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Thermal properties of graphene monolayers are studied by path-integral molecular dynamics (PIMD) simulations, which take into account the quantization of vibrational modes in the crystalline membrane, and allow one to consider anharmonic…

Materials Science · Physics 2017-09-18 Carlos P. Herrero , Rafael Ramirez

We propose a feasible and effective approach to study quantum thermal transport through anharmonic systems. The main idea is to obtain an {\it effective} harmonic Hamiltonian for the anharmonic system by applying the self-consistent phonon…

Statistical Mechanics · Physics 2016-10-19 Dahai He , Juzar Thingna , Jian-Sheng Wang , Baowen Li

Bosonic quantum devices, which utilize harmonic oscillator modes to encode information, are emerging as a promising alternative to conventional qubit-based quantum devices, especially for the simulation of vibrational dynamics and…

Quantum Physics · Physics 2025-02-18 Shreyas Malpathak , Sangeeth Das Kallullathil , Artur F. Izmaylov

We here introduce a Fortran code that computes anharmonic free energy of solids from first-principles based on our phonon quasiparticle approach. In this code, phonon quasiparticle properties, i.e., renormalized phonon frequencies and…

Materials Science · Physics 2019-06-19 Zhen Zhang , Dong-Bo Zhang , Tao Sun , Renata Wentzcovitch

The underlying dielectric properties of materials, intertwined with intriguing phenomena such as topological polariton modes and anisotropic thermal conductivities, stem from the anisotropy in atomic vibrations. Conventionally, X-ray…

The occurrence of thermal transport phenomena is widespread, exerting a pivotal influence on the functionality of diverse electronic and thermo-electric energy-conversion devices. The traditional first-principles theory governing the…

Materials Science · Physics 2026-05-20 Soham Mandal , Manish Jain , Prabal K. Maiti

We report the first successful application of the {\it ab initio} quantum Monte Carlo (QMC) framework to a phonon dispersion calculation. A full phonon dispersion of diamond is successfully calculated at the variational Monte Carlo (VMC)…

Materials Science · Physics 2021-04-14 Kousuke Nakano , Tommaso Morresi , Michele Casula , Ryo Maezono , Sandro Sorella

The detailed characterization of non-trivial coherence properties of composite quantum systems of increasing size is an indispensable prerequisite for scalable quantum computation, as well as for understanding of nonequilibrium many-body…

On the basis of the self-consistent phonon theory and the special displacement method, we develop an approach for the treatment of anharmonicity in solids. We show that this approach enables the efficient calculation of…

Materials Science · Physics 2023-08-09 Marios Zacharias , George Volonakis , Feliciano Giustino , Jacky Even

We present a perturbative method for calculating phonon properties of an insulator in the presence of a finite electric field. The starting point is a variational total-energy functional with a field-coupling term that represents the effect…

Materials Science · Physics 2009-12-17 Xinjie Wang , David Vanderbilt

We expand iterative numerically-exact influence functional path-integral tools and present a method capable of following the nonequilibrium time evolution of subsystems coupled to multiple bosonic and fermionic reservoirs simultaneously.…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Lena Simine , Dvira Segal

Including quantum mechanical effects on the dynamics of nuclei in the condensed phase is challenging, because the complexity of exact methods grows exponentially with the number of quantum degrees of freedom. Efforts to circumvent these…

Chemical Physics · Physics 2015-06-23 Mariana Rossi , Hanchao Liu , Francesco Paesani , Joel Bowman , Michele Ceriotti

We have developed a computational code, DynaPhoPy, that allow us to extract the microscopic anharmonic phonon properties from molecular dynamics (MD) simulations using the normal-mode-decomposition technique as presented by Sun et al. [T.…

Materials Science · Physics 2024-08-27 Abel Carreras , Atsushi Togo , Isao Tanaka

Interfacial thermal transport is critical for many thermal-related applications such as heat dissipation in electronics. While the total interfacial thermal conductance (ITC) can be easily measured or calculated, the ITC spectral mapping…

Materials Science · Physics 2022-10-26 Yixin Xu , Lina Yang , Yanguang Zhou

Vibrational dynamics governs the fundamental properties of molecular crystals, shaping their thermodynamics, mechanics, spectroscopy, and transport phenomena. However desirable, the first-principles calculation of solid-state vibrations,…

Materials Science · Physics 2025-03-25 Lorenzo Soprani , Andrea Giunchi , Marco Bardini , Quintin N. Meier , Gabriele D'Avino

Phononic properties are commonly studied by calculating force constants using the density functional theory (DFT) simulations. Although DFT simulations offer accurate estimations of phonon dispersion relations or thermal properties, but for…

We present an analysis of the vibrational dynamics of metal vicinal surfaces using the embedded atom method to describe the interaction potential and both a real space Green's function method and a slab method to calculate the phonons. We…

Materials Science · Physics 2016-08-31 Abdelkader Kara , Talat S. Rahman

Anharmonic potential quantum system play crucial role in physics as they provide a more realistic description of oscillatory phenomena, which often deviate from the idealized harmonic model. However, simulating such system on classical…

Quantum Physics · Physics 2025-10-08 Saurav Suman , Bikash K. Behera , Vivek Vyas , Prasanta k. Panigrahi

Bosonic exchange symmetry leads to fascinating quantum phenomena, from exciton condensation in quantum materials to the superfluidity of liquid Helium-4. Unfortunately, path integral molecular dynamics (PIMD) simulations of bosons are…

Computational Physics · Physics 2025-02-18 Yotam M. Y. Feldman , Barak Hirshberg

Convergence of path integral simulations requires a substantial number of beads when quantum effects are significant. Traditional Trotter scaling approaches estimate the continuum limit through extrapolation, however they are restricted to…

Statistical Mechanics · Physics 2024-05-28 Sabry G Moustafa