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Intercalation of two dimensional materials, particularly transition metal dichalcogenides, is a noninvasive way to modify electronic, optical and structural properties of these materials. However, research of these atomic-scale phenomena…

In this work we study the intercalation of monolayer phosphorene with nitrogen, lithium and calcium for exploring prospects of spintronic applications. The electronic and the magnetic properties of the intercalated structure are…

Materials Science · Physics 2021-02-03 S. Koley , S. Basu

The monolayer of black phosphorous, or phosphorene, has recently emerged as a new 2D semiconductor with intriguing highly anisotropic transport properties. Existing calculations of its intrinsic phonon-limited electronic transport…

Materials Science · Physics 2015-06-24 Bolin Liao , Jiawei Zhou , Bo Qiu , Mildred S. Dresselhaus , Gang Chen

Thin layers of black phosphorus present an ideal combination of a 2D material with a tunable direct bandgap and high carrier mobility. However the material suffers from degradation in ambient conditions due to an oxidation reaction which…

The incorporation of electrically tunable materials into photonic structures such as waveguides and metasurfaces enables dynamic control of light propagation by an applied potential. While many materials have been shown to exhibit…

Mesoscale and Nanoscale Physics · Physics 2017-10-03 Michelle C. Sherrott , William S. Whitney , Deep Jariwala , Cora M. Went , Joeson Wong , George R. Rossman , Harry A. Atwater

Controlling the bandgap through local-strain engineering is an exciting avenue for tailoring optoelectronic materials. Two-dimensional crystals are particularly suited for this purpose because they can withstand unprecedented…

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

Mesoscale and Nanoscale Physics · Physics 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

Black phosphorus is a monoatomic semiconducting layered material that degrades exothermically in the presence of light and ambient contaminants. Its degradation dynamics remain largely unknown. Even before degradation, local-probe studies…

Recently rediscovered black phosphorus is a layered semiconductor with promising electronic and photonic properties. Dynamic control of its bandgap can enable novel device applications and allow for the exploration of new physical…

Mesoscale and Nanoscale Physics · Physics 2017-04-21 Bingchen Deng , Vy Tran , Hao Jiang , Cheng Li , Yujun Xie , Qiushi Guo , Xiaomu Wang , He Tian , Han Wang , Judy J. Cha , Qiangfei Xia , Li Yang , Fengnian Xia

Two-dimensional crystals have emerged as a new class of materials with novel properties that may impact future technologies. Experimentally identifying and characterizing new functional two-dimensional materials in the vast material pool is…

Materials Science · Physics 2015-06-18 Likai Li , Yijun Yu , Guo Jun Ye , Qingqin Ge , Xuedong Ou , Hua Wu , Donglai Feng , Xian Hui Chen , Yuanbo Zhang

Two-dimensional black phosphorus has been configured as field-effect transistors, showing an intrinsic symmetric ambipolar transport characteristic. Here, we demonstrate the strongly modulated ambipolar characteristics of few-layer black…

Materials Science · Physics 2016-03-10 Cheng Han , Zehua Hu , Jialin Zhang , Fang Hu , Du Xiang , Jing Wu , Bo Lei , Li Wang , Wen Ping Hu , Wei Chen

Black phosphorus (P) has emerged as a layered semiconductor with a unique crystal structure featuring corrugated atomic layers and strong in-plane anisotropy in its physical properties. Here, we demonstrate that the crystal orientation and…

Mesoscale and Nanoscale Physics · Physics 2016-09-27 Zenghui Wang , Hao Jia , Xu-Qian Zheng , Rui Yang , G. J. Ye , X. H. Chen , Philip X. -L. Feng

Few-layer black phosphorus was recently rediscovered as a narrow-bandgap atomically thin semiconductor and has already attracted unprecedented attention due to its interesting properties. One feature of this material that sets it apart from…

Mesoscale and Nanoscale Physics · Physics 2017-04-04 Artem Mishchenko , Yang Cao , Geliang Yu , Colin R. Woods , Roman V. Gorbachev , Kostya S. Novoselov , Andre K. Geim , Leonid S. Levitov

Phosphorus pentamer (cyclo-P5-) ions are unstable in nature but can be synthesized at the Ag(111) surface. Unlike monolayer black phosphorous, little is known about their electronic properties when in contact with metal electrodes, although…

Introducing foreign ions, atoms, or molecules into emerging functional materials is crucial for manipulating material physical properties and innovating device applications. The intercalation of emerging new materials can induce multiple…

Applied Physics · Physics 2024-10-15 Xin He , Hua Wang , Jian Sun , Xixiang Zhang , Kai Chang , Fei Xue

We examine the electronic properties of 2D electron gas in black phosphorus multilayers in the presence of a perpendicular magnetic field, highlighting the role of in-plane anisotropy on various experimental quantities such as ac…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 Yongjin Jiang , Rafael Roldán , Francisco Guinea , Tony Low

We investigate theoretically the anisotropic electronic and optical behaviors of a monolayer black phosphorus (phosphorene) modulated by periodic potential superlattices in arbitrary directions. We demonstrate that different strength and…

Mesoscale and Nanoscale Physics · Physics 2019-12-17 Xiaojing Li , Wen Yang , Kun Luo , Zhenhua Wu

Ambipolar black phosphorus MOSFETs with record n-channel extrinsic transconductance are reported. The devices consist of multi-layer black phosphorus aligned to a local back-gate electrode with 10-nm-thick HfO2 gate dielectric. Before…

Mesoscale and Nanoscale Physics · Physics 2015-12-01 Nazila Haratipour , Steven J. Koester

We use an atomistic approach to study the electronic properties of monolayer and bilayer black phosphorus in the vicinity of a charged defect. In particular, we combine screened defect potentials obtained from first-principles linear…

Materials Science · Physics 2021-12-21 Martik Aghajanian , Arash A. Mostofi , Johannes Lischner

Properties of many layered materials, including copper- and iron-based superconductors, topological insulators, graphite and epitaxial graphene can be manipulated by inclusion of different atomic and molecular species between the layers via…

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