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The density of states of the disordered s-wave superconductor is calculated perturbatively. The effect of Coulomb interaction on diffusively moving electrons in the normal state has been known before, but in the superconducting state both…

Superconductivity · Physics 2019-10-03 Takanobu Jujo

Finding accurate exchange-correlation (XC) functionals remains the defining challenge in density functional theory (DFT). Despite 40 years of active development, the desired chemical accuracy is still elusive with existing functionals. We…

Chemical Physics · Physics 2024-09-11 Bikash Kanungo , Jeffrey Hatch , Paul M. Zimmerman , Vikram Gavini

To accurately describe the energetics of transition metal systems, density functional approximations (DFAs) must provide a balanced description of s- and d- electrons. One measure of this is the sd transfer error, which has previously been…

Chemical Physics · Physics 2025-01-13 Rohan Maniar , Priyanka B. Shukla , J. Karl Johnson , Koblar A. Jackson , John P. Perdew

Astrophysical observations spanning dwarf galaxies to galaxy clusters indicate that dark matter (DM) halos are less dense in their central regions compared to expectations from collisionless DM N-body simulations. Using detailed fits to DM…

Cosmology and Nongalactic Astrophysics · Physics 2016-02-03 Manoj Kaplinghat , Sean Tulin , Hai-Bo Yu

An oversight of some previous density functional calculations of the band gaps of wurtzite and cubic InN and of wurtzite GaN by Rinke et al. [Appl. Phys. Lett. 89,161919, 2006] led to an inaccurate and misleading statement relative to…

Materials Science · Physics 2011-02-03 D. Bagayoko , L. Franklin , G. L. Zhao

Density functional calculations on atoms are often used for determining accurate initial guesses as well as generating various types of pseudopotential approximations and efficient atomic-orbital basis sets for polyatomic calculations. To…

Computational Physics · Physics 2023-10-30 Susi Lehtola

Functionals of the meta-generalized gradient approximation (MGGA) are nowadays widely used in chemistry and solid-state physics for the simulation of electronic systems like molecules, solids, or surfaces. Due to their dependency on the…

Materials Science · Physics 2022-05-31 Jan Doumont , Fabien Tran , Peter Blaha

The approximate atomic self-interaction corrections (ASIC) method to density functional theory is put to the test by calculating the exchange interaction for a number of prototypical materials, critical to local exchange and correlation…

Materials Science · Physics 2009-11-13 A. Akande , S. Sanvito

Excited-state calculations, notably for quasiparticle band structures, are nowadays routinely performed within the GW approximation for the electronic self-energy. Nevertheless, certain numerical approximations and simplifications are still…

Model Hamiltonians with long-range interaction yield energies that are corrected taking into account the universal behavior of the electron-electron interaction at short range. Although the intention of the paper is to explore the…

Chemical Physics · Physics 2020-10-28 Andreas Savin

We show that Mn_2VAl is a compound for which the generalized gradient approximation (GGA) to the exchange-correlation functional in density functional theory makes a qualitative change in predicted behavior compared to the usual local…

Materials Science · Physics 2009-10-31 Ruben Weht , Warren E. Pickett

We introduce an extension of the dynamical mean field approximation (DMFA) which retains the causal properties and generality of the DMFA, but allows for systematic inclusion of non-local corrections. Our technique maps the problem to a…

Strongly Correlated Electrons · Physics 2009-10-31 M. H. Hettler , A. N. Tahvildar-Zadeh , M. Jarrell , T. Pruschke , H. R. Krishnamurthy

The dynamical behavior of the magnetism of diluted magnetic semiconductors (DMS) has been investigated by means of atomistic spin dynamics simulations. The conclusions drawn from the study are argued to be general for DMS systems in the low…

Materials Science · Physics 2014-04-04 J. Hellsvik , B. Skubic , L. Nordström , B. Sanyal , O. Eriksson , P. Nordblad , P. Svedlindh

To explore the applicability of orbital-free density functional theory (OF-DFT) in nuclear physics, we perform a systematic benchmark of 36 one-point kinetic energy density functionals, which are originally developed for electron systems in…

Nuclear Theory · Physics 2026-05-20 Tian Shuai Shang , Jian Li , Haozhao Liang , Xinhui Wu , Cheng Ma , Wenhui Mi , Xuecheng Shao , Yanchao Wang

Recently, Tao and Mo (TM) proposed an accurate all-purpose nonempirical meta-generalized gradient approximation (meta-GGA). The exchange part was derived from the density matrix approximation, while the correlation part is based on a…

Materials Science · Physics 2017-06-28 Yuxiang Mo , Guocai Tian , Jianmin Tao

Self-interacting dark matter (SIDM) has been proposed to address small-scale challenges faced by the cold dark matter (CDM) paradigm, such as the diverse density profiles observed in dwarf galaxies. In this study, we analyze the kinematics…

Cosmology and Nongalactic Astrophysics · Physics 2025-03-19 Shin'ichiro Ando , Kohei Hayashi , Shunichi Horigome , Masahiro Ibe , Satoshi Shirai

Many-electron wavepacket dynamics based on time-dependent configuration interaction (TDCI) is a numerically rigorous approach to quantitatively model electron-transfer across molecular junctions. TDCI simulations of cyanobenzene…

Chemical Physics · Physics 2020-06-24 Raghunathan Ramakrishnan

We present a reformulation of QM/MM as a fully quantum mechanical theory of interacting subsystems, all treated at the level of density functional theory (DFT). For the MM subsystem, which lacks orbitals, we assign an ad hoc electron…

The properties of diluted Ga$_{1-x}$Mn$_x$As are calculated for a wide range of Mn concentrations within the local spin density approximation of density functional theory. M\"ulliken population analyses and orbital-resolved densities of…

Mesoscale and Nanoscale Physics · Physics 2025-06-10 Stefano Sanvito , Pablo Ordejon , Nicola A. Hill

The Coulomb exchange and correlation energy density functionals for electron systems are applied to nuclear systems. It is found that the exchange functionals in the generalized gradient approximation provide agreements with the exact-Fock…

Nuclear Theory · Physics 2019-12-09 Tomoya Naito , Ryosuke Akashi , Gianluca Colò , Haozhao Liang , Xavier Roca-Maza