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A binary colloidal mixture of unequal sizes, subjected to an external potential barrier, has been investigated using canonical ensemble molecular dynamics simulations. The attractive depletion interaction between the external barrier and…

Soft Condensed Matter · Physics 2022-03-11 Mahammad Mustakim , A. V. Anil Kumar

Integral equation theory calculations within the mean spherical approximation (MSA) and grand canonical Monte Carlo (MC) simulations are employed to study the phase behaviour of a symmetrical binary fluid mixture in the presence of a field…

Statistical Mechanics · Physics 2009-11-11 Juergen Koefinger , Gerhard Kahl , Nigel B. Wilding

Mixed-order phase transitions display a discontinuity in the order parameter like first-order transitions yet feature critical behavior like second-order transitions. Such transitions have been predicted for a broad range of equilibrium and…

Statistical Mechanics · Physics 2017-12-07 Ricard Alert , Pietro Tierno , Jaume Casademunt

We study spinodal phase separation in unstable thin liquid films on chemically disordered substrates via simulations of the thin-film equation. The disorder is characterized by immobile patches of varying size and Hamaker constant. The…

Soft Condensed Matter · Physics 2019-03-27 Manish Vashishtha , Prabhat K. Jaiswal , Rajesh Khanna , Sanjay Puri , Ashutosh Sharma

We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations…

Statistical Mechanics · Physics 2015-03-19 Richard L. C. Vink , A. J. Archer

We apply a modified mean-field density functional theory to determine the phase behavior of binary mixtures of Stockmayer fluids whose spherical constituents interact according to Lennard-Jones (LJ) pair potentials with embedded pointlike…

Soft Condensed Matter · Physics 2009-11-11 I. Szalai , S. Dietrich

We study the thermodynamic behavior of nonpolar liquid mixtures in the vicinity of curved charged objects, such as electrodes or charged colloids. For small enough charge on the object, or equivalently, small potential, the…

Statistical Mechanics · Physics 2009-11-13 Gilad Marcus , Sela Samin , Yoav Tsori

A relativistic mean-field model of nuclear matter with arbitrary proton fraction is studied at finite temperature. An analysis is performed of the liquid-gas phase transition in a system with two conserved charges (baryon number and…

Nuclear Theory · Physics 2008-11-26 Horst Mueller , Brian D. Serot

In this paper we present a mathematical model to describe the phenomenon of phase separation, which is modelled as space regions where an order parameter changes smoothly. The model proposed, including thermal and mixing effects, is deduced…

Mathematical Physics · Physics 2011-02-08 Alessia Berti , Ivana Bochicchio

Phase transformations can be difficult to characterize at the microscopic level due to the inability to directly observe individual atomic motions. Model colloidal systems, by contrast, permit the direct observation of individual particle…

Soft Condensed Matter · Physics 2015-04-21 Ye Yang , Lin Fu , Catherine Marcoux , Joshua E. S. Socolar , Patrick Charbonneau , Benjamin B. Yellen

The dynamics of first-order phase transitions in strongly coupled systems are relevant in a variety of systems, from heavy ion collisions to the early universe. Holographic theories can be used to model these systems, with fluctuations…

High Energy Physics - Theory · Physics 2024-06-24 Alessio Caddeo , Oscar Henriksson , Carlos Hoyos , Mikel Sanchez-Garitaonandia

Binary mixtures are known to phase separate via both nucleation and spinodal decomposition, depending on the initial composition and extent of the quench. Here we develop an energy landscape view of phase separation and non-ideality in…

Statistical Mechanics · Physics 2010-12-22 Sarmistha Sarkar , Biman Bagchi

The Cahn--Hilliard equation is a classic model of phase separation in binary mixtures that exhibits spontaneous coarsening of the phases. We study the Cahn--Hilliard equation with an imposed advection term in order to model the stirring and…

Analysis of PDEs · Mathematics 2022-07-20 Yu Feng , Yuanyuan Feng , Gautam Iyer , Jean-Luc Thiffeault

2-TIPS (Two Temperature induced phase separation) refers to the phase separation phenomenon observed in mixtures of active and passive particles which are modelled using scalar activity. The active particles are connected to a thermostat at…

Soft Condensed Matter · Physics 2023-11-07 Nayana Venkatareddy , Jaydeep Mandal , Prabal K. Maiti

We investigate how the dynamics of a single chain influences the kinetics of early stage phase separation in a symmetric binary polymer mixture. We consider quenches from the disordered phase into the region of spinodal instability. On a…

Statistical Mechanics · Physics 2009-11-07 E. Reister , M. Mueller , K. Binder

Fluid polyamorphism is the existence of multiple fluid-fluid phase transitions in a single-component substance. It can occur due to interconversion between two alternative molecular or supramolecular states. In this work, we investigate a…

Soft Condensed Matter · Physics 2025-03-18 Mikhail A. Anisimov , Sergey V. Buldyrev , Frédéric Caupin , Thomas J. Longo

An electric-field-induced phase transition and pattern formation in a binary dielectric fluid layer are studied using a coarse-grained free energy functional. The electrostatic part of the free energy is a nonlinear functional of the…

Soft Condensed Matter · Physics 2007-05-23 M. D. Johnson , X. Duan , Brett Riley , Aniket Bhattacharya , Weili Luo

Quasiparticle properties are explored in an effective theory of the $t-J$ model which includes two important components: spin-charge separation and unrenormalizable phase shift. We show that the phase shift effect indeed causes the system…

Strongly Correlated Electrons · Physics 2009-10-31 Z. Y. Weng , D. N. Sheng , C. S. Ting

We consider two different collective spin systems subjected to strong dissipation -- on the same scale as interaction strengths and external fields -- and show that either continuous or discontinuous dissipative quantum phase transitions…

Quantum Physics · Physics 2008-09-23 S. Morrison , A. S. Parkins

We examine the symmetry-breaking effect of fixed constellations of particles on the surface-directed spinodal decomposition of binary blends in the presence of particles whose surfaces have a preferential affinity for one of the components.…

Chemical Physics · Physics 2020-06-16 Supriyo Ghosh , Arnab Mukherjee , Raymundo Arroyave , Jack F. Douglas