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We investigate the dynamics of a rotating Morse wave packet, appropriate for a ro-vibrating diatomic molecule. The coupling between vibrational and rotational degrees of freedom is explicated in real position space as well as in phase space…

Quantum Physics · Physics 2009-07-20 Utpal Roy , Suranjana Ghosh

Correlation among particles in finite quantum systems leads to complex behaviour and novel states of matter. One remarkable example is predicted to occur in a semiconductor quantum dot (QD) where at vanishing density the Coulomb correlation…

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

We analytically tackle opto-vibronic interactions in molecular systems driven by either classical or quantum light fields. In particular, we examine a simple model of molecules with two relevant electronic levels, characterized by potential…

Quantum Physics · Physics 2024-02-28 Q. Zhang , M. Asjad , M. Reitz , C. Sommer , B. Gurlek , C. Genes

We review studies of vibrational energy transfer in a molecular junction geometry, consisting of a molecule bridging two heat reservoirs, solids or large chemical compounds. This setup is of interest for applications in molecular…

Mesoscale and Nanoscale Physics · Physics 2016-06-22 Dvira Segal , Bijay Kumar Agarwalla

Recent theoretical and experimental developments in the field of electron vortex beam physics have raised questions on what exactly this novelty in the field of electron microscopy (and other fields, such as particle physics) really…

Quantum Physics · Physics 2015-03-17 Ruben Van Boxem , Bart Partoens , Jo Verbeeck

We study theoretically the exchange of angular momentum between a photon beam and a plasma vortex, and demonstrate the possible excitation of photon angular momentum states in a plasma. This can be relevant to laboratory and space plasma…

Plasma Physics · Physics 2008-05-19 J. T. Mendonça , B. Thidé , J. E. S. Bergman , S. M. Mohammadi , B. Eliasson , W. Baan , H. Then

We demonstrate the excitation, using a structured light beam carrying orbital angular momentum, of the center of mass motion of a single atom in the transverse direction to the beam's propagation. This interaction is achieved with a vortex…

We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar…

Quantum Physics · Physics 2017-09-13 Elena Kuznetsova , Seth T. Rittenhouse , Hossein R. Sadeghpour , Susanne F. Yelin

Vortices are whirling disturbances commonly found in nature ranging from tremendously small scales in Bose-Einstein condensates to cosmologically colossal scales in spiral galaxies. An optical vortex, generally associated with a spiral…

Optics · Physics 2021-08-23 Chenhao Wan , Jian Chen , Andy Chong , Qiwen Zhan

We investigate the properties of two interacting ultracold polar molecules described as distinguishable quantum rigid rotors, trapped in a one-dimensional harmonic potential. The molecules interact via a multichannel two-body contact…

Atomic Physics · Physics 2018-07-03 Anna Dawid , Maciej Lewenstein , Michał Tomza

We demonstrate the coherent transfer of the orbital angular momentum of a photon to an atom in quantized units of hbar, using a 2-photon stimulated Raman process with Laguerre-Gaussian beams to generate an atomic vortex state in a…

Quantum Physics · Physics 2009-11-13 M. F. Andersen , C. Ryu , Pierre Clade , V. Natarajan , A. Vaziri , K. Helmerson , W. D. Phillips

Plasmonic vortices (PV) excited by a highly focused radially polarized optical vortex (RPOV) beam on a metal surface are investigated experimentally and theoretically. The proposed method reveals a direct phase singularity and orbital…

Optics · Physics 2011-10-11 X. -C. Yuan , Z. J. Hu , G. H. Yuan , Z. Shen

This article covers few selected aspects of quantum theory of molecular rotations and vibrations. Triatomic molecules are the simplest systems, which show qualitative characteristics of larger polyatomic molecules. On the minimal example of…

Chemical Physics · Physics 2022-03-18 Emil J. Zak

We present a qualitative model for a fundamental process in molecular electronics: the change in conductance upon bond breaking. In our model a diatomic molecule is attached to spin-polarized contacts. Employing a Hubbard Hamiltonian,…

Materials Science · Physics 2008-06-24 Ali Goker , Francois Goyer , Matthias Ernzerhof

In this work we discuss the rotational structure of Rydberg molecules. We calculate the complete wave function in a laboratory fixed frame and derive the transition matrix elements for the pho- toassociation of free ground state atoms. We…

Atomic Physics · Physics 2018-08-01 O. Thomas , C. Lippe , T. Eichert , H. Ott

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

An effective Hamiltonian is considered for hydrogen bonding between two molecules due to the quantum mechanical interaction between the orbitals of the H-atom and the donor and acceptor atoms in the molecules. The Hamiltonian acts on two…

Chemical Physics · Physics 2012-04-03 Ross H. McKenzie

In a molecule subjected to no external fields, motion of nuclei is governed by a function V of nuclear coordinates. This function (potential energy) is a sum of two terms: Coulomb repulsion between nuclei and the electronic effective…

Mathematical Physics · Physics 2015-09-01 Vladimir Damljanovic

We have proposed a unified framework towards the dynamics of optical and electron vortex beams from the perspective of geometric phase and the associated Hall effects. The unification is attributed to the notion that the spin degrees of…

Mesoscale and Nanoscale Physics · Physics 2016-05-04 Pratul Bandyopadhyay , Banasri Basu , Debashree Chowdhury