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Non-bonded potentials are included in most force fields and therefore widely used in classical molecular dynamics simulations of materials and interfacial phenomena. It is commonplace to truncate these potentials for computational…

Computational Physics · Physics 2017-10-04 Martin Fitzner , Laurent Joly , Ming Ma , Gabriele C Sosso , Andrea Zen , Angelos Michaelides

Electrodynamical coupled cluster (CC) methodologies have been formulated employing standard QED Hamiltonian that is written in Coulomb gauge while using the DF and the MCDF pictures of the matter field for closed-shell and open-shell cases…

Quantum Physics · Physics 2024-01-15 Sambhu N. Datta

Addressing both dynamic and static correlation accurately is a primary goal in electronic structure theory. Non-orthogonal configuration interaction (NOCI) is a versatile tool for treating static correlation, offering chemical insights by…

Chemical Physics · Physics 2025-06-27 Chong Sun , Fei Gao , Gustavo E. Scuseria

Ensuring that predicted probabilities align with observed frequencies is critical in high-stakes domains such as clinical decision support, autonomous driving and financial risk assessment. Existing calibration methods typically apply a…

Machine Learning · Computer Science 2026-05-26 Tomer Lavi , Bracha Shapira , Nadav Rappoport

For noncovalent interactions (NCIs), the CCSD(T) coupled cluster method is widely regarded as the `gold standard'. With localized orbital approximations, benchmarks for ever larger NCI complexes are being published; yet tantalizing evidence…

Chemical Physics · Physics 2025-03-13 Vladimir Fishman , Michał Lesiuk , Jan M. L. Martin , A. Daniel Boese

Stepped-wedge cluster randomised trials (SW-CRTs) increasingly evaluate complex interventions, yet methodological guidance for analysing composite endpoints using generalized pairwise comparisons (GPC)remains limited. This work investigates…

A unitary coupled-cluster (UCC)-based self-consistent electron propagator theory (EPT) is proposed for the description of electron-detached and electron-attached states. Two practical schemes, termed IP/EA-UCC3 and IP/EA-qUCCSD, are…

Chemical Physics · Physics 2026-03-03 Yu Zhang , Junzi Liu

We derive coupled-cluster equations for three-body Hamiltonians. The equations for the one- and two-body cluster amplitudes are presented in a factorized form that leads to an efficient numerical implementation. We employ low-momentum two-…

Nuclear Theory · Physics 2008-11-26 G. Hagen , T. Papenbrock , D. J. Dean , A. Schwenk , A. Nogga , M. Wloch , P. Piecuch

Density functional theory (DFT)-based simulations of materials have first-principles accuracy, but are very computationally expensive. For simulating various properties of multi-component alloys, the cluster expansion (CE) technique has…

Materials Science · Physics 2026-04-01 Jacob Jeffries , Bochuan Sun , Enrique Martinez

Query clustering organizes queries into groups that reflect shared latent capability demands, enabling capability-aware LLM evaluation. Existing clustering methods, which primarily rely on semantic taxonomies or embeddings, often fail to…

Artificial Intelligence · Computer Science 2026-05-19 Fangzhou Wu , Sandeep Silwal , Qiuyi Zhang

The Atomic Cluster Expansion (ACE) (Drautz, Phys. Rev. B 99, 2019) has been widely applied in high energy physics, quantum mechanics and atomistic modeling to construct many-body interaction models respecting physical symmetries.…

Numerical Analysis · Mathematics 2024-01-08 Cheuk Hin Ho , Timon S. Gutleb , Christoph Ortner

Immense interest in quantum computing has prompted development of electronic structure methods that are suitable for quantum hardware. However, the slow pace at which quantum hardware progresses, forces researchers to implement their ideas…

Quantum Physics · Physics 2025-02-26 Ilya G. Ryabinkin , Seyyed Mehdi Hosseini Jenab , Scott N. Genin

We introduce single and double particle-hole excitations in the recently revived spin-projected Hartree-Fock. Our motivation is to treat static correlation with spin-projection and recover the residual correlation, mostly dynamic in nature,…

Chemical Physics · Physics 2016-01-20 Takashi Tsuchimochi , Seiichiro Ten-no

Canonical Correlation Analysis (CCA) is a linear representation learning method that seeks maximally correlated variables in multi-view data. Non-linear CCA extends this notion to a broader family of transformations, which are more powerful…

Machine Learning · Computer Science 2020-02-11 Amichai Painsky , Meir Feder , Naftali Tishby

The development of multireference coupled cluster (MRCC) techniques has remained an open area of study in electronic structure theory for decades due to the inherent complexity of expressing a multi-configurational wavefunction in the…

Chemical Physics · Physics 2023-05-24 Maria-Andreea Filip , Alex J. W. Thom

The error-pattern correcting code (EPCC) is incorporated in the design of a turbo equalizer (TE) with aim to correct dominant error events of the inter-symbol interference (ISI) channel at the output of its matching Viterbi detector. By…

Information Theory · Computer Science 2015-03-13 Hakim Alhussien , Jaekyun Moon

Projected Hartree-Fock theory provides an accurate description of many kinds of strong correlations but does not properly describe weakly-correlated systems. On the other hand, single-reference methods such as configuration interaction or…

Strongly Correlated Electrons · Physics 2022-04-06 Ruiheng Song , Thomas M. Henderson , Gustavo E. Scuseria

In this paper, we develop a class of antisymmetrized geminal power configuration interaction (AGP-CI) wave functions that extend the AGP framework by incorporating inter-geminal correlations through a CI expansion. To make these…

Chemical Physics · Physics 2026-04-16 Airi Kawasaki , Fei Gao , Gustavo E. Scuseria

Extensions of the eikonal approximation to low energy (20MeV/nucleon typically) are studied. The relation between the dynamical eikonal approximation (DEA) and the continuum-discretized coupled-channels method with the eikonal approximation…

Nuclear Theory · Physics 2014-09-25 Tokuro Fukui , Kazuyuki Ogata , Pierre Capel

Contrary to the assumption that most quantum error-correcting codes (QECC) make, it is expected that phase errors are much more likely than bit errors in physical devices. By employing the entanglement-assisted stabilizer formalism, we…

Quantum Physics · Physics 2011-04-27 Yuichiro Fujiwara , Min-Hsiu Hsieh