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High-performance osmotic energy conversion (OEC) with perm-selective porous membrane requires both high ionic selectivity and permeability simultaneously. Here, hydrodynamic slip is considered on surfaces of nanopores to break the tradeoff…

Chemical Physics · Physics 2022-06-08 Long Ma , Kabin Lin , Yinghua Qiu , Jiakun Zhuang , Xuan An , Zhishan Yuan , Chuanzhen Huang

High-performance osmotic energy conversion requires both large ionic throughput and high ionic selectivity, which can be significantly promoted by exterior surface charges simultaneously, especially for short nanopores. Here, we investigate…

Chemical Physics · Physics 2022-06-08 Long Ma , Xuan An , Fenhong Song , Yinghua Qiu

Besides the dominant NaCl, natural seawater/river water contains trace multivalent ions, which can provide effective screening to surface charges. Here, in both negatively and positively charged nanopores, influences from divalent ions as…

Chemical Physics · Physics 2024-02-08 Fenhong Song , Xuan An , Long Ma , Jiakun Zhuang , Yinghua Qiu

Electroosmotic flow (EOF) through nanoporous membranes has broad applications in micro- and nanofluidic systems, particularly in biomedical diagnostics and chemical analysis. The use of short nanopores enables high fluid flux, and the…

Chemical Physics · Physics 2025-12-08 Chao Zhang , Xiaomei Zhang , Hongwen Zhang , Zekun Gong , Xiuhua Ren , Mengnan Guo , Yinghua Qiu

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

Soft Condensed Matter · Physics 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

Liquid transport through nanopore is central into many applications, from water purification to biosensing or energy harvesting. Ultimately thin nanopores are of major interest in these applications to increase driving potential and reduce…

Fluid Dynamics · Physics 2020-10-05 Olivier Liot , Catherine Sempere , Christophe Ybert , Anne-Laure Biance

Blue energy relies on the chemical potential difference generated between solutions of high and low ionic strength and would provide a sun-and-wind independent energy source at estuaries around the world. Converting this osmotic energy…

Nanopore membranes are a versatile platform for a wide range of applications ranging from medical sensing to filtration and clean energy generation. To attain high-flux rectifying ionic flow, it is required to produce short channels…

Mesoscale and Nanoscale Physics · Physics 2023-05-12 Alexander Kiy , Shankar Dutt , Christian Notthoff , Maria E. Toimil-Molares , Nigel Kirby , Patrick Kluth

Electrical conductivity is an inherent property of a hydrophobic porous media (HPM) and has critical applications. This research aims to provide a solution for predicting the electrical conductivity of nanoscale HPM with heterogeneous pore…

Soft Condensed Matter · Physics 2021-05-31 Zhongliang Chen , Xiaohu Dong , Zhangxin Chen , Marc-Olivier Coppens

Thermo-osmosis refers to fluid migration due to temperature gradient. The mechanistic understanding of thermo-osmosis in charged nano-porous media is still incomplete, while it is important for several environmental and energy applications,…

Chemical Physics · Physics 2023-07-14 Wei Qiang Chen , Andrey P Jivkov , Majid Sedighi

The integration of the coupling effects of intrinsic wettability and surface charge in a nanochannel can cause non-intuitive behavior in the electrokinetic energy conversion processes. We demonstrate that in a nanofluidic device the energy…

Fluid Dynamics · Physics 2015-11-12 Chirodeep Bakli , Suman Chakraborty

Short nanopores find extensive applications capitalizing on their high throughput and detection resolution. Ionic behaviors through long nanopores are mainly determined by charged inner-pore walls. When pore lengths decrease to sub-200 nm,…

Chemical Physics · Physics 2024-02-19 Long Ma , Zhe Liu , Bowen Ai , Jia Man , Jianyong Li , Kechen Wu , Yinghua Qiu

It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in…

Fluid Dynamics · Physics 2015-06-15 Gowrishankar Seshadri , Tobias Baier

The performance of organic solar cells (OSCs) can be greatly improved by incorporating silica-coated gold nanorods (Au@SiO2 NRs) at the interface between the hole transporting layer and the active layer due to the plasmonic effect. The…

The forced intrusion of water in hydrophobic nanoporous pulverulent material is of interest for quick storage of energy. With nanometric pores the energy storage capacity is controlled by interfacial phenomena. With subnanometric pores, we…

Soft Condensed Matter · Physics 2015-07-03 Millán Michelin-Jamois , Cyril Picard , Gérard Vigier , Elisabeth Charlaix

As an important property of porous membranes, the surface charge property determines many ionic behaviors of nanopores, such as ionic conductance and selectivity. Based on the dependence of electric double layers on bulk concentrations,…

Chemical Physics · Physics 2024-02-08 Jiakun Zhuang , Long Ma , Yinghua Qiu

The ionic selectivity of nanopores is crucial for the energy conversion based on nanoporous membranes. It can be significantly affected by various parameters of nanopores and the applied fields driving ions through porous membranes. Here,…

Soft Condensed Matter · Physics 2024-10-29 Chao Zhang , Mengnan Guo , Hongwen Zhang , Xiuhua Ren , Yinghao Gao , Yinghua Qiu

In this paper we report the theory describing the electro-osmotic flow in charged nanopores with constant radius and charge density driven by alternating current. We solve the ion and solution transport in unsteady conditions as described…

Chemical Physics · Physics 2018-10-17 J. Catalano , P. M. Biesheuvel

The electro-osmotic flow (EOF) in a neutral system consisting of an aqueous NaCl solution confined in a nanochannel with two parallel Molybdenum disulfide ($\textrm{MoS}_{\textrm{2}}$) walls and in the presence of an external electric field…

Soft Condensed Matter · Physics 2023-12-04 S. M. Kazem Manzoorolajdad , Hossein Hamzehpour , Jalal Sarabadani

Our Society is in high need of alternatives to fossil fuels. Nanoporous systems filled with aqueous electrolytes show great promises for harvesting the osmotic energy of sea water or waste heat. At the core of energy conversion in such…

Fluid Dynamics · Physics 2022-04-29 Cecilia Herrero , Aymeric Allemand , Samy Merabia , Anne-Laure Biance , Laurent Joly
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