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We introduce the use of superchiral surface waves for the all-optical separation of chiral compounds. Using a combination of electrodynamics modeling and analytical techniques, we show that the proposed approach provides chiral optical…

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

Chemical Physics · Physics 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

Inspired by a sea creature, we identify a robust chiral optical force that pushes the opposite enantiomers of a chiral molecule towards regions of orthogonal linear polarization in an optical field via electric dipole interactions. Our…

Efficient chirality sorting is now highly demanded to separate assembled mesoscopic chiral structures which are of very special physical properties rather than their achiral counterparts or those at the single-particle level. However, the…

Soft Condensed Matter · Physics 2019-07-03 Jie Su , Huijun Jiang , Zhonghuai Hou

We report on the first experimental demonstration of enantioselective rotational control of chiral molecules with a laser field. In our experiments, two enantiomers of propylene oxide are brought to accelerated unidirectional rotation by…

Versatile manipulation of nano- and microobjects underlies the optomechanics and a variety of its applications in biology, medicine, and lab-on-a-chip platforms. For flexible tailoring optical forces, as well as for extraordinary…

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

We propose a theoretical method for enantio-discrimination based on the light deflection effect in four-level models of chiral molecules. This four-level model consists of a cyclic three-level subsystem coupled by three strong driving…

Optics · Physics 2020-08-12 Yu-Yuan Chen , Chong Ye , Quansheng Zhang , Yong Li

Enantiodetection of chiral molecules is important to pharmaceutical drug production, chemical reaction control, and biological function designs. Traditional optical methods of enantiodetection rely on the weak magnetic-dipole or…

Chemical Physics · Physics 2022-09-14 Mao-Rui Cai , Chong Ye , Hui Dong , Yong Li

Controlling scattering and routing of chiral light at the nanoscale is important for optical information processing and imaging, quantum technologies as well as optical manipulation. Here, we introduce a concept of rotating chiral dipoles…

Optics · Physics 2025-09-25 Yuanyang Xie , Alexey V. Krasavin , Diane J. Roth , Anatoly V. Zayats

The practical applications of chiral discrimination are usually limited by the weak chiral response of enantiomers and the high complexity of detection methods. Here, we propose to use the C lines (i.e., lines of polarization singularities)…

Optics · Physics 2022-03-22 Shiqi Jia , Jie Peng , Yuqiong Cheng , Shubo Wang

Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…

Sorting of microswimmers based on their mobility properties is of utmost importance for various branches of science and engineering. In this paper, we proposed a novel sorting method, where the mixed chiral particles can be separated by…

Soft Condensed Matter · Physics 2016-12-28 Qun Chen , Bao-quan Ai

We propose a novel high resolution microscopy technique for enantio-specific detection of chiral samples down to sub-100 nm size, based on force measurement. We delve into the differential photo-induced optical force exerted on an achiral…

Detecting and controlling the chirality of materials play an essential role in exploring nature, providing new avenues for material creation, discrimination, and manipulation. In such tasks, chiral reagents are essential in defining or…

Optical forces can be chiral when they exhibit opposite signs for the two enantiomeric versions of a chiral molecule or particle. Such forces could be eventually used to separate enantiomers, which could find application in numerous…

We report for the first time the theory of optical tweezers of spherical dielectric particles embedded in a chiral medium. We develop a partial-wave (Mie) expansion to calculate the optical force acting on a dielectric microsphere…

Optics · Physics 2020-09-28 Rfaqat Ali , R. S. Dutra , F. A. Pinheiro , F. S. S. Rosa , P. A. Maia Neto

Synthetic chiral light enables ultrafast and highly efficient imaging of molecular chirality. Unlike standard circularly polarized light, the handedness of synthetic chiral light does not rely on the spatial structure of the light field: it…

Optics · Physics 2022-06-06 Laura Rego , David Ayuso

We discuss how tensorial observables, available in photoelectron angular distributions resulting from interaction between isotropic chiral samples and cross polarized $\omega$-$2\omega$ bichromatic fields, allow for chiral discrimination…

Atomic Physics · Physics 2022-06-28 Andres F. Ordonez , Olga Smirnova

Controlling the polarization state of electromagnetic radiation enables the investigation of fundamental symmetry properties of matter through chiroptical processes. Many strategies have been developed to reveal structural or dynamical…