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Magnetic pyrochlore oxides, including the spin ice materials, have proved to be a rich field for the study of geometrical frustration in 3 dimensions. Recently, a new family of magnetic oxides has been synthesised in which the half of the…

Strongly Correlated Electrons · Physics 2015-12-08 Owen Benton , Nic Shannon

The A-site ordered chromate spinels LiGa1-xInxCr4O8 host a network of size-alternating spin-3/2 Cr3+ tetrahedra known as a 'breathing' pyrochlore lattice. For the x=0.05 composition, the complex magneto-structural ordering observed in the…

We present a comprehensive neutron scattering study of the breathing pyrochlore magnet LiGaCr4S8. We observe an unconventional magnetic excitation spectrum with a separation of high and low-energy spin dynamics in the correlated…

The standard approach to realize a spin liquid state is through magnetically frustrated states, relying on ingredients such as the lattice geometry, dimensionality, and magnetic interaction type of the spins. While Heisenberg spins on a…

Strongly Correlated Electrons · Physics 2025-04-10 Margarita G. Dronova , Vaclav Petricek , Zachary Morgan , Feng Ye , Daniel M. Silevitch , Yejun Feng

We report neutron scattering measurements of the spinel oxide LiGaCr$_{4}$O$_{8}$, in which magnetic ions Cr$^{3+}$ form a breathing pyrochlore lattice. Our experiments reveal the coexistence of a nearly dispersionless resonance mode and…

Strongly Correlated Electrons · Physics 2021-12-23 Zheng He , Yiqing Gu , Hongliang Wo , Yu Feng , Die Hu , Yiqing Hao , Yimeng Gu , Helen C. Walker , Devashibhai T. Adroja , Jun Zhao

Reproducing the electronic structure of AM$_4$X$_8$ lacunar spinels with a breathing pyrochlore lattice is a great theoretical challenge due to the interplay of various factors. The character of the M$_4$X$_4$ cluster orbitals is critically…

Strongly Correlated Electrons · Physics 2020-02-20 S. Reschke , F. Meggle , F. Mayr , V. Tsurkan , L. Prodan , H. Nakamura , J. Deisenhofer , C. A. Kuntscher , I. Kézsmárki

We review the mechanism of spin-lattice coupling in relieving the geometrical frustration of pyrochlore antiferromagnets, in particular spinel oxides. The tetrahedral unit, which is the building block of the pyrochlore lattice, undergoes a…

Strongly Correlated Electrons · Physics 2018-07-25 O. Tchernyshyov , G. -W. Chern

We report a comprehensive neutron scattering study of low energy magnetic excitations in the breathing pyrochlore helimagnetic $\text{Cu}_2\text{OSeO}_3$. Fully documenting the four lowest energy magnetic modes that leave the ferrimagnetic…

Breathing pyrochlores are a unique class of materials characterized by a three-dimensional lattice of corner-sharing tetrahedra. However, unlike conventional pyrochlores where all tetrahedra are identical in size, the breathing pyrochlore…

We study the antiferromagnetic spin exchange models with $S=1/2$ and S=1 on a one-dimensional tetrahedron chain by both analytical and numerical approaches. The system is shown to be effectively mapped to a decoupled spin chain in the…

Strongly Correlated Electrons · Physics 2007-05-23 Shu Chen , Yupeng Wang , W. Q. Ning , Congjun Wu , H. Q. Lin

A unique type of frustrated lattice is found in two A-site ordered spinel oxides, LiGaCr4O8 and LiInCr4O8. Because of the large size mismatch between Li+ and Ga3+/In3+ ions at the A site, the pyrochlore lattice, made up of Cr3+ ions…

Materials Science · Physics 2015-06-12 Yoshihiko Okamoto , Gøran J. Nilsen , J. Paul Attfield , Zenji Hiroi

We investigate the crystallographic and magnetic properties of a chromium-based thiospinel CuGaCr$_{4}$S$_{8}$. From a synchrotron x-ray diffraction experiment and structural refinement, Cu and Ga atoms are found to occupy the tetrahedral…

Low energy Raman scattering of the s=1/2 spin tetrahedra system Cu_2Te_2O_5Br_2 is dominated by an excitation at 18 cm^{-1} corresponding to an energy E_S=0.6\Delta, with \Delta the spin gap of the compound. For elevated temperatures this…

Strongly Correlated Electrons · Physics 2009-11-07 P. Lemmens , K. Y. Choi , A. Ionescu , J. Pommer , G. Guentherodt , R. Valenti , C. Gros , W. Brenig , M. Johnsson , P. Millet , F. Mila

We report low-temperature powder X-ray and neutron diffraction studies on breathing pyrochlore magnets Cu$M$Cr$_{4}$S$_{8}$ ($M$ = Al, Ga), which undergo a magnetic transition at $T_{\rm N} \approx$ 21 and 31 K for {$M$ = Al and Ga,…

Materials Science · Physics 2024-05-09 Masaki Gen , Taro Nakajima , Hiraku Saito , Yusuke Tokunaga , Taka-hisa Arima

Spin excitations of layered copper oxide show various characteristic features, depending on the carrier concentration. In this study, we conducted inelastic neutron scattering (INS) measurements on La$_{2-x}$Sr$_{x}$CuO$_4$ (LSCO), with $x$…

Superconductivity · Physics 2022-01-26 K. Ikeuchi , S. Wakimoto , M. Fujita , T. Fukuda , R. Kajimoto , M. Arai

The three-dimensional frustrated spin lattice in MgCrGaO4, where Cr3+ ions occupy a pyrochlore-like network, exemplifies a quantum magnet with competing interactions, macroscopic degeneracy, and exotic low-energy excitations. Using…

Strongly Correlated Electrons · Physics 2026-03-17 U. Jena , S. Kundu , Suheon Lee , Q. Faure , F. Damay , S. Rols , Adam Berlie , S. Petit , Kwang-Yong Choi , P. Khuntia

Recently a new class of quantum magnets, the so-called breathing pyrochlore spin systems, have attracted much attention due to their potential to host exotic emergent phenomena. Here, we present magnetometry, heat capacity, thermal…

Using synchrotron X-rays and neutron diffraction we disentangle spin-lattice order in highly frustrated ZnCr$_2$O$_4$ where magnetic chromium ions occupy the vertices of regular tetrahedra. Upon cooling below 12.5 K the quandary of…

Strongly Correlated Electrons · Physics 2009-05-14 S. Ji , S. -H. Lee , C. Broholm , T. Y. Koo , W. Ratcliff , S-W. Cheong , P. Zschack

We study the magnetism of a lattice of coupled tetrahedral spin-1/2 clusters which might be of relevance to the tellurate compounds Cu2Te2O5X2, with X=Cl, Br. Using the flow equation method we perform a series expansion in terms of the…

Strongly Correlated Electrons · Physics 2009-11-07 Wolfram Brenig

Emergent molecular-like excitations have been discovered in a series of pyrochlore antiferromagnets, yet their origins and relationships with the coexisting magnon excitations remain a puzzle. Here, by incorporating the dynamic spin-lattice…

Strongly Correlated Electrons · Physics 2024-12-31 Shang Gao
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