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In this paper, we formulate a field-theoretical model of dilute salt solutions of electrically neutral spherical colloid particles. Each colloid particle consists of a 'central' charge that is situated at the center and compensating…

Soft Condensed Matter · Physics 2020-01-08 Yu. A. Budkov

Using self-assembly techniques, x-ray reflectivity measurements, and computer simulations, we study the effective interaction between charged polymer rods and surfaces. Long-time Brownian dynamics simulations are used to measure the…

Soft Condensed Matter · Physics 2009-10-31 R. Jay Mashl , Niels Grønbech-Jensen , M. R. Fitzsimmons , M. Lütt , DeQuan Li

The effect of fixed discrete colloidal charges in the primitive model is investigated for spherical macroions. Instead of considering a central bare charge, as it is traditionally done, we distribute \textit{discrete} charges randomly on…

Soft Condensed Matter · Physics 2009-10-31 Rene Messina , Christian Holm , Kurt Kremer

A binary mixture of oppositely charged components confined to a plane such as cationic and anionic lipid bilayers may exhibit local segregation. The relative strength of the net short range interactions, which favors macroscopic…

Soft Condensed Matter · Physics 2009-11-11 Sharon M. Loverde , Yury S. Velichko , Monica Olvera de la Cruz

To gain some insight into electrochemical activity of dielectric colloids of technical and biomedical interest we investigate a model of dielectric nanosolution whose micro-constitution is dominated by dipolarions -- positively and…

Soft Condensed Matter · Physics 2014-03-27 Sergey Bastrukov , Pik-Yin Lai , Irina Molodtsova

We examine binary mixtures of superparamagnetic colloidal particles confined to a two-dimensional water-air interface both by real-space experiments and Monte-Carlo computer simulations at high coupling strength. In the simulations, the…

Soft Condensed Matter · Physics 2015-05-13 L Assoud , F Ebert , P Keim , R Messina , G Maret , H Löwen

We investigate numerically and on the scaling level the adsorption of a charged colloid on an oppositely charged flexible membrane. We show that the long ranged character of the electrostatic interaction leads to a wrapping reentrance of…

Biological Physics · Physics 2009-11-10 Christian C. Fleck , Roland R. Netz

We study a classical system of identically charged counter-ions near a planar wall carrying a uniform surface charge density. The equilibrium statistical mechanics of the system depends on a single dimensionless coupling parameter. A new…

Soft Condensed Matter · Physics 2019-01-21 I. Palaia , M. Trulsson , L. Samaj , E. Trizac

An approach is proposed which allows to self-consistently calculate the structural and thermodynamic properties of highly charged aqueous colloidal suspensions. The method is based on the renormalized Jellium model with the background…

Soft Condensed Matter · Physics 2009-10-27 Thiago E. Colla , Yan Levin , E. Trizac

We propose the use of topographic modulation of surfaces to select and localize particles in nematic colloids. By considering convex and concave deformations of one of the confining surfaces we show that the colloid-flat surface repulsion…

Soft Condensed Matter · Physics 2014-10-15 Z. Eskandari , N. M. Silvestre , M. M. Telo da Gama , M. R. Ejtehadi

The addition of enough non-adsorbing polymer to an otherwise stable colloidal suspension gives rise to a variety of phase behavior and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a…

Soft Condensed Matter · Physics 2024-06-19 Sam E Griffiths , Nick Koumakis , Aidan T Brown , Teun Vissers , Patrick B Warren , Wilson C K Poon

The contact value of the charge profile for nonsymmetrical electrolytes is presented as the sum of three contributions. One of them is the normal component of the Maxwell electrostatic stress tensor. The second one is the surface…

Statistical Mechanics · Physics 2009-11-13 M. Holovko , D. di Caprio

Polymer chains adsorbed onto oppositely charged spherical colloidal particles can significantly modify the particle-particle interactions. For sufficient amounts of added polymers, the original electrostatic repulsion can even turn into an…

Soft Condensed Matter · Physics 2015-05-13 D. Truzzolillo , F. Bordi , F. Sciortino , C. Cametti

The ionic composition and pair correlations in fluid phases of realistically salt-free charged colloidal sphere suspensions are calculated in the primitive model. We obtain the number densities of all ionic species in suspension, including…

Soft Condensed Matter · Physics 2014-03-28 Marco Heinen , Thomas Palberg , Hartmut Löwen

In this thesis, the electrostatic interaction between two chemically identical colloids, both carrying constant surface potential is studied in the limit of short inter-particle separation at the interface of two immiscible fluids. Using an…

Soft Condensed Matter · Physics 2020-01-01 Rick Bebon

Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Ludger Harnau , S. Dietrich

Recently, the celebrated Keldysh potential has been widely used to describe the Coulomb interaction of few-body complexes in monolayer transition-metal dichalcogenides. Using this potential to model charged excitons (trions), one finds a…

Materials Science · Physics 2018-10-03 Dinh Van Tuan , Min Yang , Hanan Dery

A simple field theory approach is developed to model the properties of charged, dielectric bodies and their associated counterions. This predictive theory is able to accurately describe the properties of systems (as compared to computer…

Soft Condensed Matter · Physics 2009-01-20 Marius M. Hatlo , Leo Lue

Monte Carlo simulations were employed to study two charged rods confined between two unlike charged plates, all immersed in a model electrolyte. Recently, it was shown that two rods immersed in a multivalent counterion solution may show…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 G. Odriozola , F. Jiménez-Ángeles , M. Lozada-Cassou

A simple theory of the fluid state of a charged colloidal suspension is proposed. The full free energy of a polyelectrolyte solution is calculated. It is found that the counterions condense onto the polyions forming clusters composed of one…

Soft Condensed Matter · Physics 2009-10-30 Yan Levin , Marcia C. Barbosa , M. N. Tamashiro