Related papers: Thermodynamic geometry of the Gaussian core model …
We evaluate the thermodynamic curvature $R$ for fluid argon, hydrogen, carbon dioxide, and water. For these fluids, $R$ is mostly negative, but we also find significant regimes of positive $R$, which we interpret as indicating solid-like…
The new mathematical framework based on the free energy of pure classical fluids presented in [R. D. Rohrmann, Physica A 347, 221 (2005)] is extended to multi-component systems to determine thermodynamic and structural properties of…
A number of simple pair interaction potentials of the carbon dioxide molecule are investigated and found to underestimate the magnitude of the second virial coefficient in the temperature interval 220 K to 448 K by up to 20%. Also the third…
This work tests the statistical mechanical theory of hydrophobic interactions, isolates consequences of excluded volume interactions, and obtains B2 for those purposes. Cavity methods that are particularly appropriate for study of…
The square-well fluid with hard-sphere diameters is studied within the framework of Thermodynamic Geometry (TG). Coexistence and spinodal curves, as well as the Widom line for ranges $\lambda^{*} = 1.25, 1.5, 2.0, 3.0$ for this fluid are…
Singularities in the thermodynamics of Kerr-Newman black holes are commonly associated with phase transitions. However, such interpretations are complicated by a lack of stability and, more significantly, by a lack of conclusive insight…
Microscopic models of realistic thermodynamic systems usually involve a number of parameters, not all of equal macroscopic relevance. We examine a decorated $(1+3)$ Ising spin chain containing two microscopic parameters: a "stiff" $K$…
Bending rigidities of tensionless balanced liquid-liquid interfaces as occurring in microemulsions are predicted using self-consistent field theory for molecularly inhomogeneous systems. Considering geometries with scale invariant curvature…
Using Monte Carlo simulations a lattice gas model with only repulsive interactions was checked for the presence of anomalies. We show that this system exhibits the density (temperature of maximum density - TMD) and diffusion anomalies as…
The geometry of thermodynamic state space is studied for asymptotically anti-de Sitter black holes in D-dimensional space times. Convexity of thermodynamic potentials and the analytic structure of the response functions is analysed. The…
On the basis of a microscopic model of self-consistent field, the thermodynamics of the many-particle Fermi system at finite temperatures with account of three-body interactions is built and the quasiparticle equations of motion are…
We have identified the ground state configurations of soft particles (interacting via inverse power potentials) confined between two hard, impenetrable walls. To this end we have used a highly reliable optimization scheme at {\it vanishing}…
We study a cell fluid model of a many-particle system with Curie-Weiss-type interaction potential. It is considered as an open system in a fixed volume partitioned into a large number of congruent cubic cells. The interaction potential…
In this paper we derive an equation of state for liquid cesium based on a suggested potential function in accord to the characteristics large attraction and soft repulsion at the asymptotes of interaction potentials. By considering the…
A simple model of dimerizing hard spheres with highly nontrivial fluid-solid phase behaviour is proposed. The model is studied using the recently proposed resummed thermodynamic perturbation theory for central force (RTPT-CF) associating…
We study the dynamics of a heavy particle of mass $M$ moving in a one-dimensional repulsively interacting Fermi gas. The Fermi gas is described using the Luttinger model and bosonization. By transforming to a frame co-moving with the heavy…
Liquid water has anomalous liquid properties, such as its density maximum at 4\degree C. An attempt at theoretical explanation proposes a liquid-liquid phase transition line in the supercooled liquid state, with coexisting low-density (LDL)…
We report the effect of including repulsive interactions on various thermodynamic observables calculated using a S-matrix based Hadron Resonance Gas (HRG) model to already available corresponding results with only attractive interactions…
We study the thermodynamics of soft wall model in AdS/QCD framework. The low temperature phase of QCD is described by thermal AdS and high temperature phase by AdS Black hole solution of five dimensional gravity with negative cosmological…
We numerically study crystal nucleation and glassy slow dynamics of the one-component Gaussian core model (GCM) at high densities. The nucleation rate at a fixed supersaturation is found to decrease as the density increases. At very high…