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Ionic liquids constrained at interfaces or restricted in subnanometric pores are increasingly employed in modern technologies, including energy applications. Understanding the details of their behavior in these conditions is therefore…

Materials Science · Physics 2018-09-25 Stefano Mossa

Experimental studies were carried out on the motions and transformations of liquid metal in ionic liquid under applied electric field. The induced vortex rings and flows of ionic liquid were determined via the photographs taken sequentially…

Fluid Dynamics · Physics 2017-04-13 Fujun Liu , Yongze Yu , Jing Liu

Brownian Dynamics simulations are carried out to understand the effect of temperature and dielectric constant of the medium on microphase separation of charged-neutral diblock copolymer systems. For different dielectric media, we focus on…

Soft Condensed Matter · Physics 2011-07-20 Monojoy Goswami , Rajeev Kumar , Bobby G. Sumpter , Jimmy Mays

Electrical charging of parallel plates confining a model ionic liquid down to nanoscale distances yields a variety of charge-induced changes in the structural features of the confined film. That includes even-odd switching of the structural…

Materials Science · Physics 2015-06-23 R. Capozza , A. Vanossi , A. Benassi , E. Tosatti

A statistical-type model is developed to describe the ion production and electron emission in collisions of (molecular) ions with atoms. The model is based on the Boltzmann population of the bound electronic energy levels of the quasi…

Atomic Physics · Physics 2016-08-19 Zoltán Juhász

Electrohydrodynamic instabilities of fluid-fluid interfaces can be exploited in various microfluidic applications in order to enhance mixing, replicate well-controlled patterns or generate drops of a particular size. In this work, we study…

Fluid Dynamics · Physics 2021-06-29 Mohammadhossein Firouznia , David Saintillan

The present paper report is focused toward the preparation of the flexible and freestanding blend solid polymer electrolyte films based on PEO-PVP complexed with NaPF6 by solution cast technique. The structural/morphological features of the…

Materials Science · Physics 2018-07-12 Anil Arya , A. L. Sharma*

Nonlinear behavior of electro-osmosis in dilute non-adsorbing polymer solutions with low salinity is investigated with Brownian dynamics simulations and a kinetic theory. In the Brownian simulations, the hydrodynamic interaction between the…

Soft Condensed Matter · Physics 2015-06-19 Yuki Uematsu

Electrochemical devices often consist of multicomponent electrolyte solutions. Two processes influence the overall dynamics of these devices: the formation of electrical double layers and chemical conversion due to redox reactions. However,…

Chemical Physics · Physics 2022-06-20 Nathan Jarvey , Filipe Henrique , Ankur Gupta

A model is developed for describing the transport of charged colloidal particles in an evaporating sessile droplet on the electrified metal substrate in the presence of a solvent flow. The model takes into account the electric charge of…

Soft Condensed Matter · Physics 2022-03-16 Semen V. Zavarzin , Andrei L. Kolesnikov , Yury A. Budkov , Lev Yu. Barash

Stretching dynamics of polymers in microfluidics is of particular interest for polymer scientists. As a charged polymer, a polyelectrolyte can be deformed from its coiled equilibrium configuration to an extended chain by applying uniform or…

Soft Condensed Matter · Physics 2014-11-18 Farnoush Farahpour , Fathollah Varnik , Mohammad Reza Ejtehadi

Electro-thermal poling experiments were carried out on a bioactive glass, and the kinetics of the Na+ ion depletion layer formation under the anode was studied in-situ by means of ac impedance spectroscopy. One important finding is a linear…

Materials Science · Physics 2008-10-03 C. R. Mariappan , B. Roling

As an anode material for lithium-ion batteries, amorphous silicon offers a significantly higher energy density than the graphite anodes currently used. Alloying reactions of lithium and silicon, however, induce large deformation and lead to…

Numerical Analysis · Mathematics 2024-08-07 Raphael Schoof , Johannes Niermann , Alexander Dyck , Thomas Böhlke , Willy Dörfler

We model the flow behaviour of dense melts of flexible and semiflexible ring polymers in the presence of walls using a hybrid multiscale approach. Specifically, we perform molecular dynamics simulations and apply the Irving-Kirkwood formula…

Numerical Analysis · Mathematics 2026-05-25 Ranajay Datta , Mária Lukáčová-Medviďová , Andreas Schömer , Peter Virnau

Recent experiments and simulations have demonstrated that particle-covered interfaces can exist in stable non-spherical shapes as a result of the steric jamming of the interfacially trapped particles, which confers the interface with…

Soft Condensed Matter · Physics 2010-11-23 Anand Bala Subramaniam , Manouk Abkarian , L. Mahadevan , Howard A. Stone

Boosting the sensitivity of solid-state gas sensors by incorporating nanostructured materials as the active sensing element can be complicated by interfacial effects. Interfaces at nanoparticles, grains, or contacts may result in non-linear…

Electroactive-Polymers (EAPs) are one of the best soft materials with great applications in active microfluidics. Ionic ones (i-EAPs) have more promising features for being appropriate candidates to use in active microfluidic devices. Here,…

Quantitative Methods · Quantitative Biology 2019-10-10 Mohsen Annabestani , Sina Azizmohseni , Pouria Esmaeili-Dokht , Nahal Bagheri , Afarin Aghassizadeh and , Mahdi Fardmanesh

Morphology of polymer electrolytes membranes (PEM), e.g., Nafion, inside PEM fuel cell catalyst layers has significant impact on the electrochemical activity and transport phenomena that determine cell performance. In those regions, Nafion…

Materials Science · Physics 2015-01-27 Daiane Damasceno Borges , Gerard Gebel , Alejandro A. Franco , Kourosh Malek , Stefano Mossa

Understanding the structure and thermodynamics of solvated ions is essential for advancing applications in electrochemistry, water treatment, and energy storage. While ab initio molecular dynamics methods are highly accurate, they are…

Chemical Physics · Physics 2025-07-15 Ademola Soyemi , Tibor Szilvasi

The associative interaction, such as hydrogen bonding, can bring about versatile functionalities to polymer systems, which has been investigated by tremendous researches, but the fundamental understanding on association process is still…

Soft Condensed Matter · Physics 2025-01-20 Xiangyu Zhang , Dong Meng