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The exponential computational cost of describing strongly correlated electrons can be mitigated by adopting a reduced density-matrix (RDM)-based description of the electronic structure. While variational two-electron RDM (v2RDM) methods can…

Chemical Physics · Physics 2026-01-06 Grier M. Jones , Run. R. Li , A. Eugene DePrince , Konstantinos D. Vogiatzis

Computing excited-state properties of molecules and solids is considered one of the most important near-term applications of quantum computers. While many of the current excited-state quantum algorithms differ in circuit architecture,…

Quantum Physics · Physics 2024-03-19 Carlos L. Benavides-Riveros , Yuchen Wang , Samuel Warren , David A. Mazziotti

Exactly solvable models play an extremely important role in many fields of quantum physics. In this study, the Schr\"{o}dinger equation is applied for a solution of a two--dimensional (2D) problem for two particles interacting via Kratzer,…

Quantum Physics · Physics 2023-11-21 Roman Ya. Kezerashvili , Jianning Luo , Claudio R. Malvino

Classical shadow tomography offers a scalable route to estimating properties of quantum states, but the resulting reduced density matrices (RDMs) often violate constraints that ensure they represent $N$-electron states -- known as…

Efficient simulation of strongly correlated electrons has become a routine tool in molecular electronic structure theory due to recent advances in approximate configuration interaction (CI) techniques. Nonetheless, the quantitative and…

Quantum Physics · Physics 2026-04-06 Daniel Gibney , Anthony W Schlimgen , Jan-Niklas Boyn

Electronic ground states are of central importance in chemical simulations, but have remained beyond the reach of efficient classical algorithms except in cases of weak electron correlation or one-dimensional spatial geometry. We introduce…

Quantum Physics · Physics 2026-02-06 Oskar Leimkuhler , K. Birgitta Whaley

We propose a hybrid quantum-classical eigensolver to address the computational challenges of simulating strongly correlated quantum many-body systems, where the exponential growth of the Hilbert space and extensive entanglement render…

Quantum Physics · Physics 2025-10-23 Lei Xu , Ling Wang

In this paper, a quantum dot mathematical model based on a two-dimensional Schr\"odinger equation assuming the 1/r inter-electronic potential is revisited. Generally, it is argued that the solutions of this model obtained by solving a…

Quantum Physics · Physics 2021-10-19 Francisco Caruso , Vitor Oguri , Felipe Silveira

Accurate computation of multiple eigenvalues of quantum Hamiltonians is essential in quantum chemistry, materials science, and molecular spectroscopy. Estimating excited-state energies is challenging for classical algorithms due to…

Quantum Physics · Physics 2026-05-22 Grzegorz Rajchel-Mieldzioć , Szymon Pliś , Emil Zak

We present an analysis of the two-dimensional Schrodinger equation for two electrons interacting via Coulombic force and confined in an anizotropic harmonic potential. The separable case of wy = 2wx is studied particularly carefully. The…

Quantum Physics · Physics 2017-07-17 Przemyslaw Koscik , Anna Okopinska

While the treatment of chemically relevant systems containing hundreds or even thousands of electrons remains beyond the reach of quantum devices, the development of quantum-classical hybrid algorithms to resolve electronic correlation…

Quantum theory has been remarkably successful in providing an understanding of physical systems at foundational scales. Solving the Schr\"odinger equation provides full knowledge of all dynamical quantities of the physical system. However…

Quantum Physics · Physics 2020-11-24 Cesar Lema , Anna Choromanska

Excited-state properties of highly correlated systems are key to understanding photosynthesis, luminescence, and the development of novel optical materials, but accurately capturing their interactions is computationally costly. We present…

Quantum Physics · Physics 2024-08-21 Irma Avdic , David A. Mazziotti

Quantum computers are promising tools for simulating many-body quantum systems due to their potential scaling advantage over classical computers. While significant effort has been expended on many-fermion systems, here we simulate a model…

Quantum Physics · Physics 2023-07-17 Yuchen Wang , LeeAnn M. Sager-Smith , David A. Mazziotti

The Schr\"odinger equation for two and tree-body problems is solved for scattering states in a hybrid representation where solutions are expanded in the eigenstates of the harmonic oscillator in the interaction region and on a finite…

Computational Physics · Physics 2015-03-19 Yuriy Bidasyuk , Wim Vanroose

Accurately solving the Schr\"odinger equation remains a central challenge in computational physics, chemistry, and materials science. Here, we propose an alternative eigenvalue problem based on a system's autocorrelation function, avoiding…

Quantum Physics · Physics 2025-07-22 Timothy Stroschein , Davide Castaldo , Markus Reiher

We improve the complex scaling method (CSM) to obtain virtual states, which were previously challenging in the conventional CSM. Our approach solves the Schr\"odinger equation in the momentum space as an eigenvalue problem by choosing the…

High Energy Physics - Phenomenology · Physics 2024-02-22 Yan-Ke Chen , Lu Meng , Zi-Yang Lin , Shi-Lin Zhu

We study the exactly solvable quantum system of two particles confined in a three-dimensional harmonic trap and interacting via finite-range soft-core interaction by means of the separation of variables and ansatz method. Supposing the…

Quantum Physics · Physics 2019-06-11 Muhammad Adnan Shahzad

We present an exact ansatz for the eigenstate problem of mixed fermion-boson systems that can be implemented on quantum devices. Based on a generalization of the electronic contracted Schr\"odinger equation (CSE), our approach guides a…

Quantum Physics · Physics 2024-08-26 Samuel Warren , Yuchen Wang , Carlos L. Benavides-Riveros , David A. Mazziotti

In this study, we develop a semi-analytical framework to solve generalized Jaynes-Tavis-Cummings Hamiltonians describing multi-qudit systems coupled via EM resonators. Besides the multi-level generalization we allow for an arbitrary number…

Quantum Physics · Physics 2018-11-27 H. W. L. Naus , R. Versluis