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Molecular conduction operating in dielectric solvent environments are often described using kinetic rates based on Marcus theory of electron transfer at a molecule-metal electrode interface. However, the successive nature of charge transfer…

Chemical Physics · Physics 2020-02-18 Henning Kirchberg , Michael Thorwart , Abraham Nitzan

We develop a new approach to electron transport in mesoscopic systems by using a particular single-particle basis. Although this basis generates redundant many-particle amplitudes, it greatly simplifies the treatment. By using our method…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Shmuel Gurvitz

We formulate a stochastic description of entropy production in scattering theory for coherent transport. We distinguish between the information entropy change due to partial knowledge of the leads' state and the thermodynamic entropy change…

Mesoscale and Nanoscale Physics · Physics 2026-04-29 Ludovico Tesser , Henning Kirchberg , Matteo Acciai , Janine Splettstoesser

The accuracy of the noninteracting electron approximation is examined for a model of vibrationally coupled electron transport in single molecule junction. In the absence of electronic-vibrational coupling, steady state transport in this…

Mesoscale and Nanoscale Physics · Physics 2017-01-04 Haobin Wang , Michael Thoss

The electrical transport properties of atomic-scale conductors are reviewed, with an emphasis on the relations of this problem with studies on quantum size effects in metallic clusters. A brief introduction is given of the natural formalism…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. M. van Ruitenbeek

Recent electronic transport experiments using metallic contacts attached to proteins identified some 'stylized facts' which contradict conventional wisdom that increasing either the spatial distance between the electrodes or the temperature…

Disordered Systems and Neural Networks · Physics 2019-09-04 Eszter Papp , Dávid P. Jelenfi , Máté T. Veszeli , Gábor Vattay

The multilayer multiconfiguration time-dependent Hartree theory within second quantization representation of the Fock space is applied to study correlated electron transport in models of single-molecule junctions. Extending previous work,…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Haobin Wang , Michael Thoss

We present a theoretical study of the heat dissipation in single-molecule junctions. In order to investigate the heat dissipation in the electrodes and the relationship between the transmission spectra and the electronic structures, we…

Mesoscale and Nanoscale Physics · Physics 2016-08-09 Yaghoob Naimi , Javad Vahedi

Molecule-electrode interfaces in molecular electronic junctions are prone to chemical reactions, structural changes, and localized heating effects caused by electric current. These can be exploited for device functionality or may be…

Mesoscale and Nanoscale Physics · Physics 2020-04-22 Riley J. Preston , Vincent F. Kershaw , Daniel S. Kosov

We study the interplay of intrinsic-electronic and environmental factors on long-range charge transport across molecular chains with up to $N\sim 80$ monomers. We describe the molecular electronic structure of the chain with a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 Francisco Lai Liang , Dvira Segal

In the present work we theoretically analyze thermoelectric transport in single-molecule junctions (SMJ) characterized by strong interactions between electrons on the molecular linkers and phonons in their nuclear environments where…

Mesoscale and Nanoscale Physics · Physics 2024-01-17 Natalya A. Zimbovskaya

Using a model comprising a 2-level bridge connecting free electron reservoirs we show that coupling of a molecular bridge to electron-hole excitations in the leads can markedly effect the source-drain current through a molecular junction.In…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan , Mark A. Ratner

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

Recent experiments demonstrate a temperature control of the electric conduction through a ferrocene-based molecular junction. Here we examine the results in view of determining means to distinguish between transport through single-particle…

Mesoscale and Nanoscale Physics · Physics 2018-02-23 Miguel A. Sierra , David Sánchez , Alvar R. Garrigues , Enrique del Barco , Lejia Wang , Christian A. Nijhuis

Thermal conductance of single molecular junctions at room temperature has been measured recently using picowatt-resolution scanning probes. However, fully understanding thermal transport in a much wider temperature range is needed for the…

Mesoscale and Nanoscale Physics · Physics 2022-02-15 Gen Li , Bing-Zhong Hu , Nuo Yang , Jing-Tao Lü

We present a scattering approach for the study of the transport and thermodynamics of quantum systems strongly coupled to their thermal environment(s). This formalism recovers the standard non-equilibrium Green's function expressions for…

Statistical Mechanics · Physics 2020-07-15 Alexander Semenov , Abraham Nitzan

We present a detailed study of the first simple mechanical system that shows fully realistic transport behavior while still being exactly solvable at the level of equilibrium statistical mechanics. The system under consideration is a…

Statistical Mechanics · Physics 2009-09-29 H. Larralde , F. Leyvraz , C. Mejia-Monasterio

We investigate nonlinear transport properties of quantum conductors in response to both electrical and thermal driving forces. Within scattering approach, we determine the nonequilibrium screening potential of a generic mesoscopic system…

Mesoscale and Nanoscale Physics · Physics 2013-01-16 David Sanchez , Rosa Lopez

We extend the Landauer-B\"uttiker probe formalism for conductances to the high bias regime, and study the effects of environmentally-induced elastic and inelastic scattering on charge current in single molecule junctions, focusing on…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 Michael Kilgour , Dvira Segal

Electric, thermal and thermoelectric transport in correlated electron systems probe different aspects of the many-body dynamics, and thus provide complementary information. These are well studied in the low- and high-temperature limits,…

Strongly Correlated Electrons · Physics 2020-02-19 Woo-Ram Lee , Alexander M. Finkel'stein , Karen Michaeli , Georg Schwiete