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We study the combination of orbital-optimized density cumulant theory and a new parameterization of the reduced density matrices in which the variables are the particle-hole cumulant elements. We call this combination O$\lambda$DCT. We find…

Chemical Physics · Physics 2022-01-12 Jonathon P. Misiewicz , Justin M. Turney , Henry F. Schaefer

Starting from renormalised Effective Lagrangian, in the presence of an external Chromo-Electric field at finite temperature, the expression for thermal coupling constant ($\alpha = (g^2)/(4 \pi)$) as a function of temperature and external…

High Energy Physics - Theory · Physics 2007-05-23 Avijit K. Ganguly

We investigate a novel approach to approximate tensor-network contraction via the exact, matrix-free decomposition of full tensor-networks. We study this method as a means to eliminate the propagation of error in the approximation of…

Chemical Physics · Physics 2025-06-23 Karl Pierce

The problem of precise evaluation of perturbative QCD predictions at moderate energies is addressed. In order to improve stability of the predictions with respect to change of the renormalization scheme it is proposed to replace the…

High Energy Physics - Phenomenology · Physics 2007-05-23 Piotr A. Raczka

Recent disagreement between state-of-the-art quantum chemical methods, coupled cluster with single, double and perturbative triples excitations and fixed-node diffusion Monte Carlo, calls for systematic examination of possible sources of…

Chemical Physics · Physics 2025-05-14 S. Lambie , C. Rickert , D. Usvyat , A. Alavi , D. Kats

Basis set convergence of correlation effects on molecular atomization energies beyond the CCSD (coupled cluster with singles and doubles) approximation has been studied near the one-particle basis set limit. Quasiperturbative connected…

Chemical Physics · Physics 2008-08-17 Amir Karton , Peter R. Taylor , Jan M. L. Martin

We propose to use wavefunction overlaps obtained from a quantum computer as inputs for the classical split-amplitude techniques, tailored and externally corrected coupled cluster, to achieve balanced treatment of static and dynamic…

We discuss diagrammatic modifications to the coupled cluster doubles (CCD) equations, wherein different groups of terms out of rings, ladders, crossed-rings and mosaics can be removed to form approximations to the coupled cluster method, of…

Chemical Physics · Physics 2014-05-06 James J. Shepherd , Thomas. M. Henderson , Gustavo E. Scuseria

We develop a cubic scaling approach to excited-state-specific second order perturbation theory in which the completeness of a local correlation treatment is carefully matched between the ground and excited state. With this matching, the…

Chemical Physics · Physics 2025-05-14 Rachel Clune , Eric Neuscamman

An exact renormalization group equation is derived for the free energy of matrix models. The renormalization group equation turns out to be nonlinear for matrix models, as opposed to linear for vector models. An algorithm for determining…

High Energy Physics - Theory · Physics 2009-10-22 Saburo Higuchi , Chigak Itoi , Shinsuke Nishigaki , Norisuke Sakai

The $\Delta \text{NO}$ method for static correlation is combined with second-order M{\o}ller-Plesset perturbation theory (MP2) and coupled-cluster singles and doubles (CCSD) to account for dynamic correlation. The MP2 and CCSD expressions…

Chemical Physics · Physics 2020-06-05 Joshua W. Hollett , Pierre-François Loos

Approximate full configuration interaction (FCI) calculations have recently become tractable for systems of unforeseen size thanks to stochastic and adaptive approximations to the exponentially scaling FCI problem. The result of an FCI…

Strongly Correlated Electrons · Physics 2017-10-25 Susi Lehtola , Norm M. Tubman , K. Birgitta Whaley , Martin Head-Gordon

An implementation of the coupled-cluster single- and double excitations (CCSD) method on two-dimensional quantum dots is presented. Advantages and limitations are studied through comparison with other high accuracy approaches for two to…

Mesoscale and Nanoscale Physics · Physics 2013-05-30 Erik Waltersson , Eva Lindroth

We present a self-consistent approach for computing the correlated quasiparticle spectrum of charged excitations in iterative $\mathcal{O}[N^5]$ computational time. This is based on the auxiliary second-order Green's function approach [O.…

Chemical Physics · Physics 2020-10-05 Oliver J. Backhouse , George H. Booth

We present the quantum-selected configuration interaction-tailored coupled-cluster (QSCI-TCC) method, a hybrid quantum-classical scheme that tailors coupled-cluster (CC) theory with a quantum-selected configuration interaction (QSCI) wave…

Chemical Physics · Physics 2025-06-23 Luca Erhart , Yuichiro Yoshida , Wataru Mizukami

We explore the use of exact diagonalization methods for solving the self consistent equations of the cellular dynamical mean field theory (CDMFT) for the one dimensional regular and extended Hubbard models. We investigate the nature of the…

Strongly Correlated Electrons · Physics 2007-05-23 C. J. Bolech , S. S. Kancharla , G. Kotliar

The accurate and efficient description of strongly correlated systems remains an important challenge for computational methods. Doubly occupied configuration interaction (DOCI), in which all electrons are paired and no correlations which…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Gustavo E. Scuseria

We perform density matrix renormalization group (DMRG) calculations extensively on one-dimensional chains with on site (U) as well as nearest neighbour (V) Coulomb repulsions. The calculations are carried out in full parameter space with…

Strongly Correlated Electrons · Physics 2009-11-13 Sudipta Dutta , Swapan K. Pati

We extend the active space decomposition method, recently developed by us, to more than two active sites using the density matrix renormalization group algorithm. The fragment wave functions are described by complete or restricted…

Chemical Physics · Physics 2014-12-09 Shane M. Parker , Toru Shiozaki

The polarizable embedding (PE) approach is a flexible embedding model where a pre-selected region out of a larger system is described quantum mechanically while the interaction with the surrounding environment is modeled through an…

Chemical Physics · Physics 2017-01-24 Erik D. Hedegård , Markus Reiher