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One of the most promising acceptor precursors for atomic-precision $\delta$-doping of silicon is BCl$_3$. The chemical pathway, and the resulting kinetics, through which BCl$_3$ adsorbs and dissociates on silicon, however, has only been…

Materials Science · Physics 2025-05-14 Quinn T. Campbell , Shashank Misra , Jeffrey A. Ivie

BCl$_3$ is a promising candidate for atomic-precision acceptor doping in Si, but optimizing the electrical properties of structures created with this technique requires a detailed understanding of adsorption and dissociation pathways for…

The adsorption of AlCl$_{3}$ on Si(100) and the effect of annealing the AlCl$_{3}$-dosed substrate was studied to reveal key surface processes for the development of atomic-precision acceptor-doping techniques. This investigation was…

Atomically precise dopant arrays in Si are being pursued for solid-state quantum computing applications. We propose a guided self-assembly process to produce atomically precise arrays of single dopant atoms in lieu of lithographic…

Materials Science · Physics 2022-01-05 Matthew S. Radue , Yifei Mo , R. E. Butera

We report on the structural properties of highly B-doped silicon (> 2 at. %) realised by nanosecond laser doping. We investigate the crystalline quality, deformation and B distribution profile of the doped layer by STEM analysis followed by…

Materials Science · Physics 2023-02-22 G. Hallais , G. Patriarche , L. Desvignes , D. Débarre , F. Chiodi

Boron (B) has the potential for generating an intermediate band in cubic silicon carbide (3C-SiC), turning this material into a highly efficient absorber for single-junction solar cells. The formation of a delocalized band demands high…

In this work, the interaction of n-type dopants in Si doped (AlxGa1-x)2O3 films with varying Al content over the entire composition range (x = 0-100%) was analyzed using atom probe tomography. An almost uniform dopant distribution with…

Applied Physics · Physics 2020-09-04 Jith Sarker , A F M Anhar Uddin Bhuiyan , Zixuan Feng , Hongping Zhao , Baishakhi Mazumder

Recent work on atomic-precision dopant incorporation technologies has led to the creation of both boron and aluminum $\delta$-doped layers in silicon with densities above the solid solubility limit. We use density functional theory to…

Materials Science · Physics 2023-08-23 Quinn T. Campbell , Shashank Misra , Andrew D. Baczewski

We demonstrate the controlled incorporation of P dopant atoms in Si (001) presenting a new path toward the creation of atomic-scale electronic devices. We present a detailed study of the interaction of PH3 with Si (001) and show that it is…

Materials Science · Physics 2009-11-10 S. R. Schofield , N. J. Curson , M. Y. Simmons , F. J. Ruess , T. Hallam , L. Oberbeck , R. G. Clark

As a first step to porting scanning tunneling microscopy methods of atomic-precision fabrication to a strained-Si/SiGe platform, we demonstrate post-growth P atomic-layer doping of SiGe heterostructures. To preserve the substrate structure…

The lack of p-type doping has impeded the development of vertical gallium oxide (Ga2O3) devices. Current blocking layers (CBL) using implanted deep acceptors has been used to demonstrate vertical devices. This paper presents the first…

Superconductivity in ultra-doped $Si_{1-x}Ge_{x}:B$ epilayers is demonstrated by nanosecond laser doping, which allows introducing substitutional B concentrations well above the solubility limit and up to $7\,at.\%$. A Ge fraction $x$…

Superconductivity · Physics 2024-04-04 S. Nath , I. Turan , L. Desvignes , L. Largeau , O. Mauguin , M. Túnica , M. Amato , C. Renard , G. Hallais , D. Débarre , F. Chiodi

(Al,Cr)2O3 coatings with Al/(Al+Cr) = 0.5 or Al = 70 at.%, doped with 0, 5 or 10 at.% Si, were deposited on hard metal and Si(100) substrates to elucidate the influence of Si on the resulting coatings. The chemical analysis of the coatings…

Crystalline Si substrates are doped by laser annealing of solution processed Si. For this experiment, dispersions of highly B-doped Si nanoparticles (NPs) are deposited onto intrinsic Si and laser processed using an 807.5nm cw-laser. During…

Here we develop and characterize high thermal conductivity/high thermal shock resistant bulk Ce doped Al2O3 and propose it as a new phosphor converting capping layer for high-powered/high-brightness solid-state white lighting (SSWL). The…

Applied Physics · Physics 2020-06-24 E. H. Penilla , P. Sellappan , M. A. Duarte , A. T. Wieg , M. Wingert , J. E. Garay

We present molecular dynamics simulations of shallow Al implantation in 4H-SiC to clarify how implantation temperature and dose control defect evolution and dopant activation during early annealing. Using the Gao-Weber potential together…

Materials Science · Physics 2026-04-27 Sabine Leroch , Robert Stella , Andreas Hössinger , Lado Filipovic

Secondary Ions Mass Spectroscopy and Hall effect measurements were performed on boron doped silicon with concentration between 0.02 at.% and 12 at.%. Ultra-high boron doping was made by saturating the chemisorption sites of a Si wafer with…

For the most precise incorporation of single impurities in silicon, which is utilized to create quantum devices, a monolayer of adatoms on the Si(100) surface and a dopant-containing molecule are used. Here we studied the interaction of a…

Materials Science · Physics 2023-11-30 T. V. Pavlova , V. M. Shevlyuga

Black silicon (BSi) is a synthetic nanomaterial with high aspect ratio nano protrusions inducing several interesting properties such as a very large absorptivity of incident radiation. We have recently shown that heavily doping the BSi in…

Mesoscale and Nanoscale Physics · Physics 2022-12-21 Sreyash Sarkar , Elyes Nefzaoui , Georges Hamaoui , Frédéric Marty , Philippe Basset , Tarik Bourouina

The experimental realization of the quantum anomalous Hall (QAH) effect in magnetically-doped (Bi, Sb)2Te3 films stands out as a landmark of modern condensed matter physics. However, ultra-low temperatures down to few tens of mK are needed…

Mesoscale and Nanoscale Physics · Physics 2016-09-12 W. Li , M. Claassen , Cui-Zu Chang , B. Moritz , T. Jia , C. Zhang , S. Rebec , J. J. Lee , M. Hashimoto , D. -H. Lu , R. G. Moore , J. S. Moodera , T. P. Devereaux , Z. -X. Shen
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