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V2O3 is the prototype system for the Mott transition, one of the most fundamental phenomena of electronic correlation. Temperature, doping or pressure induce a metal to insulator transition (MIT) between a paramagnetic metal (PM) and a…

Vanadium sesquioxide, V2O3, is a prototypical metal-to-insulator system where, in temperature-dependent studies, the transition always coincides with a corundum-to-monoclinic structural transition. As a function of pressure, V2O3 follows…

Vanadium oxides are strongly correlated materials which display metal-insulator transitions as well as various structural and magnetic properties that depend heavily on oxygen stoichiometry. Therefore, it is crucial to precisely control…

Materials Science · Physics 2020-12-21 Min-Han Lee , Yoav Kalcheim , Javier del Valle , Ivan K. Schuller

Controlling the Mott transition through strain engineering is crucial for advancing the development and application of memristive and neuromorphic computing devices. Yet, Mott insulators are heterogeneous due to intrinsic phase boundaries…

Materials Science · Physics 2024-07-02 Ziming Shao , Aileen Luo , Eti Barazani , Tao Zhou , Zhonghou Cai , Martin V. Holt , Yoav Kalcheim , Andrej Singer

Correlated electron materials (CEMs) host a rich variety of condensed matter phases. Vanadium dioxide (VO2) is a prototypical CEM with a temperature-dependent metal-to-insulator (MIT) transition with a concomitant crystal symmetry change.…

We report an isothermal electric field-induced first-order phase transition from Mott-insulator to the metallic state in the epitaxial thin film of V$_2$O$_3$ in the temperature regime below its Mott transition temperature $\approx$ 180 K.…

Strongly Correlated Electrons · Physics 2024-07-17 Binoy Krishna De , V. G. Sathe , S. B. Roy

Epitaxial SrTi1-xVxO3 thin films with thicknesses of ~16 nm were grown on (001)-oriented LSAT substrates using the pulsed electron-beam deposition technique. The transport study revealed a temperature driven metal-insulator transition (MIT)…

Strongly Correlated Electrons · Physics 2015-06-17 Man Gu , Stuart A. Wolf , Jiwei Lu

Vanadium sesquioxide V2O3 is considered a textbook example of Mott-Hubbard physics. In this paper we present an extended optical study of its whole temperature/doping phase diagram as obtained by doping the pure material with M=Cr or Ti…

Strongly Correlated Electrons · Physics 2015-04-29 I. Lo Vecchio , L. Baldassarre , F. D'Apuzzo , O. Limaj , D. Nicoletti , A. Perucchi , L. Fan , P. Metcalf , M. Marsi , S. Lupi

The Mott transistor is a paradigm for a new class of electronic devices---often referred to by the term Mottronics---, which are based on charge correlations between the electrons. Since correlation-induced insulating phases of most oxide…

The V2O3 phase diagram contains two insulating phases and one metallic phase with different lattice structures. The stability of these phases is very sensitive to pressure, offering a mechanism to tune phase transitions by inducing strain…

Materials Science · Physics 2025-10-06 Reetendra Singh , Abhishek Rakshit , Galit Atiya , Michael Kalina , Yaron Kauffmann , Yoav Kalcheim

Electric field-induced giant resistive switching triggered by insulator-to-metal transition (IMT) is one of the promising approaches for developing a new class of electronics often referred to as Mottronics. Achieving this resistive…

Insulator-to-metal (MI) phase transition in vanadium dioxide (VO2) thin films with controlled lattice distortion was investigated by thermopower measurements. VO2 epitaxial films with different crystallographic orientations, grown on (0001)…

Strongly Correlated Electrons · Physics 2015-07-15 Takayoshi Katase , Kenji Endo , Hiromichi Ohta

Dimensional confinement has shown to be an effective strategy to tune competing degrees of freedom in complex oxides. Here, we achieved atomic layered growth of trigonal vanadium sesquioxide (V2O3) by means of oxygen-assisted molecular beam…

The electronic structure of vanadium sesquioxide in its different phases has been calculated using the screened exchange (sX) hybrid functional. The hybrid functional reproduces the electronic properties of all three phases, the…

Strongly Correlated Electrons · Physics 2013-03-22 Yuzheng Guo , Stewart J. Clark , John Robertson

We present a study of the synthesis of epitaxial V$_2$O$_3$ films on $c$-plane Al$_2$O$_3$ substrates by reactive dc-magnetron sputtering. The results reveal a temperature window, at substantially lower values than previously reported,…

Materials Science · Physics 2018-05-03 Einar B. Thorsteinsson , Seyedmohammad Shayestehaminzadeh , Unnar B. Arnalds

Phase transitions are key in determining and controlling the quantum properties of correlated materials. Here, by using the powerful combination of precise material synthesis and angle resolved photoelectron spectroscopy, we show evidence…

The pressure driven Mott-transition in Chromium doped V2O3 films is investigated by direct electrical measurements on polycrystalline films with thicknesses down to 10 nm, and doping concentrations of 2%, 5% and 15%. A change in resistivity…

Strongly Correlated Electrons · Physics 2024-05-15 Johannes Mohr , Tyler Hennen , Daniel Bedau , Rainer Waser , Dirk J. Wouters

Memory effects during metal-insulator transitions in quantum materials reveal complex physics and potential for novel electronics mimicking biological neural systems. Nonetheless, understanding of memory and nonlinearity in sequential…

Mott physics is characterized by an interaction-driven metal-to-insulator transition in a partially filled band. In the resulting insulating state, antiferromagnetic orders of the local moments typically develop, but in rare situations no…

We use density functional theory plus dynamical mean-field theory (DFT+DMFT) to study multiple control parameters for tuning the metal-insulator transition (MIT) in CaVO$_3$ thin films. We focus on separating the effects resulting from…

Strongly Correlated Electrons · Physics 2018-02-14 Sophie Beck , Gabriele Sclauzero , Uday Chopra , Claude Ederer
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