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Complex oxide perovskites have been widely studied for their diverse functional properties. When dimensionally reduced to epitaxial thin films and heterostructures these properties are frequently tunable, and the symmetry-breaking inherent…

We provide insights into the influence of surface termination on the oxygen vacancy incorporation for the perovskite model material SrTiO3 during annealing in reducing gas environments. We present a novel approach to control to tailor the…

Materials Science · Physics 2019-11-15 Felix V. E. Hensling , Christoph Baeumer , Marc-André Rose , Felix Gunkel , Regina Dittmann

Understanding and controlling the chemical states both in the bulk and at the interfaces of complex oxide thin films is essential for engineering a wide range of electronic, optical, and magnetic functionalities, which arise through…

Materials Science · Physics 2025-12-30 Harish Kumarasubramanian , Jayakanth Ravichandran

Charge redistribution across heterojunctions has long been utilized to induce functional response in materials systems. Here we examine how the composition of the terminating surface affects charge transfer across a heterojunction…

Materials Science · Physics 2023-03-28 M. Chrysler , J. Gabel , T. -L. Lee , Z. Zhu , T. C. Kaspar , P. V. Sushko , S. A. Chambers , J. H. Ngai

Heterostructures and crystal interfaces play a major role in state-of-the-art semiconductor devices and play a central role in the field of oxide electronics. In oxides the link between the microscopic properties of the interfaces and bulk…

Controlling the surface structure on the atomic scale is a major difficulty for most transition metal oxides; this is especially true for the ternary perovskites. The influence of surface stoichiometry on the atomic structure of the…

Materials Science · Physics 2018-04-13 Stefan Gerhold , Zhiming Wang , Michael Schmid , Ulrike Diebold

A wealth of intriguing properties emerge in the seemingly simple system composed of the band insulators LaAlO3 and SrTiO3 such as a two-dimensional electron gas, superconductivity and magnetism. In this paper we review the current insight…

Materials Science · Physics 2013-08-05 R. Pentcheva , R. Arras , K. Otte , V. G. Ruiz , W. E. Pickett

Perovskite oxides attract increasing attention due to their broad potential in many applications. Understanding their surfaces is challenging, though, because the ternary composition of the bulk allows for multiple stable surface…

Materials Science · Physics 2019-03-27 Igor Sokolovic , Michael Schmid , Ulrike Diebold , Martin Setvin

Advances in synthesis techniques and materials understanding have given rise to oxide heterostructures with intriguing physical phenomena that cannot be found in their constituents. In these structures, precise control of interface quality,…

The surface/interface species in perovskite oxides play an essential role in many novel emergent physical phenomena and chemical processes. With low eigen-energy in the terahertz region, such species at buried interfaces remain poorly…

We report the first observation of coherent surface states on cubic perovskite oxide SrVO3(001) thin films through spectroscopic imaging scanning tunneling microscopy. A direct link between the observed atomic-scale interference patterns…

Emergent behavior at complex oxide interfaces has driven much of the research in the oxide thin film community for the past twenty years. Interfaces have been engineered for potential applications in spintronics, topological quantum…

Materials Science · Physics 2021-07-06 Suresh Thapa , Rajendra Paudel , Miles D. Blanchet , Patrick T. Gemperline , Ryan B. Comes

Perovskite films have rapidly emerged as leading active materials in optoelectronic devices due to their strong optical absorption, high carrier mobility and ease of fabrication. Whilst proving to be promising materials for solar cells and…

Perovskite photoelectrodes are being extensively studied in search for photocatalytic materials that can produce hydrogen through water splitting. The solar-to-hydrogen efficiency of these materials is critically dependent on the…

Applied Physics · Physics 2019-06-26 Yihuang Xiong , Ismaila Dabo

Oxide heterointerfaces constitute a rich platform for realizing novel functionalities in condensed matter. A key aspect is the strong link between structural and electronic properties, which can be modified by interfacing materials with…

Materials Science · Physics 2021-07-09 T. C. van Thiel , J. Fowlie , C. Autieri , N. Manca , M. Šiškins , D. Afanasiev , S. Gariglio , A. D. Caviglia

Selective optical excitation of a substrate lattice can drive phase changes across hetero-interfaces. This phenomenon is a non-equilibrium analogue of static strain control in heterostructures and may lead to new applications in optically…

Interfaces between dissimilar correlated oxides can offer devices with versatile functionalities. In that respect, manipulating and measuring novel physical properties of oxide heterointerfaces are highly desired. Yet, despite extensive…

A large challenge in determining the physics of helimagnetic SrFeO3 is in stabilizing the stoichiometric chemical phase over long enough time scales to conduct extensive measurements. Degradation in SrFeO3 manifests mainly as a crossover…

Using real-time spectroscopic ellipsometry, we directly observed a reversible lattice and electronic structure evolution in SrCoOx (x = 2.5 - 3) epitaxial thin films. Drastically different electronic ground states, which are extremely…

Strongly Correlated Electrons · Physics 2013-08-29 Woo Seok Choi , Hyoungjeen Jeen , Jun Hee Lee , S. S. Ambrose Seo , Valentino R. Cooper , Karin M. Rabe , Ho Nyung Lee

The discovery of high-mobility two-dimensional electron gas and low carrier density superconductivity in multiple SrTiO$_3$-based heterostructures has stimulated intense interest in the surface properties of SrTiO$_3$. The recent discovery…

Mesoscale and Nanoscale Physics · Physics 2024-05-31 Cui Ding , Wenfeng Dong , Xiaotong Jiao , Zhiyu Zhang , Guanming Gong , Zhongxu Wei , Lili Wang , Jin-Feng Jia , Qi-Kun Xue
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