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The interaction between charged objects in an electrolyte solution is a fundamental question in soft matter physics. It is well-known that the electrostatic contribution to the interaction energy decays exponentially with object separation.…

Soft Condensed Matter · Physics 2017-08-02 Alpha A. Lee , Carla Perez-Martinez , Alexander M. Smith , Susan Perkin

Correlation functions in concentrated ionic systems are studied within the mesoscopic theory at the level of the Gaussian approximation. The previously neglected fluctuation contribution to the inverse charge-charge correlation function is…

Soft Condensed Matter · Physics 2025-06-26 O. Patsahan , A. Ciach

Recently, underscreening in concentrated electrolytes was discovered in experiments and confirmed in simulations and theory. It was found that the correlation length of the charge-charge correlations, $\lambda_s$, satisfies the scaling…

Statistical Mechanics · Physics 2022-11-07 A. Ciach , O. Patsahan

According to classical electrolyte theories interactions in dilute (low ion density) electrolytes decay exponentially with distance, with the Debye screening length the characteristic length-scale. This decay length decreases monotonically…

Soft Condensed Matter · Physics 2016-07-15 Alexander M. Smith , Alpha A. Lee , Susan Perkin

We calculate the conductance of atomic chains as a function of their length. Using the Density Matrix Renormalization Group algorithm for a many-body model which takes into account electron-electron interactions and the shape of the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Rafael A. Molina , Dietmar Weinmann , Jean-Louis Pichard

A self-consistent mode-coupling theory is presented for the viscosity of solutions of charged rod-like polymers. The static structure factor used in the theory is obtained from polymer integral equation theory; the Debye-H\"{u}ckel…

Soft Condensed Matter · Physics 2009-11-10 Kunimasa Miyazaki , Biman Bagchi , Arun Yethiraj

The decay of correlations in ionic fluids is a classical problem in soft matter physics that underpins applications ranging from controlling colloidal self-assembly to batteries and supercapacitors. The conventional wisdom, based on…

Statistical Mechanics · Physics 2018-08-22 Fabian Coupette , Alpha A. Lee , Andreas Härtel

Electrostatic correlations between ions dissolved in water are known to impact their transport properties in numerous ways, from conductivity to ion selectivity. The effects of these correlations on the solvent itself remain, however, much…

Soft Condensed Matter · Physics 2024-01-31 Paul Robin

The presence of long-ranged correlations in a fluid undergoing uniform shear flow is investigated. An exact relation between the density autocorrelation function and the density-mometum correlation function implies that the former must…

Statistical Mechanics · Physics 2009-11-07 James F. Lutsko , J. W. Dufty

The classical Debye-Huckel (DH) theory clearly accounts for the origin of screening in electrolyte solutions and works rather well for dilute electrolyte solutions. While the Debye screening length decreases with the ion concentration and…

Soft Condensed Matter · Physics 2019-10-30 Ram M. Adar , Samuel A. Safran , Haim Diamant , David Andelman

The Debye charging method is generalized to study the linear response properties of the asymmetric primitive model for electrolytes. Analytic results are obtained for the effective charge distributions of constituent ions inside the…

Soft Condensed Matter · Physics 2016-11-23 Mingnan Ding , Yihao Liang , Bing-Sui Lu , Xiangjun Xing

Dense non-Brownian suspension flows of hard particles display mystifying properties: as the jamming threshold is approached, the viscosity diverges, as well as a length scale that can be identified from velocity correlations. To unravel the…

Statistical Mechanics · Physics 2015-06-16 Gustavo Düring , Edan Lerner , Matthieu Wyart

We obtain large and moderate deviation estimates, as well as concentration inequalities, for a class of nonuniformly expanding maps with stretched exponential decay of correlations. In the large deviation regime, we also exhibit examples…

Probability · Mathematics 2022-01-26 C Cuny , J Dedecker , F Merlevède

A one-dimensional diagonal tight binding electronic system with correlated disorder is investigated. The correlation of the random potential is exponentially decaying with distance and its correlation length diverges as the concentration of…

Disordered Systems and Neural Networks · Physics 2009-11-11 I Avgin

We study the Coulomb chain where particles are restricted to one dimension and experience three-dimensional Coulomb interactions with their nearest and next-to-nearest neighbours. The distances between consecutive particles are treated as…

Probability · Mathematics 2024-04-24 Henrik Ekström

We compute and compare the decay lengths of several correlation functions and effective coupling constants in the many-body localized (MBL) phase. To this end, we consider the distribution of the logarithms of these couplings and…

Strongly Correlated Electrons · Physics 2019-09-25 Vipin Kerala Varma , Abhishek Raj , Sarang Gopalakrishnan , Vadim Oganesyan , David Pekker

We show that scale-scale correlations are a generic feature of slow-roll inflation theories. These correlations result from the long-time tails characteristic of the time dependent correlations because the long wavelength density…

Astrophysics · Physics 2009-10-31 Li-Zhi Fang , Wolung Lee , Jesús Pando

We analyze a decomposition of the Coulomb electron-electron interaction into a long-range and a short-range part in the framework of density functional theory, deriving some scaling relations and the corresponding virial theorem. We study…

Chemical Physics · Physics 2015-06-26 Julien Toulouse , Paola Gori-Giorgi , Andreas Savin

The electrostatic screening length predicted by Debye-H\"uckel theory decreases with increasing ionic strength, but recent experiments have found that the screening length can instead increase in concentrated electrolytes. This phenomenon,…

Soft Condensed Matter · Physics 2021-10-13 Emily Krucker-Velasquez , James W. Swan

Screening of a surface charge by electrolyte and the resulting interaction energy between charged objects is of fundamental importance in scenarios from bio-molecular interactions to energy storage. The conventional wisdom is that the…

Chemical Physics · Physics 2017-01-30 Alpha A. Lee , Carla Perez-Martinez , Alexander M. Smith , Susan Perkin
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