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We analyze the exciton dynamics in PhotosystemI from Thermosynechococcus elongatus using the distributed memory implementation of the hierarchical equation of motion (DM-HEOM) for the 96 Chlorophylls in the monomeric unit. The…

We provide a unified theoretical approach to the quantum dynamics of absorption of single photons and subsequent excitonic energy transfer in photosynthetic light-harvesting complexes. Our analysis combines a continuous mode <n>-photon…

Chemical Physics · Physics 2018-02-20 Herman C. H. Chan , Omar E. Gamel , Graham R. Fleming , K. Birgitta Whaley

Elucidating quantum coherence effects and geometrical factors for efficient energy transfer in photosynthesis has the potential to uncover non-classical design principles for advanced organic materials. We study energy transfer in a linear…

Biological Physics · Physics 2013-07-30 Qing Ai , Tzu-Chi Yen , Bih-Yaw Jin , Yuan-Chung Cheng

Photosynthetic complexes improve the transfer of excitation energy from peripheral antennas to reaction centers in several ways. In particular, a downward energy funnel can direct excitons in the right direction, while coherent excitonic…

Biological Physics · Physics 2016-03-04 Sima Baghbanzadeh , Ivan Kassal

The question of how quantum coherence facilitates energy transfer has been intensively debated in the scientific community. Since natural and artificial light-harvesting units operate under the stationary condition, we address this question…

Chemical Physics · Physics 2020-07-22 Pei-Yun Yang , Jianshu Cao

Answering the titular question has become a central motivation in the field of quantum biology, ever since the idea was raised following a series of experiments demonstrating wave-like behavior in photosynthetic complexes. Here, we report a…

Biological Physics · Physics 2021-03-05 Elinor Zerah-Harush , Yonatan Dubi

Photosystem II (PSII) and its associated light-harvesting complex II (LHCII) are highly concentrated in the stacked grana regions of photosynthetic thylakoid membranes. Within the membrane, PSII-LHCII supercomplexes can be arranged in…

Soft Condensed Matter · Physics 2015-06-15 Anna R. Schneider , Phillip L. Geissler

We discuss our recent theoretical work on vibronic coupling mechanisms in a model energy transfer system in the context of previous 2DEV experiments on a natural light-harvesting system, light-harvesting complex II (LHCII), where vibronic…

Chemical Physics · Physics 2021-09-22 Eric A. Arsenault , Addison J. Schile , David T. Limmer , Graham R. Fleming

Light-harvesting bacteria Rhodospirillum Photometricum were recently found to adopt strikingly different architectures depending on illumination conditions. We present analytic and numerical calculations which explain this observation by…

Soft Condensed Matter · Physics 2015-05-18 Felipe Caycedo-Soler , Ferney J. Rodriguez , Luis Quiroga , Neil F. Johnson

We study here the collective quantum optical effect of superradiance in neuroprotein architectures. This phenomenon arises from the interaction of the electromagnetic field with an organized network of tryptophan chromophores, where each…

Biological Physics · Physics 2026-04-15 Hamza Patwa , Nathan S. Babcock , Philip Kurian

We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…

Chemical Physics · Physics 2016-07-27 Jan J. J. Roden , Doran I. G. Bennett , K. Birgitta Whaley

Research into the efficiency of photosynthetic light harvesting has focused on two factors: (1) entanglement of chromophores, and (2) environmental noise. While chromophores are conjugated $\pi$-bonding molecules with strongly correlated…

Biological Physics · Physics 2013-03-29 David A. Mazziotti

The extent of exciton coherence in protein-pigment complexes has significant implications for the initial light harvesting step in photosynthetic organisms. In this work we model the main antenna protein of photosystem II, namely light…

Other Condensed Matter · Physics 2008-12-09 Jiahao Chen , Nancy Makri

Quantum fluids of light merge many-body physics and nonlinear optics, through the study of light propagation in a nonlinear medium under the shine of quantum hydrodynamics. One of the most outstanding evidence of light behaving as an…

We analyze a theoretical model for energy and electron transfer in an artificial photosynthetic system. The photosystem consists of a molecular triad (i.e., with a donor, a photosensitive unit, and an acceptor) coupled to four accessory…

Biological Physics · Physics 2015-05-20 Pulak Kumar Ghosh , Anatoly Yu. Smirnov , Franco Nori

The remarkable rotational symmetry of the photosynthetic antenna complexes of purple bacteria has long been thought to enhance their light harvesting and excitation energy transport. We study the role of symmetry by modeling hypothetical…

Chemical Physics · Physics 2016-09-20 Sima Baghbanzadeh , Ivan Kassal

Stunningly large exciton transfer rates in the light harvesting complex of photosynthesis, together with recent experimental 2D spectroscopic data, have spurred a vivid debate on the possible quantum origin of such efficiency. Here we show…

Quantum Physics · Physics 2011-08-29 Torsten Scholak , Thomas Wellens , Andreas Buchleitner

A variety of open quantum networks are currently under intense examination to model energy transport in photosynthetic systems. Here we study the coherent transfer of a quantum excitation over a network incoherently coupled with a…

Quantum Physics · Physics 2015-03-18 Lorenzo Campos Venuti , Paolo Zanardi

Photosynthesis first step mechanism concerns the sunlight absorption and both negative and positive charges separation. Recent and important photosynthesis literature claims that this mechanism is quantum mechanics controlled, however…

Photosystem II (PSII) reaction center is a unique protein-chromophore complex that is capable of efficiently separating electronic charges across the membrane after photoexcitation. In the PSII reaction center, the primary energy- and…