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The nuclear-polarization (NP) energies with the collective model commonly employed in the NP calculations for hydrogenlike heavy ions are found to have serious gauge violations when the ladder and cross diagrams only are taken into account.…

Atomic Physics · Physics 2009-11-07 Yataro Horikawa , Akihiro Haga

We present a new ab initio approach to study molecules containing heavy atoms strongly interacting with quantum fields in optical devices. The theory has been derived from the relativistic quantum electrodynamics (QED) introducing the…

Chemical Physics · Physics 2025-07-03 Guillaume Thiam , Riccardo Rossi , Henrik Koch , Leonardo Belpassi , Enrico Ronca

The energy difference between two iso-electronic systems can be accurately approximated by the alchemical first order Hellmann-Feynmann derivative for the averaged Hamiltonian. This approximation is exact up to third order because…

Chemical Physics · Physics 2025-09-05 O. Anatole von Lilienfeld , Giorgio Domenichini

The authors in their previous papers obtained compact, arbitrarily accurate expressions for two-center one- and two-electron relativistic molecular integrals expressed over Slater-type orbitals. In this present study, the accuracy limits of…

Mathematical Physics · Physics 2015-10-28 A. Bagci , P. E. Hoggan

The quantum electrodynamic theory of the nuclear recoil effect in atoms to all orders in \alpha Z and to first order in m/M is considered. The complete \alpha Z - dependence formulas for the relativistic recoil corrections to the atomic…

Atomic Physics · Physics 2007-05-23 V. M. Shabaev

The general relativistic corrections in the equations of motion and associated energy of a binary system of point-like masses are derived at the third post-Newtonian (3PN) order. The derivation is based on a post-Newtonian expansion of the…

General Relativity and Quantum Cosmology · Physics 2009-12-31 Luc Blanchet , Guillaume Faye

New, gauge-independent, second-order Lagrangian for the motion of classical, charged test particles is used to derive the corresponding Hamiltonian formulation. For this purpose a Hamiltonian description of the theories derived from the…

Classical Physics · Physics 2009-10-31 D. Chruscinski , J. Kijowski

A fundamental issue in classical electrodynamics is represented by the search of the exact equation of motion for a classical charged particle under the action of its electromagnetic (EM) self-field - the so-called radiation-reaction…

Classical Physics · Physics 2008-09-22 M. Tessarotto , C. Cremaschini , M. Dorigo

The static dipole polarizability for the hydrogen molecular ions H$_2^+$, HD$^+$, and D$_2^+$ are calculated. These new data for polarizability takes into account the leading order relativistic corrections to the wave function of the…

Atomic Physics · Physics 2017-02-01 D. T. Aznabayev , A. K Bekbaev , S. A. Zhaugasheva , V. I. Korobov

The article deals with the extension of the relativistic double-ionization equation-of-motion coupled-cluster (DI-EOMCC) method [H. Pathak et al. Phys. Rev. A 90, 010501(R) (2014)] for the molecular systems. The Dirac-Coulomb (DC)…

Chemical Physics · Physics 2020-04-22 Himadri Pathak , Sudip Sasmal , Kaushik Talukdar , Malaya K. Nayak , Nayana Vaval , Sourav Pal

The new manifestation of conformal invariance for a massless scalar particle in a Riemannian spacetime of general relativity is found. Conformal transformations conserve the Hamiltonian and wave function in the Foldy-Wouthuysen…

Mathematical Physics · Physics 2013-08-07 Alexander J. Silenko

The adaptive perturbation chooses a non-standard decomposition. The Hamiltonian becomes a sum of solvable and perturbation parts. We calculate the spectrum using the adaptive perturbation method at the leading-order to compare to numerical…

Quantum Physics · Physics 2021-07-08 Chen-Te Ma

The ambiguity involved in the definition of effective-mass Hamiltonians for nonrelativistic models is resolved using the Dirac equation. The multistep approximation is extended for relativistic cases allowing the treatment of arbitrary…

Condensed Matter · Physics 2009-10-31 R. Renan , M. H. Pacheco , C. A. S. Almeida

We implement a full nonlinear optimization method to fit continuum states with complex Gaussians. The application to a set of regular scattering Coulomb functions allows us to validate the numerical feasibility, to explore the range of…

Computational Physics · Physics 2020-08-28 Abdallah Ammar , Arnaud Leclerc , Lorenzo Ugo Ancarani

Scalar relativistic corrections to atomization energies of 1st-and 2nd-row molecules can be rationalized in terms of a simple additive model, linear in changes in atomic s populations. In a sample of 200 first-and second-row molecules, such…

Chemical Physics · Physics 2018-08-13 Jan M. L. Martin , Nitai Sylvetsky

A large collaboration carefully benchmarks 20 first principles many-body electronic structure methods on a test set of 7 transition metal atoms, and their ions and monoxides. Good agreement is attained between the 3 systematically converged…

We compute from chiral two- and three-nucleon interactions the energy per particle of symmetric nuclear matter and pure neutron matter at third-order in perturbation theory including self-consistent second-order single-particle energies.…

Nuclear Theory · Physics 2017-04-05 J. W. Holt , N. Kaiser

The nonrelativistic energy of low lying rovibrational levels of HT, DT, and \T\ is determined to an absolute accuracy of $10^{-7}-10^{-8}$ cm$^{-1}$ using the variational method with the four-body nonadiabatic James-Coolidge functions. The…

Chemical Physics · Physics 2023-01-11 Krzysztof Pachucki , Jacek Komasa

A simple locally accurate uniform approximation for the nodeless wavefunction is constructed for a {\it neutral} system of two Coulomb charges of different masses $(-q,m_1)$ and $(q,m_2)$ at rest in a constant uniform magnetic field for the…

Quantum Physics · Physics 2022-04-20 J. C. del Valle , A. V. Turbiner , Adrian M Escobar Ruiz

We present a coordinate-free approach for constructing approximate first integrals of generalized slow-fast Hamiltonian systems, based on the global averaging method on parameter-dependent phase spaces with $\mathbb{S}^1 -$symmetry.…

Dynamical Systems · Mathematics 2014-05-06 M. Avendaño-Camacho , J. A. Vallejo , Yu. Vorobiev
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