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Originally formulated for macroscopic machines, the laws of thermodynamics were recently shown to hold for quantum systems coupled to ideal sources of work (external classical fields) and heat (systems at equilibrium). Ongoing efforts have…

Quantum Physics · Physics 2023-06-29 Cyril Elouard , Camille Lombard Latune

Considering a broad class of steady-state nonequilibrium systems for which some additive quantities are conserved by the dynamics, we introduce from a statistical approach intensive thermodynamic parameters (ITPs) conjugated to the…

Statistical Mechanics · Physics 2007-05-23 Eric Bertin , Kirsten Martens , Olivier Dauchot , Michel Droz

We define thermodynamic configurations and identify two primitives of discrete quantum processes between configurations for which heat and work can be defined in a natural way. This allows us to uncover a general second law for any discrete…

Quantum Physics · Physics 2015-06-12 Janet Anders , Vittorio Giovannetti

Thermodynamic uncertainty relations have emerged as universal bounds on current fluctuations in non-equilibrium systems. Here we derive a new bound for a particular class of run-and-tumble type processes using the mathematical framework of…

Statistical Mechanics · Physics 2019-07-02 Mayank Shreshtha , Rosemary J. Harris

The second law of classical thermodynamics, based on the positivity of the entropy production, only holds for deterministic processes. Therefore the Second Law in stochastic quantum thermodynamics may not hold. By making a fundamental…

Quantum Physics · Physics 2019-11-14 B. Ahmadi , S. Salimi , A. S. Khorashad

We revisit the classic thermodynamic problem of maximum work extraction from two arbitrary sized hot and cold reservoirs, modelled as perfect gases. Assuming ignorance about the extent to which the process has advanced, which implies an…

Statistical Mechanics · Physics 2015-06-19 Ramandeep S. Johal

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

If the second law of thermodynamics forbids a transition from one state to another, then it is still possible to make the transition happen by using a sufficient amount of work. But if we do not have access to this amount of work, can the…

Quantum Physics · Physics 2016-11-02 Álvaro M. Alhambra , Jonathan Oppenheim , Christopher Perry

The optimal efficiency of quantum (or classical) heat engines whose heat baths are $n$-particle systems is given by the information geometry and the strong large deviation. We give the optimal work extraction process as a concrete…

Quantum Physics · Physics 2017-07-19 Hiroyasu Tajima , Masahito Hayashi

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

Enhancing the precision of a thermodynamic process inevitably necessitates a thermodynamic cost. This notion was recently formulated as the thermodynamic uncertainty relation, which states that the lower bound on the relative variance of…

Quantum Physics · Physics 2025-11-14 Yoshihiko Hasegawa

For configurational changes of soft matter systems affected or caused by external hydrodynamic flow, we identify applied work, exchanged heat, and entropy change on the level of a single trajectory. These expressions guarantee invariance of…

Soft Condensed Matter · Physics 2009-01-15 Thomas Speck , Jakob Mehl , Udo Seifert

Active biological systems reside far from equilibrium, dissipating heat even in their steady state, thus requiring an extension of conventional equilibrium thermodynamics and statistical mechanics. In this Letter, we have extended the…

Soft Condensed Matter · Physics 2017-12-22 Dibyendu Mandal , Katherine Klymko , Michael R. DeWeese

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…

General Physics · Physics 2007-05-23 Bin Zhou

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

A few decades after Hill's work on nano-thermodynamics, the development of a thermodynamic framework, to account consistently for the fluctuations of small systems due to their interactions with the surrounding environment, is still…

Statistical Mechanics · Physics 2019-09-23 Salvatore Calabrese , Lamberto Rondoni , Amilcare Porporato

We develop a Lindblad framework for quantum stochastic thermodynamics to study the nonequilibrium thermodynamics of open quantum systems. Our approach adopts the local quantum detailed balance condition, ensuring thermodynamic consistency…

Quantum Physics · Physics 2025-02-28 Jin-Fu Chen