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Understanding strongly correlated systems is essential for advancing quantum chemistry and materials science, yet conventional methods like Density Functional Theory (DFT) often fail to capture their complex electronic behavior. To address…

Chemical Physics · Physics 2025-09-01 Archith Rayabharam , N. R. Aluru

A quantitative description of the excited electronic states of point defects and impurities is crucial for understanding materials properties, and possible applications of defects in quantum technologies. This is a considerable challenge…

The density functional theory (DFT) is the most versatile electronic structure method used in quantum chemical calculations, and is increasingly applied in astrochemical research. This mini-review provides an overview of the applications of…

Astrophysics of Galaxies · Physics 2023-10-24 Qingli Liao , Junzhi Wang , Peng Xie , Enwei Liang , Zhao Wang

Accurate modeling in the warm dense matter regime is a persistent challenge with the most detailed models such as quantum molecular dynamics and path integral Monte Carlo being immensely computationally expensive. Density functional theory…

Materials Science · Physics 2024-09-04 Sameen Yunus , David A. Strubbe

In this study, we formulate a density functional theory (DFT) for systems of labeled particles, considering a two-dimensional bead-spring lattice with a magnetic dipole on every bead as a model for ferrogels. On the one hand, DFT has been…

Soft Condensed Matter · Physics 2019-07-22 Segun Goh , René Wittmann , Andreas M. Menzel , Hartmut Löwen

From the lightest Hydrogen isotopes up to the recently synthesized Oganesson (Z=118), it is estimated that as many as about 3000 atomic nuclei could exist in nature. Most of these nuclei are too short-lived to be occurring on Earth, but…

One of the greatest challenges when designing new technologies that make use of non-trivial quantum materials is the difficulty associated with predicting material-specific properties, such as critical temperature, gap parameter, etc. There…

Superconductivity · Physics 2025-03-24 Adrian D. Scheppe , Michael V. Pak

Exchange interactions are a manifestation of the quantum mechanical nature of the electrons and play a key role in predicting the properties of materials from first principles. In density functional theory (DFT), a widely used approximation…

Materials Science · Physics 2020-03-27 Marco Bernardi

Cavity-QED systems have recently reached a regime where the light-matter interaction strength amounts to a non-negligible fraction of the resonance frequencies of the bare subsystems. In this regime, it is known that the usual normal-order…

Strongly correlated systems have long been a central and highly non-trivial topic in condensed matter physics. At the non-interacting level, strong correlation can be associated with powerful (near) degeneracies between occupied and…

Strongly Correlated Electrons · Physics 2026-04-29 Daniel D. Rivera , Gustavo M. Dalpian , John P. Perdew

The macroscopic behaviors of materials are determined by interactions that occur at multiple lengths and time scales. Depending on the application, describing, predicting, and understanding these behaviors require models that rely on…

Computational Engineering, Finance, and Science · Computer Science 2026-01-29 Zhaoxiang Shen , Raúl I. Sosa , Stéphane P. A. Bordas , Alexandre Tkatchenko , Jakub Lengiewicz

I summarize Density Functional Theory (DFT) in a language familiar to quantum field theorists, and introduce several apparently novel ideas for constructing {\it systematic} approximations for the density functional. I also note that, at…

Materials Science · Physics 2015-03-11 T. Banks

Multipole moments are the first order responses of the energy to spatial derivatives of the electric field strength. The quality of density functional theory (DFT) prediction of molecular multipole moments thus characterizes errors in…

Chemical Physics · Physics 2021-02-23 Diptarka Hait , Yu Hsuan Liang , Martin Head-Gordon

Dynamical Mean-Field Theory (DMFT) has opened new perspectives for the investigation of strongly correlated electron systems and greatly improved our understanding of correlation effects in models and materials. In contrast to…

Strongly Correlated Electrons · Physics 2020-07-16 Dieter Vollhardt

Density Functional Theory (DFT) has become the quasi-standard for ab-initio simulations for a wide range of applications. While the intrinsic cubic scaling of DFT was for a long time limiting the accessible system size to some hundred…

Materials Science · Physics 2018-02-23 Stephan Mohr , Marc Eixarch , Maximilian Amsler , Mervi J. Mantsinen , Luigi Genovese

The light-matter interaction can be utilized to qualitatively alter physical properties of materials. Recent theoretical and experimental studies have explored this possibility of controlling matter by light based on driving many-body…

Mesoscale and Nanoscale Physics · Physics 2020-11-11 Yuto Ashida , Atac Imamoglu , Jerome Faist , Dieter Jaksch , Andrea Cavalleri , Eugene Demler

Proper inclusion of van der Waals (vdW) interactions in theoretical simulations based on standard density functional theory (DFT) is crucial to describe the physics and chemistry of systems such as organic and layered materials. Many…

Materials Science · Physics 2023-07-19 Jinwoo Park , Byung Deok Yu , Suklyun Hong

When light and matter interact strongly, the resulting hybrid system inherits properties from both constituents, allowing one to modify material behavior by engineering the surrounding electromagnetic environment. This concept underlies the…

We demonstrate the existence of different density-density functionals designed to retain selected properties of the many-body ground state in a non-interacting solution starting from the standard density functional theory ground state. We…

Other Condensed Matter · Physics 2009-11-13 F. A. Reboredo , P. R. C. Kent

We present a density-functional theory (DFT) approach to the study of the phase diagram of the maximum density droplet (MDD) in two-dimensional quantum dots in a magnetic field. Within the lowest Landau level (LLL) approximation, analytical…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 M. Ferconi , G. Vignale
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