brought in contact with a heat bath at finite temperature. We study the…

General Relativity and Quantum Cosmology · Physics 2015-06-25 B. L. Hu , Yuhong Zhang

We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the…

Statistical Mechanics · Physics 2017-09-15 Yi Peng , Heng Fan

Fluctuation theorems are relations constraining the out-of-equilibrium fluctuations of thermodynamic quantities like the entropy production that were initially introduced for classical or quantum systems in contact with a thermal bath. Here…

Quantum Physics · Physics 2019-02-27 Sreenath K. Manikandan , Cyril Elouard , Andrew N. Jordan

The Heisenberg uncertainty relation, which links the uncertainties of the position and momentum of a particle, has an important footprint on the quantum behavior of a physical system. Analogous to this principle, we propose that…

Quantum Physics · Physics 2026-02-18 Pratik Sathe , Luis Pedro García-Pintos , Francesco Caravelli

We present a new class of fluctuation relations, to which we will refer as Fluctuation Relations for Current Components (FRCCs). FRCCs can be used to estimate system parameters when complete information about nonequilibrium many-body…

Mesoscale and Nanoscale Physics · Physics 2015-05-30 Sriram Ganeshan , N. A. Sinitsyn

Fluctuations associated with relaxations in far-from-equilibrium regime is of fundamental interest for a large variety of systems within broad scales. Recent advances in techniques such as spectroscopy have generated the possibility for…

Quantum Physics · Physics 2021-09-08 Zhedong Zhang , Xuanhua Wang , Jin Wang

Despite the strength of Molecular Dynamics simulations in providing insights into the microscopic details of phenomenon in many fields in materials science, physics and biology, the biggest barrier is its limited timescale which is several…

Materials Science · Physics 2026-05-19 Mahdi Tavakol , Jin-Chong Tan , Alexander M. Korsunsky