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Accurately identifying metabolites i.e. small molecules from mass spectrometry data remains a core challenge in metabolomics, with broad applications in drug discovery, environmental analysis, and clinical research. We address the Molecule…

Electrospray tandem mass spectrometry (ESI-MS/MS) is commonly used in high throughput metabolomics. One of the key obstacles to the effective use of this technology is the difficulty in interpreting measured spectra to accurately and…

Computational Engineering, Finance, and Science · Computer Science 2014-06-10 F. Allen , R. Greiner , D. Wishart

The identification of metabolites from complex biological samples often involves matching experimental mass spectrometry data to signatures of compounds derived from massive chemical databases. However, misidentifications may result due to…

Quantitative Methods · Quantitative Biology 2023-07-11 Christine H. Chang , Bryan J. Killinger , Ryan S. Renslow , Sean M. Colby

Identifying a small molecule from its mass spectrum is the primary open problem in computational metabolomics. This is typically cast as information retrieval: an unknown spectrum is matched against spectra predicted computationally from a…

Machine Learning · Computer Science 2023-01-30 Michael Murphy , Stefanie Jegelka , Ernest Fraenkel , Tobias Kind , David Healey , Thomas Butler

Untargeted metabolomics using LC-MS/MS offers the potential to comprehensively profile the chemical diversity of biological samples. However, the process is fundamentally limited by the "identification bottleneck," where only a small…

Quantitative Methods · Quantitative Biology 2025-10-14 Hansol Hong , Sangwon Lee , Jang-Ho Ha , Sung-June Chu , So-Hee An , Woo-Hyun Paek , Gyuhwa Chung , Kyoung Tai No

Chemical formula annotation for tandem mass spectrometry (MS/MS) data is the first step toward structurally elucidating unknown metabolites. While great strides have been made toward solving this problem, the current state-of-the-art method…

Quantitative Methods · Quantitative Biology 2023-10-24 Samuel Goldman , Jiayi Xin , Joules Provenzano , Connor W. Coley

Molecular property prediction is essential in a variety of contemporary scientific fields, such as drug development and designing energy storage materials. Although there are many machine learning models available for this purpose, those…

Machine Learning · Computer Science 2025-06-03 Gihan Panapitiya , Peiyuan Gao , C Mark Maupin , Emily G Saldanha

Small-molecule identification from tandem mass spectrometry (MS/MS) remains a bottleneck in untargeted settings where spectral libraries are incomplete. While deep learning offers a solution, current approaches typically fall into two…

Machine Learning · Computer Science 2026-03-05 Yinkai Wang , Yan Zhou Chen , Xiaohui Chen , Li-Ping Liu , Soha Hassoun

In genome-scale constraint-based metabolic models, gene deletion strategies are essential for achieving growth-coupled production, where cell growth and target metabolite synthesis occur simultaneously. Despite the inherently networked…

Quantitative Methods · Quantitative Biology 2026-04-10 Ziwei Yang , Takeyuki Tamura

Mass spectra, which are agglomerations of ionized fragments from targeted molecules, play a crucial role across various fields for the identification of molecular structures. A prevalent analysis method involves spectral library…

Machine Learning · Computer Science 2023-06-29 Jiwon Park , Jeonghee Jo , Sungroh Yoon

Structural biology has made significant progress in determining membrane proteins, leading to a remarkable increase in the number of available structures in dedicated databases. The inherent complexity of membrane protein structures,…

A key challenge in metabolomics is annotating measured spectra from a biological sample with chemical identities. Currently, only a small fraction of measurements can be assigned identities. Two complementary computational approaches have…

Machine Learning · Computer Science 2022-03-28 Xinmeng Li , Hao Zhu , Li-ping Liu , Soha Hassoun

Substructure search in chemical compound databases is a fundamental task in cheminformatics with critical implications for fields such as drug discovery, materials science, and toxicology. However, the increasing size and complexity of…

Databases · Computer Science 2023-10-04 Vsevolod Vaskin , Dmitri Jakovlev , Fedor Bakharev

The identification and property prediction of chemical molecules is of central importance in the advancement of drug discovery and material science, where the tandem mass spectrometry technology gives valuable fragmentation cues in the form…

Artificial Intelligence · Computer Science 2026-04-14 Yunhua Zhong , Yixuan Tang , Yifan Li , Jie Yang , Pan Liu , Jun Xia

Structure-Based Drug Design (SBDD) is a powerful strategy in computational drug discovery, utilizing three-dimensional protein structures to guide the design of molecules with improved binding affinity. However, capturing complex…

Machine Learning · Computer Science 2025-11-18 Long Xu , Yongcai Chen , Fengshuo Liu , Yuzhong Peng

Untargeted metabolomics generates large volumes of tandem mass spectrometry (MS/MS) data and computational annotations that can reveal molecular mechanisms across organisms and environments. Public reuse has improved through harmonized…

Databases · Computer Science 2026-05-26 Matthieu Féraud , Dina Boukhajou , Fabien Gandon , Louis-Félix Nothias

Many datasets exhibit a well-defined structure that can be exploited to design faster search tools, but it is not always clear when such acceleration is possible. Here, we introduce a framework for similarity search based on characterizing…

Data Structures and Algorithms · Computer Science 2015-09-22 Y. William Yu , Noah M. Daniels , David Christian Danko , Bonnie Berger

Fragment-based shape signature techniques have proven to be powerful tools for computer-aided drug design. They allow scientists to search for target molecules with some similarity to a known active compound. They do not require reference…

Artificial Intelligence · Computer Science 2022-01-05 Thierry Petit , Randy J. Zauhar

The Mixed-Membership Stochastic Blockmodel~(MMSB) is proposed as one of the state-of-the-art Bayesian relational methods suitable for learning the complex hidden structure underlying the network data. However, the current formulation of…

Machine Learning · Statistics 2020-02-04 Zheng Yu , Xuhui Fan , Marcin Pietrasik , Marek Reformat

In contrast to the abundant research focusing on large-scale models, the progress in lightweight semantic segmentation appears to be advancing at a comparatively slower pace. However, existing compact methods often suffer from limited…

Computer Vision and Pattern Recognition · Computer Science 2023-09-13 Guoan Xu , Wenjing Jia , Tao Wu , Ligeng Chen
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