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Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

Ultracold polar molecules uniquely combine a rich structure of long-lived internal states with access to controllable long-range, anisotropic dipole-dipole interactions. In particular, the rotational states of polar molecules confined in…

We investigate theoretically the interaction of polar molecules with optical lattices and microwave fields. We demonstrate the existence of frequency windows in the optical domain where the complex internal structure of the molecule does…

Quantum Physics · Physics 2009-11-13 S. Kotochigova , E. Tiesinga

The narrow transition from the lowest rovibrational level of the $\mathrm{X}^{1}\Sigma^{+}$ electronic ground state to the lowest vibrational level of the $\mathrm{b}^{3}\Pi_{0}$ potential provides opportunities for achieving…

Selection of "magic" trapping conditions with ultracold atoms or molecules, where pairs of internal states experience identical trapping potentials, brings substantial benefits to precision measurements and quantum computing schemes.…

Quantum Physics · Physics 2011-01-04 Svetlana Kotochigova , David DeMille

Optical trapping of molecules with long coherence times is crucial for many protocols in quantum information and metrology. However, the factors that limit the lifetimes of the trapped molecules remain elusive and require improved…

Atomic Physics · Physics 2020-10-14 K. H. Leung , I. Majewska , H. Bekker , C. -H. Lee , E. Tiberi , S. S. Kondov , R. Moszynski , T. Zelevinsky

Realising quantum control and entanglement of particles is crucial for advancing both quantum technologies and fundamental science. Significant developments in this domain have been achieved in a variety of systems. In this context,…

Atomic Physics · Physics 2025-01-27 Daniel K. Ruttley , Tom R. Hepworth , Alexander Guttridge , Simon L. Cornish

Diatomic polar molecules are one of the most promising platforms of quantum computing due to their rich internal states and large electric dipole moments. Here, we propose entangling rotational states of adjacent polar molecules via a…

Atomic Physics · Physics 2021-05-07 Eunmi Chae

Rotational states of ultracold polar molecules possess long radiative lifetimes, microwave-domain coupling, and tunable dipolar interactions. The availability of numerous rotational states has inspired many proposed applications, including…

We report on the optical polarizability of microwave-shielded ultracold NaCs molecules in an optical dipole trap. While dressing a pair of rotational states with a microwave field, we observe a marked dependence of the optical…

Quantum Gases · Physics 2025-01-16 Siwei Zhang , Weijun Yuan , Niccolò Bigagli , Claire Warner , Ian Stevenson , Sebastian Will

We investigate oscillation frequencies for simultaneous trapping of more than one type of alkali atoms in a common optical lattice. For this purpose, we present numerical results for magic trapping conditions, where the oscillation…

Atomic Physics · Physics 2016-05-31 Kiranpreet Kaur , B. K. Sahoo , Bindiya Arora

We report the finding of "triply magic" conditions (the doubly magic frequency-intensity conditions of an optical dipole trap plus the magic magnetic field) for the microwave transitions of optically trapped alkali-metal atoms. The…

Quantum Physics · Physics 2020-01-15 Gang Li , Yali Tian , Wei Wu , Shaokang Li , Xiangyan Li , Yanxin Liu , Pengfei Zhang , Tiancai Zhang

The present paper aims at finding optimal parameters for trapping of Cs$_2$ molecules in optical lattices, with the perspective of creating a quantum degenerate gas of ground-state molecules. We have calculated dynamic polarizabilities of…

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

We demonstrate efficient transfer of ultracold molecules into a deeply bound rovibrational level of the singlet ground state potential in the presence of an optical lattice. The overall molecule creation efficiency is 25%, and the transfer…

We theoretically investigate trapping conditions for ultracold polar molecules in optical lattices, when external magnetic and electric fields are simultaneously applied. Our results are based on an accurate electronic-structure calculation…

Quantum Physics · Physics 2017-08-29 Ming Li , Alexander Petrov , Constantinos Makrides , Eite Tiesinga , Svetlana Kotochigova

In experiments with trapped atoms, atomic energy levels are shifted by the trapping optical and magnetic fields. Regardless of this strong perturbation, precision spectroscopy may be still carried out using specially crafted, "magic"…

Quantum Gases · Physics 2015-05-18 Andrei Derevianko

Extending the search for the magic wavelengths using the circularly polarized light in rubidium [Phys. Rev. A 86, 033416 (2012)], we pursue here to look for the magic wavelengths in the $ns-np_{1/2,3/2}$ transitions of Li, Na and K alkali…

Atomic Physics · Physics 2015-06-12 B. K. Sahoo , Bindiya Arora

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

We demonstrate a versatile, rotational-state dependent trapping scheme for the ground and first excited rotational states of $^{23}$Na$^{40}$K molecules. Close to the rotational manifold of a narrow electronic transition, we determine…

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