Related papers: A note on Kauzmann's paradox
We perform kinetic Monte Carlo simulations of a distinguishable-particle lattice model of structural glasses with random particle interactions. By varying the interaction distribution and the average particle hopping energy barrier, we…
We consider the effect of droplet excitations in the random first order transition theory of glasses on the configurational entropy. The contribution of these excitations is estimated both at and above the ideal glass transition…
The nature of the glass transition is theoretically understood in the mean-field limit of infinite spatial dimensions, but the problem remains totally open in physical dimensions. Nontrivial finite-dimensional fluctuations are hard to…
The liquid and supercooled states of water show a series of anomalies whose nature is debated. A key role is attributed to the formation of structural aggregates induced by critical phenomena occurring deep in the supercooled region; the…
Glassy solids exhibit a wide variety of generic thermomechanical properties, ranging from universal anomalous specific heat at cryogenic temperatures to nonlinear plastic yielding and failure under external driving forces, which…
Nearly-logarithmic decay of correlations, which was observed for several supercooled liquids in optical-Kerr-effect experiments [G. Hinze et al. Phys. Rev. Lett. 84, 2437(2000), H. Cang et al. Phys. Rev. Lett. 90, 197401 (2003)], is…
After negative temperature is restated, we find that it will derive necessarily decrease of entropy. Negative temperature is based on the Kelvin scale and the condition dU>0 and dS<0. Conversely, there is also negative temperature for dU<0…
We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in…
We discuss the microscopic mechanisms by which low-temperature amorphous states, such as ultrastable glasses, transform into equilibrium fluids, after a sudden temperature increase. Experiments suggest that this process is similar to the…
We apply microcanonical ensemble considerations to suggest that, whenever it may thermalize, a general disorder-free many-body Hamiltonian of a typical atomic system has solid-like eigenstates at low energies and fluid-type (and gaseous,…
We discuss a theoretical approach to structural glasses as they happen in real situations. Older ideas based on `configurational entropy', on `fictive temperatures' and on Edwards' `compactivity' are sharpened and unified in an out of…
A popular Adam--Gibbs scenario has suggested that the excess entropy of glass and liquid over crystal dominates the dynamical arrest at the glass transition with exclusive contribution from configurational entropy over vibrational entropy.…
While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…
In work [1] ("Temperature dependence of ultracold neutron loss rates" E.Korobkina et al., PRB 70,035409) results of measurement of temperature dependence of losses of ultracold neutrons (UCN) in a range from 4 K to 300 K at UCN storage in a…
The metastable states of a glass are counted by adding a weak pinning field which explicitly breaks the ergodicity. Their entropy, that is the logarithm of their number, is extensive in a range of temperatures $T_G < T < T_C$ only, where…
When classical systems fail to explore their entire configurational space, intriguing macroscopic phenomena like aging and glass formation may emerge. Also closed quanto-mechanical systems may stop wandering freely around the whole Hilbert…
A simple, non-disordered spin model has been studied in an effort to understand the origin of the precipitous slowing down of dynamics observed in supercooled liquids approaching the glass transition. A combination of Monte Carlo…
Quantum effects in material systems are often pronounced at low energies and become insignificant at high temperatures. We find that, perhaps counterintuitively, certain quantum effects may follow the opposite route and become sharp when…
Fermi liquid theory forms the basis for our understanding of the majority of metals, which is manifested in the description of transport properties that the electrical resistivity goes as temperature squared in the limit of zero…
We report a wavelike fracture pattern in a Zr-based bulk metallic glass that has been deformed under quasi-static uniaxial tensions at temperatures between room temperature (300 K) and liquid nitrogen temperature (77 K). We attribute this…