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A dynamical model is proposed to describe the coupled decomposition and profile evolution of a free surface film of a binary mixture. An example is a thin film of a polymer blend on a solid substrate undergoing simultaneous phase separation…

Fluid Dynamics · Physics 2013-03-25 Uwe Thiele , Santiago Madruga , Lubor Frastia

Fluids made of two-dimensional hard particles with polygonal shapes may stabilize symmetries which do not result directly from the particle shape. This is due to the formation of clusters in the fluid. Entropy alone can drive these effects,…

Soft Condensed Matter · Physics 2024-02-05 Yuri Martinez-Raton , Enrique Velasco

A microscopic density functional theory is used to investigate the adsorption of short chains on attractive solid surfaces. We analyze the structure of the adsorbed fluid and investigate how the wetting transition changes with the change of…

Soft Condensed Matter · Physics 2007-05-23 P. Bryk , S. Sokolowski

Using dynamical density functional theory (DDFT), we theoretically study Brownian self-diffusion and structural relaxation of hard disks and compare to experimental results on quasi two-dimensional colloidal hard spheres. To this end, we…

Soft Condensed Matter · Physics 2018-04-04 Daniel Stopper , Alice Thorneywork , Roel Dullens , Roland Roth

Density functional theory is used to study colloidal hard-rod fluids near an individual right-angled wedge or edge as well as near a hard wall which is periodically patterned with rectangular barriers. The Zwanzig model, in which the…

Soft Condensed Matter · Physics 2009-11-10 L. Harnau , F. Penna , S. Dietrich

Drying of fluids undergoing sol-gel transition in porous media, a process crucial for the consolidation of damaged porous structures in cultural heritage, often leads to skin formation at the surface. This phenomenon significantly hinders…

Soft Condensed Matter · Physics 2025-09-29 Romane Le Dizès Castell , Marc Prat , Noushine Shahidzadeh , Sara Jabbari-Farouji

Drying complex fluids is a common phenomenon where a liquid phase transforms into a dense or porous solid. This transformation involves several physical processes, such as the diffusion of liquid molecules into the surrounding atmosphere…

Fluid Dynamics · Physics 2023-06-21 Ranajit Mondal , Hisay Lama , Kirti Chandra Sahu

We performed a thorough investigation of the drying dynamics of a charged colloidal dispersion drop in a confined geometry. We developed an original methodology based on Raman micro-spectroscopy to measure spatially-resolved colloids…

Soft Condensed Matter · Physics 2016-12-13 Charles Loussert , Anne Bouchaudy , Jean-Baptiste Salmon

The influence of poor solvent quality on fluid demixing of a model mixture of colloids and nonadsorbing polymers is investigated using density functional theory. The colloidal particles are modelled as hard spheres and the polymer coils as…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

Microswimmers typically operate in complex environments. In biological systems, often diverse species are simultaneously present and interact with each other. Here, we derive a (time-dependent) particle-scale statistical description, namely…

Soft Condensed Matter · Physics 2019-08-13 Christian Hoell , Hartmut Löwen , Andreas M. Menzel

Understanding the nanoscale effects controlling the dynamics of a contact line -- defined as the line formed at the junction of two fluid phases and a solid -- has been a longstanding problem in fluid mechanics pushing experimental and…

Fluid Dynamics · Physics 2025-01-06 Andreas Nold , Benjamin D. Goddard , David N. Sibley , Serafim Kalliadasis

We study the distribution of colloidal particles confined in drying spherical droplets using both dynamic density functional theory (DDFT) and particle-based simulations. In particular, we focus on the advection-dominated regime typical of…

Soft Condensed Matter · Physics 2025-01-24 Mayukh Kundu , Kritika Kritika , Yashraj M. Wani , Arash Nikoubashman , Michael P. Howard

A fundamental assumption of the dynamical density functional theory (DDFT) of colloidal systems is that a grand-canonical free energy functional may be employed to generate the thermodynamic driving forces. Using one-dimensional hard-rods…

Soft Condensed Matter · Physics 2013-06-04 Johannes Reinhardt , Joseph Michael Brader

Density-functional theory is a formally exact description of a many-body quantum system in terms of its density; in practice, however, approximations to the universal density functional are required. In this work, a model based on deep…

Computational Physics · Physics 2016-08-02 Jeffrey M. McMahon

We study the dynamics of a colloidal fluid including inertia and hydrodynamic interactions, two effects which strongly influence the non-equilibrium properties of the system. We derive a general dynamical density functional theory (DDFT)…

Statistical Mechanics · Physics 2012-09-24 Benjamin D. Goddard , Andreas Nold , Nikos Savva , Grigorios A. Pavliotis , Serafim Kalliadasis

An efficient way to precisely pattern particles on solid surfaces is to dispense and evaporate colloidal drops, as for bioassays. The dried deposits often exhibit complex structures exemplified by the coffee ring pattern, where most…

Fluid Dynamics · Physics 2015-05-20 Rajneesh Bhardwaj , Xiaohua Fang , Daniel Attinger

Dewetting of a binary alloy thin film is studied using a continuum many-parameter model that accounts for the surface and bulk diffusion, the bulk phase separation, the surface segregation and the particles formation. Analytical solution is…

Materials Science · Physics 2018-01-19 Mikhail Khenner

Wrinkling instabilities of thin elastic sheets can be used to generate periodic structures over a wide range of length scales. Viscosity of the thin elastic sheet or its surrounding medium has been shown to be responsible for dynamic…

Soft Condensed Matter · Physics 2024-01-25 Veit Krause , Axel Voigt

Motivated by recent studies on the dynamics of colloidal solutions in narrow channels, we consider the steady state properties of an assembly of non interacting particles subject to the action of a traveling potential moving at a constant…

Soft Condensed Matter · Physics 2009-11-13 Pedro Tarazona , Umberto Marini Bettolo Marconi

Using dynamical density functional theory we calculate the speed of solidification fronts advancing into a quenched two-dimensional model fluid of soft-core particles. We find that solidification fronts can advance via two different…

Soft Condensed Matter · Physics 2014-10-22 A. J. Archer , M. C. Walters , U. Thiele , E. Knobloch
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