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A new mathematical representation for nonlinear viscoelasticity is presented based on application of the Volterra series expansion to the general nonlinear relationship between shear stress and shear strain history. This theoretical and…

Soft Condensed Matter · Physics 2022-02-11 Kyle R. Lennon , Gareth H. McKinley , James W. Swan

The weakly nonlinear rheology of a surfactant solution of wormlike micelles is investigated from both a modeling and experimental perspective using the framework of medium amplitude parallel superposition (MAPS) rheology. MAPS rheology…

Soft Condensed Matter · Physics 2022-02-10 Kyle R. Lennon , Gareth H. McKinley , James W. Swan

We derive new analytical solutions for the non-affine Johnson-Segalman/Gordon-Schowalter (JS/GS) constitutive equation with a general relaxation kernel in medium-amplitude oscillatory shear (MAOS) deformation. The results show time-strain…

Soft Condensed Matter · Physics 2020-12-02 Nabil Ramlawi , N. Ashwin Bharadwaj , Randy H. Ewoldt

We introduce a nonlinear generalized tensorial Maxwell-type constitutive equation to describe shear-thinning glass-forming fluids, motivated by a recent microscopic approach to the nonlinear rheology of colloidal suspensions. The model…

Soft Condensed Matter · Physics 2015-06-17 Simon Papenkort , Thomas Voigtmann

Rheological properties, especially 'shear-thinning', of dense colloidal dispersions are discussed on three different levels. A generalized phenomonological Maxwell model gives a broad framework connecting glassy dynamics to the linear and…

Soft Condensed Matter · Physics 2007-05-23 Matthias Fuchs , Matthias Ballauff

We introduce a general decomposition of the stress tensor for incompressible fluids in terms of its components on a tensorial basis adapted to the local flow conditions, which include extensional flows, simple shear flows, and any type of…

Fluid Dynamics · Physics 2018-04-30 Giulio G. Giusteri , Ryohei Seto

In this work we discuss possible physical origins for non-trivial exponents in the athermal rheology of soft materials at low but finite driving rates. A key ingredient in our scenario is the presence of a self-consistent mechanical noise…

Soft Condensed Matter · Physics 2017-07-06 Elisabeth Agoritsas , Kirsten Martens

Medium or large amplitude oscillatory shear (M/LAOS) is sensitive to polymer chain structure, yet poses unsolved challenges for 'a priori' structural characterisation. In this letter, we present a MAOS protocol applied to near-monodisperse…

Soft Condensed Matter · Physics 2020-09-30 Carl D. Reynolds , David M. Hoyle , Richard L. Thompson , Tom C. B. McLeish

We recently developed a tensorial constitutive model for dense, shear-thickening particle suspensions that combines rate-independent microstructural evolution with a stress-dependent jamming threshold. This gives a good qualitative account…

Fluid Dynamics · Physics 2020-07-14 Jurriaan Gillissen , Christopher Ness , Joseph Peterson , Helen Wilson , Michael Cates

This paper develops a trace-regular variational framework for time-harmonic Maxwell scattering problems involving pointwise nonlinear boundary and interface responses. We investigate three canonical classes of models: nonlinear impedance,…

Analysis of PDEs · Mathematics 2026-05-26 Chao Deng , Yixian Gao

Using mode-coupling theory, we derive a constitutive equation for the nonlinear rheology of dense colloidal suspensions under arbitrary time-dependent homogeneous flow. Generalizing previous results for simple shear, this allows the full…

Soft Condensed Matter · Physics 2009-11-13 J. M. Brader , M. E. Cates , M. Fuchs

The frequency dependence of third-harmonic medium amplitude oscillatory shear (MAOS) modulus $G_{33}^{*}(\omega)$ provides insight into material behavior and microstructure in the asymptotically nonlinear regime. Motivated by the difficulty…

Soft Condensed Matter · Physics 2022-08-31 Sachin Shanbhag , Yogesh M. Joshi

Large Amplitude Oscillatory Shear (LAOS) is a key technique for characterizing nonlinear viscoelasticity in a wide range of materials. Most research to date has focused on the shear stress response to an oscillatory strain input. However,…

Soft Condensed Matter · Physics 2026-04-14 Nicholas King , Eugene Pashkovski , Reid Patterson , Paige Rockwell , Gareth H. McKinley

We derive from particle-level dynamics a constitutive model describing the rheology of two-dimensional dense soft suspensions below the jamming transition, in a regime where hydrodynamic interactions between particles are screened. Based on…

Soft Condensed Matter · Physics 2026-01-08 N. Cuny , E. Bertin , R. Mari

We have measured the nonlinear rheological response of a model transient network over a large range of steady shear rates. The system is built up from an oil in water droplet microemulsion into which a telechelic polymer is incorporated.…

Soft Condensed Matter · Physics 2009-11-10 Eric Michel , Jacqueline Appell , Francois Molino , Jean Kieffer , Gregoire Porte

Nonlinearities in constitutive equations of extended objects in shear flow lead to novel phenomena, {\it e.g.} "rheochaos" in solutions of wormlike micelles and "elastic turbulence" in polymer solutions. Since both phenomena involve…

Soft Condensed Matter · Physics 2019-08-20 Rituparno Mandal , Buddhapriya Chakrabarti , Debarshini Chakraborti , Chandan Dasgupta

Mathematical models of biological populations commonly use discrete structure classes to capture trait variation among individuals (e.g. age, size, phenotype, intracellular state). Upscaling these discrete models into continuum descriptions…

Populations and Evolution · Quantitative Biology 2026-03-18 Eleonora Agostinelli , Keith L. Chambers , Helen M. Byrne , Mohit P. Dalwadi

In this work we present a generalised viscoelastic model using distributed-order derivatives. The model consists of two distributed-order elements (distributed springpots) connected in series, as in the Maxwell model. The new model…

Classical Physics · Physics 2022-12-28 Luis Ferrás , Maria Luisa Morgado , Magda Rebelo

This paper explores a class of non-linear constitutive relations for materials with memory in the framework of covariant macroscopic Maxwell theory. Based on earlier models for the response of hysteretic ferromagnetic materials to…

Mathematical Physics · Physics 2014-02-04 Alison C. Hale , Robin W. Tucker

The original Maxwell visco-elastic constitutive model cannot predict the correct mechanical properties for most fluids. In this work, the model is generalized with respect to wave-vector and extended with a correction function. This new…

Soft Condensed Matter · Physics 2024-01-25 Jesper Schmidt Hansen
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