Related papers: Role of cavitation in drying cementitious material…
It has been known for a long time that the adsorption and condensation of gas cause elastic deformation of the porous matrix. The reversible formation of an adsorbed film, which precedes capillary condensation, results in an extension of…
We investigate the drying dynamics of porous media with two pore diameters separated by several orders of magnitude. Nanometer-sized pores at the edge of our samples prevent air entry, while drying proceeds by heterogeneous nucleation of…
Capillary effects such as imbibition-drying cycles impact the mechanics of granular systems over time. A multiscale poromechanics framework was applied to cement paste, that is the most common building material, experiencing broad humidity…
Pressure reduction in liquids may result in vaporization and bubble formation. This thermodynamic process is termed cavitation. It is commonly observed in hydraulic machinery, ship propellers, and even in medical therapy within the human…
Drying induced cracking of concrete surfaces and repair layers is a common problem. A principal cause for this type of cracking is the moisture and resulting contraction gradient that develops in the cement paste matrix upon drying. This…
Cavitation is a process where the viscous terms in a relativistic fluid result in reducing the effective pressure, thus facilitating the nucleation of bubbles of a stable phase. The effect is particularly pronounced in the vicinity of a…
The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase.…
It is well known that a solid (e.g. wood or rubber) can be put under tensile stress by pulling on it. Once a critical stress is overcome, the solid breaks, leaving an empty space. Similarly, due to internal cohesion, a liquid can withstand…
We study the influence of the relative size of the reservoir on the adsorption isotherms of a fluid in disordered or inhomogeneous mesoporous solids. We consider both an atomistic model of a fluid in a simple, yet structured pore, whose…
Cavitation, the formation of vapor bubbles in metastable liquids, is highly sensitive to nanoscale surface defects. Using molecular dynamics simulations and classical nucleation theory, we show that pure water confined within defect-free…
Values of water permeability for cementitious materials reported in the literature show a large scatter. This is partially attributed to the fact that materials used in different studies are different. To eliminate the effects of cements,…
We study the effect of spatially-correlated heterogeneity on isothermal drying of porous media. We combine a minimal pore-scale model with microfluidic experiments with the same pore geometry. Our simulated drying behavior compare favorably…
We consider the theoretical description of a fluid adsorbed in a nanopore. Hysteresis and discontinuities in the isotherms in general hampers the determination of equilibrium thermodynamic properties, even in computer simulations. A…
Experimental methods allow the shape and chemical composition of solid surfaces to be controlled at a mesoscopic level. Exposing such structured substrates to a gas close to coexistence with its liquid can produce quite distinct adsorption…
Vapor condensation is a physical phenomenon that finds application in heat removal systems. The traditional design of these systems involves round tubes but experience shows that this geometry is not optimal for heat transfer. Flattened…
Cavitation in soft elastomers and adhesives is often viewed as an elastic instability, commonly tied to the study of incompressible solids. It is the first step prior to fibrillation and ultimate failure in adhesives. Building on the work…
The roles of applied strain and temperature on the hydration dynamics of cement paste are uncovered in the present study. We find that the system hardens over time through two different aging processes. The first process dominates the…
The fundamental impacts of surface geometry on the stability of wetting states, and the transitions between them are elucidated for posts and reentrant structures in both two and three dimensions. We identify three principal outcomes of…
Drying a droplet of colloidal dispersion can result in complex pattern formation due to both development and deformation of a skin at the drop surface. The present study focus on the drying process of droplets of colloidal dispersions in a…
In this paper, we study the drying of water-saturated porous polydimethylsiloxane (PDMS) elastomers with closed porosity in which the evaporation of water is possible only via the diffusion across the PDMS. Starting from water/PDMS…