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We have performed charge transfer phase formation studies on the donor/acceptor system bis(ethylendithio)tetrathiafulvalene,(BEDT-TTF)/tetracyanoquinodimethane,(TCNQ) by means of physical vapor deposition. We prepared donor/acceptor bilayer…

Materials Science · Physics 2009-03-15 Vita Levitan , Kerstin Keller , Michael Huth

Vanadium disulfide (VS_{2}) attracts elevated interests for its charge-density wave (CDW) phase transition, ferromagnetism, and catalytic reactivity, but the electronic structure of monolayer has not been well understood yet. Here we report…

Strongly Correlated Electrons · Physics 2021-11-24 Hyuk Jin Kim , Byoung Ki Choi , In Hak Lee , Min Jay Kim , Seung-Hyun Chun , Chris Jozwiak , Aaron Bostwick , Eli Rotenberg , Young Jun Chang

Two-dimensional systems with flat bands support correlated phases such as superconductivity and charge fractionalization. While twisted moire systems like twisted bilayer graphene have revealed such states, they remain complex to control.…

Mesoscale and Nanoscale Physics · Physics 2025-07-02 Elias Andrade , Alejandro Jimeno-Pozo , Pierre A. Pantaleon , Francisco Guinea , Gerardo G. Naumis

Certain layered transition metal dichalcogenides (TMDCs), such as 1T-TaS2, show a rich collection of charge density wave (CDW) phases at different temperatures, and their atomic structures and electron conductions have been widely studied.…

The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting.…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 Andrea Vezzoli , Iain Grace , Carly Brooke , Kun Wang , Colin J. Lambert , Bingqian Xu , Richard J. Nichols , Simon J. Higgins

We investigated transport properties of organic heterointerfaces formed by single-crystals of two organic donor-acceptor molecules, tetramethyltetraselenafulvalene (TMTSF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ). Whereas the individual…

Materials Science · Physics 2015-05-18 M. Nakano , H. Alves , A. S. Molinari , S. Ono , N. Minder , A. F. Morpurgo

Proximity effect is a very powerful approach and has been widely applied to induce electron correlations such as: superconductivity, magnetism and spin-orbit effects at the interface of heterostructure quantum materials. However, proximity…

Epitaxial growth of graphene on transition metal substrates is an important route for obtaining large scale graphene. However, the interaction between graphene and the substrate often leads to multiple orientations, distorted graphene band…

We have demonstrated transient charge localization effects with a driving high-frequency field of 7-fs, 1.5-cycle near infrared light in correlated organic conductors. In a layered organic conductor alpha-(BEDT-TTF)2I3 (BEDT-TTF:…

Strongly Correlated Electrons · Physics 2018-08-29 Yohei Kawakami , Hirotake Itoh , Kenji Yonemitsu , Shinichiro Iwai

A Kondo resonance has been observed on purely organic molecules in several combinations of charge transfer complexes on a metal surface. It has been regarded as a fingerprint of the transfer of one electron from the donor to the extended…

Mesoscale and Nanoscale Physics · Physics 2018-11-06 Paul Stoll , Christian Lotze , Janina N. Ladenthin , Tobias R. Umbach , Isabel Fernandez-Torrente , Katharina J. Franke

In the search for novel organic charge transfer salts with variable charge transfer degree we study the effects of two modifications to the recently synthesized donor-acceptor Tetramethoxypyrene (TMP)-Tetracyanoquinodimethane (TCNQ). One is…

We describe the synthesis and single molecule electrical transport properties of a molecular wire containing a ${\pi}$-extended tetrathiafulvalene (exTTF) group and its charge-transfer complex with F4TCNQ. We form single molecule junctions…

Charge transfer complexes are materials with a wide range of interesting optical and electronic properties. They have seen a great deal of research over the past decade, both in device development as well as research to elucidate the…

Materials Science · Physics 2024-06-04 Satwik Ramanjanappa , Edward R Van Keuren

Epitaxial graphene on SiC(0001) suffers from strong intrinsic n-type doping. We demonstrate that the excess negative charge can be fully compensated by non-covalently functionalizing graphene with the strong electron acceptor…

Effects of interaction of graphene with electron donor and acceptor molecules have been investigated by employing Raman spectroscopy. The G band softens progressively with the increasing concentration of tetrathiafulvalene (TTF) which is an…

Materials Science · Physics 2008-08-26 Rakesh Voggu , Barun Das , Chandra Sekhar Rout , C. N. R. Rao

The proximity-effect, whereby materials in contact appropriate each others electronic-properties, is widely used to induce correlated states, such as superconductivity or magnetism, at heterostructure interfaces. Thus far however,…

Inorganic-organic interfaces are important for enhancing the power conversion efficiency of silicon-based solar cells through singlet exciton fission (SF). We elucidated the structure of the first monolayers of tetracene (Tc), a SF…

Graphene has exceptional optical, mechanical and electrical properties, making it an emerging material for novel optoelectronics, photonics and for flexible transparent electrode applications. However, the relatively high sheet resistance…

Mesoscale and Nanoscale Physics · Physics 2013-02-06 Guang-Xin Ni , Yi Zheng , Sukang Bae , Chin Yaw Tan , Orhan Kahya , Jing Wu , Byung Hee Hong , Kui Yao , Barbaros Özyilmaz

The formation of donor-acceptor complexes (DACs) between the electron donor Dibenzotetrathiafulvalene (DBTTF) and the acceptor Hexaaza\-triphenylene\-hexacarbo\-nitrile (HATCN) results in a new phase with a distinctly different crystal…

We calculate the transport properties of multilayer graphene, considering the effect of multisubband scattering in a high density regime, where higher subbands are occupied by charge carriers. To calculate the conductivity of multilayer…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Seungchan Woo , E. H. Hwang , Hongki Min
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