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Fermi level engineering and mechanical properties evolution in high entropy carbides are investigated by theoretical and experimental means. Massive elemental diversity in high entropy ceramics broadens the compositional space but imposes…

Materials Science · Physics 2021-01-14 Mohammad Delower Hossain , Sarah Lowum , Trent Borman , Jon-Paul Maria

Ultra-high temperature ceramics (UHTCs) represent a class of crystalline materials for extreme environments. They can withstand extremely high temperatures but are mechanically difficult to work with due to their inherent brittleness.…

The synthesis and characterization, along with the resulting properties, of fully dense \((\mathrm{Cr, Mo, Ta, V, W})\mathrm{C}\) high-entropy carbide ceramics were studied. The ceramics were synthesized from metal oxide and carbon powders…

Developing ductile refractory BCC alloys has remained a challenge. The intrinsic ductility (D) of an alloy is the ratio of surface energy ($\gamma_s$) and unstable stacking fault energy ($\gamma_{usfe}$). Lowering the valence electron…

Materials Science · Physics 2023-01-03 Sufyan M. Shaikh , B. S. Murty , Satyesh K. Yadav

The formation possibility of a new (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramic (ZHC-1) was first analyzed by the first-principles calculations and thermodynamical analysis and then it was successfully fabricated by hot pressing…

Materials Science · Physics 2019-03-01 Beilin Ye , Tongqi Wen , Manh Cuong Nguyen , Luyao Hao , Cai-Zhuang Wang , Yanhui Chu

Traditionally, increasing compositional complexity and chemical diversity of high entropy alloy ceramics whilst maintaining a stable single-phase solid solution has been a primary design strategy for the development of new ceramics.…

Materials Science · Physics 2024-03-19 O. V. Pshyk , A. Vasylenko , P. Kuttel , B. Wicher , P. Schweizer , J. Michler , T. E. J. Edwards

Revealing the hardening and strengthening mechanisms is crucial for facilitating the design of superhard and high-strength high-entropy ceramics (HECs). Here, we take high-entropy diborides (HEB$_2$) as the prototype to thoroughly…

Materials Science · Physics 2023-12-18 Yiwen Liu , Haifeng Tang , Mengdong Ma , Hulei Yu , Zhongyu Tang , Yanhui Chu

High-entropy alloys (HEAs) are potential candidates for applications as refractory materials. While dual-phase refractory HEAs containing an ordered phase exhibit high hardness, there is high interest in developing intermetallic-free and…

Materials Science · Physics 2024-12-30 Shivam Dangwal , Kaveh Edalati

The possibility of solid solution formation in high entropy alloys (HEAs) has been calculated for alloys with four to seven elements, using a rule previously reported. Thirty elements were included: transition elements of the fourth, fifth…

Materials Science · Physics 2021-05-03 Oscar Coreno Alonso , Juan Coreno Alonso

We investigate the thermodynamics and phase stability of the AlTiVCr lightweight high-entropy alloy using a combination of ab initio electronic structure calculations, a concentration wave analysis, and atomistic Monte Carlo simulations. In…

Materials Science · Physics 2026-01-26 Christopher D. Woodgate , Hubert J. Naguszewski , Nicolas F. Piwek , David Redka

This invited talk will review a series of our recent studies on high-entropy ceramics (HECs) and compositionally complex ceramics (CCCs) and discuss the future perspective. Various single-phase equimolar quinary (five-component) HECs, e.g.,…

Materials Science · Physics 2022-12-22 Jian Luo

X-ray powder diffraction, electrical resistivity, magnetization, and thermodynamic measurements were conducted to investigate the structure and superconducting properties of TiHfNbTaMo, a novel high-entropy alloy possessing a valence…

Response of refractory high-entropy alloys MoNbTaVW and HfNbTaTiZr to ultrafast laser radiation is modelled with the hybrid code XTANT-3, combining tight-binding molecular dynamics with the transport Monte Carlo and Boltzmann equation. A…

Materials Science · Physics 2026-02-19 Nikita Medvedev

Refractory High-Entropy Alloys (RHEAs) hold promising potential to be used as structural materials in future nuclear fusion reactors, where W and its alloys are currently leading candidates. Fusion materials must be able to withstand…

We explored quinary body-centered cubic (bcc) high-entropy alloy (HEA) superconductors with valence electron concentrations (VECs) ranging from 4.6 to 5.0, a domain that has received limited attention in prior research. Our search has led…

Energy efficiency is motivating the search for new high-temperature metals. Some new body-centered-cubic random multicomponent "high entropy alloys (HEAs)" based on refractory elements (Cr-Mo-Nb-Ta-V-W-Hf-Ti-Zr) possess exceptional…

Three novel precipitation strengthened bcc alloys which exhibit a smooth microstructural gradient with composition have been fabricated in bulk form by induction casting. All three alloys are comprised of a mixture of disordered A2-(Fe, Cr)…

Materials Science · Physics 2021-03-23 Silas Wolff-Goodrich , Sebastian Haas , Uwe Glatzel , Christian Liebscher

In this study Mo-Nb-Ta-W refractory high-entropy alloys (R-HEAs) have been studied for their phase stability for a wide temperature range (100 K to 2000 K). The equilibrium thermodynamic phases are determined by the changes in enthalpy and…

Materials Science · Physics 2021-03-16 Varnita Bajpai , Soumyadipta Maiti , Shashank Mishra , Beena Rai

Using fluorite oxides as an example, this study broadens high-entropy ceramics (HECs) to compositionally-complex ceramics (CCCs) or multi-principal cation ceramics (MPCCs) to include medium-entropy and/or non-equimolar compositions. Nine…

Materials Science · Physics 2020-01-08 Andrew J. Wright , Qingyang Wang , Chuying Huang , Andy Nieto , Renkun Chen , Jian Luo

A comprehensive literature review on recently rediscovered Co- and/or CoNi-based superalloys, strengthened by the {\gamma}' phase, revealed a relationship between the configurational entropy of the system and the {\gamma}' solvus…

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