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Binary hydrides formed by the pnictogens of phosphorus, arsenic and antimony are studied at high pressures using first principles methods. Stable structures are predicted and their electronic, vibrational and superconducting properties are…

Superconductivity at temperatures up to 190 K at high pressures has recently been observed in $H_2S$ and interpreted as conventional BCS-electron-phonon-driven superconductivity.\cite{h2s} Instead we propose that it is another example of…

Superconductivity · Physics 2015-04-24 J. E. Hirsch , F. Marsiglio

We calculated the superconductivity properties of alkali metals under high pressure using the results of band theory and the rigid-muffin-tin theory of Gaspari and Gyorffy. Our results suggest that at high pressures Lithium, Potassium,…

Superconductivity · Physics 2009-11-11 Lei Shi , Dimitrios A. Papaconstantopoulos

Hydrogen-based compounds have attracted significant attention in recent years due to the discovery of conventional superconductivity with high critical temperature under high pressure, rekindling hopes for searching room temperature…

Superconductivity · Physics 2024-11-20 Yao Ma , Mingqi Li , Wenjia Shi , Vei Wang , Pugeng Hou , Mi Pang

With the motivation of searching for new superconductors in the Mg-B system, we performed ab initio evolutionary searches for all the stable compounds in this binary system in the pressure range of 0-200 GPa. We found previously unknown,…

Superconductivity · Physics 2017-05-24 M. M. Davari Esfahani , Q. Zhu , H. Dong , A. R. Oganov , S. Wang , M. S. Rakitin , X-F. Zhou

Pressure-induced superconductivity and structural phase transitions in phosphorous (P) are studied by resistivity measurements under pressures up to 170 GPa and fully $ab-initio$ crystal structure and superconductivity calculations up to…

The trigonal ${\alpha}$-HgS has a 3-fold helical chain structure, and is in form of a noncentrosymmetric $P3_121$ phase, known as the cinnabar phase. However, under pressure, the helical chains gradually approach and connect with each…

Superconductivity · Physics 2023-12-29 He Zhang , Wei Zhong , Yanghao Meng , Bowen Tang , Binbin Yue , Xiaohui Yu , Fang Hong

We develop a first-principles framework for finite-temperature structural optimization that incorporates vibrational contributions to the free energy through anharmonic phonon theory. We extend and further improve the efficiency of the…

Superconductivity · Physics 2025-12-10 Ryoma Asai , Ryotaro Arita , Takumi Chida , Ryota Masuki , Kazuhiko Kuroki , Terumasa Tadano

We report X-ray diffraction patterns and calculated electronic band structures of the Dirac line-nodal material CaSb$_2$ under pressure. Its superconducting transition temperature ($T_{\mathrm{c}}=1.7$ K) increases under pressure and…

Making use of first-principles calculations we analyze the effect of quantum ionic fluctuations and lattice anharmonicity on the crystal structure and superconductivity of I-43m CH4-H3S, one of the lowest enthalpy structures in the C-S-H…

Materials Science · Physics 2024-12-25 Pugeng Hou , Francesco Belli , Tiange Bi , Eva Zurek , Ion Errea

We present first-principles calculations of metallic atomic hydrogen in the 400-600 GPa pressure range in a tetragonal structure with space group $I4_1/amd$, which is predicted to be its first atomic phase. Our calculations show a band…

Superconductivity · Physics 2016-06-01 Miguel Borinaga , Ion Errea , Matteo Calandra , Francesco Mauri , Aitor Bergara

With the motivation of discovering high-temperature superconductors, evolutionary algorithm is employed to search for all stable compounds in the Sn-H system. In addition to the traditional SnH$_4$, new hydrides SnH$_8$, SnH$_{12}$ and…

Density-functional calculations are presented for high-pressure structural phases of S and Se. The structural phase diagrams, phonon spectra, electron-phonon coupling, and superconducting properties of the isovalent elements are compared.…

Condensed Matter · Physics 2009-10-31 Sven P. Rudin , Amy Y. Liu , J. K. Freericks , A. Quandt

Phonon measurements in the A15-type superconductors were complicated in the past because of the unavailability of large single crystals for inelastic neutron scattering, e.g., in the case of Nb$_3$Sn, or unfavorable neutron scattering…

Superconductivity · Physics 2019-04-19 A. Sauer , D. A. Zocco , A. H. Said , R. Heid , A. Böhmer , F. Weber

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

Superconductivity · Physics 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross

We examine coherent phonons in a strongly driven sample of optimally-doped high temperature superconductor YBa$_2$Cu$_3$O$_{7-\delta}$. We observe a non-linear lattice response of the 4.5\,THz copper-oxygen vibrational mode at high…

We discuss the BCS theory for electrons in graphene with a superimposed electrical unidirectional superlattice potential (SL). New Dirac points emerge together with van Hove singularities (VHS) linking them. We obtain a superconducting…

Mesoscale and Nanoscale Physics · Physics 2013-10-22 J. Dietel , V. Bezerra , H. Kleinert

The structural stability and phonon properties of SnSe/SnS superlattices at finite temperatures have been studied using machine learning force field molecular dynamics and the anharmonic phonon approach. The vertical SnSe/SnS superlattice…

Materials Science · Physics 2025-02-13 Feng-ning Xue , Wei Li , Zi Li , Yong Lu

The semimetal antimony (Sb) element doped into hydrogen has been performed theoretically to explored high-pressure crystal structure and superconductivity of antimony hydrides. The unexpected stoichiometry $\textrm{SbH}_\textrm{4}$ with…

Superconductivity · Physics 2015-06-24 Yanbin Ma , Defang Duan , Da Li , Yunxian Liu , Fubo Tian , Xiaoli Huang , Zhonglong Zhao , Hongyu Yu , Bingbing Liu , Tian Cui

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided a new impetus to the search for even higher $T_c$. Theory predicted and experiment confirmed that the phase…