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A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

Atomic Physics · Physics 2008-07-15 Ivan C. H. Liu , Jovica Stanojevic , Jan M. Rost

We report the observation of cold Cs Rydberg atom molecules bound at internuclear separations of R~3-9 um. The bound states result from avoided crossings between Rydberg atom pair interaction potentials in an applied electric field. The…

A three-level atomic medium can be made transparent to a resonant probe field in the presence of a strong control field acting on an adjacent atomic transition to a long-lived state, which can be represented by a highly excited Rydberg…

Quantum Physics · Physics 2017-03-16 David Petrosyan

Obtaining full control over the internal and external quantum states of molecules is the central goal of ultracold chemistry and allows for the study of coherent molecular dynamics, collisions and tests of fundamental laws of physics. When…

Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical…

Resonant laser excitation of multiple Rydberg atoms are prohibited, leading to Rydberg blockade, when the long-range van der Waals interactions are stronger than the laser-atom coupling. Rydberg blockade can be violated, i.e. simultaneous…

Quantum Physics · Physics 2021-10-04 Shi-Lei Su , Weibin Li

Divalent atoms have emerged as powerful alternatives to alkalis in ultracold atom platforms, offering unique advantages arising from their two-electron structure. Among these species, ytterbium (Yb) is especially promising, yet its anionic…

The theoretical treatment of Rydberg states in one-electron ions is facilitated by the virtual absence of the nuclear-size correction, and fundamental constants like the Rydberg constant may be in the reach of planned high-precision…

Atomic Physics · Physics 2012-07-03 B. J. Wundt , U. D. Jentschura

Strongly Rydberg-blockaded two-level atoms form a Rydberg superatom, which is excited only to a collective symmetrical Dicke state. However, emerging often in the alkali-earth atoms, the spontaneous decay from the Rydberg state to an…

Quantum Physics · Physics 2021-12-21 Chang Qiao , Wenxian Zhang

By investigating the quantum properties of magnetically trapped nS Rydberg atoms, it is demonstrated that the composite nature of Rydberg atoms significantly alters their trapping properties opposed to point-like particles with the same…

Atomic Physics · Physics 2009-04-22 M. Mayle , I. Lesanovsky , P. Schmelcher

Conical intersections (CI) between molecular potential energy surfaces with non-vanishing non-adiabatic couplings generally occur in any molecule consisting of at least three atoms. They play a fundamental role in describing the molecular…

We present a method to control collisions between ultracold neutral atoms in the electronic ground state and trapped ions. During the collision, the neutral atom is resonantly excited by a laser to a low-field-seeking Rydberg state, which…

Quantum Gases · Physics 2020-06-24 Limei Wang , Markus Deiß , Georg Raithel , Johannes Hecker Denschlag

Discrete time quasi-crystals are non-equilibrium quantum phenomena with quasi-periodic order in the time dimension, and are an extension of the discrete time-crystal phase. As a natural platform to explore the non-equilibrium phase of…

Quantum Physics · Physics 2025-05-19 Xiaofan Luo , Yaoting Zhou , Zhongxiao Xu , Weilun Jiang

Rydberg molecule, formed by one or more Rydberg atoms, exhibits remarkable properties, including an exceptionally large spatial extent, rich rovibrational level structures, permanent electric dipole moments, and a pronounced sensitivity to…

Atomic Physics · Physics 2026-03-11 Jingxu Bai , Yuechun Jiao , Xiao-Qiang Shao , Weibin Li , Jianming Zhao

Arrays of Rydberg atoms in the blockade regime realize a wealth of strongly correlated quantum physics, but theoretical analysis beyond the chain is rather difficult. Here we study a tractable model of Rydberg-blockade atoms on the square…

Strongly Correlated Electrons · Physics 2024-03-13 Luisa Eck , Paul Fendley

The nature of the theory of circular Rydberg states of hydrogenlike ions allows highly-accurate predictions to be made for energy levels. In particular, uncertainties arising from the problematic nuclear size correction which beset low…

Atomic Physics · Physics 2010-03-30 U. D. Jentschura , P. J. Mohr , J. N. Tan

We investigate the structure of a prototypical two-state conical intersection (BeH$_2$) using a phase space electronic Hamiltonian $\hat{H}_{PS}(\bR,\bP)$ that goes beyond the Born-Oppenheimer framework. By parameterizing the electronic…

Chemical Physics · Physics 2025-06-16 Titouan Duston , Nadine Bradbury , Zhen Tao , Joseph E. Subotnik

We present a theory of electromagnetically induced transparency in a cold ensemble of strongly interacting Rydberg atoms. Long-range interactions between the atoms constrain the medium to behave as a collection of superatoms, each…

Quantum Physics · Physics 2011-11-23 David Petrosyan , Johannes Otterbach , Michael Fleischhauer

Strong resonant dipole-dipole interactions in flexible Rydberg aggregates enable the formation of exciton pulses, the interplay of atomic motion and electronic excitation transfer which feature high fidelity entanglement transport. Here, we…

Quantum Physics · Physics 2016-12-26 Karsten Leonhardt

For two states of opposite parity that cross as a function of an external magnetic field, the addition of an electric field will break the symmetry and induce an avoided crossing. A suitable arrangement of fields may be used to create a…

Quantum Gases · Physics 2013-05-29 Alisdair O. G. Wallis , S. A. Gardiner , Jeremy M. Hutson