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In Density Functional Theory simulations based on the LAPW method, each self-consistent field cycle comprises dozens of large dense generalized eigenproblems. In contrast to real-space methods, eigenpairs solving for problems at distinct…

Data Structures and Algorithms · Computer Science 2015-03-20 Edoardo Di Napoli , Mario Berljafa

The plane wave method is most widely used for solving the Kohn-Sham equations in first-principles materials science computations. In this procedure, the three-dimensional (3-dim) trial wave functions' fast Fourier transform (FFT) is a…

Computational Physics · Physics 2018-01-17 Xingyu Gao , Zeyao Mo , Jun Fang , Han Wang

This paper presents a method for computing eigenvalues and eigenvectors for some types of nonlinear eigenvalue problems. The main idea is to approximate the functions involved in the eigenvalue problem by rational functions and then apply a…

Numerical Analysis · Mathematics 2020-06-11 Yousef Saad , Mohamed El-Guide , Agnieszka Międlar

In this work, we developed an automatic convergence procedure for k-points and plane wave cut-off in density functional (DFT) calculations and applied it to more than 30000 materials. The computational framework for automatic convergence…

Materials Science · Physics 2019-02-20 Kamal Choudhary , Francesca Tavazza

We discuss analytically and numerically the propagation and energy transmission of electromagnetic waves caused by the coupling of surface plasmon polaritons (SPPs) between two spatially separated layers of 2D materials, such as graphene,…

Computational Physics · Physics 2019-05-01 Jung Heon Song , Matthias Maier , Mitchell Luskin

We show that quasiparticle (QP) energies as calculated in the $GW$ approximation converge to the wrong value using the projector augmented wave (PAW) method, since the overlap integrals between occupied orbitals and high energy, plane wave…

Materials Science · Physics 2014-08-20 Jiří Klimeš , Merzuk Kaltak , Georg Kresse

We present a variational algorithm for fault tolerant quantum computing to solve a system of linear equations which directly maximises the parameters of the target fidelity. This so-called measurement test algorithm can be applied to any…

Quantum Physics · Physics 2026-04-30 Alain Giresse Tene , Thomas Konrad

Ab initio electronic structure calculations of two-dimensional layered structures are typically performed using codes that were developed for three-dimensional structures, which are periodic in all three directions. The introduction of a…

Strongly Correlated Electrons · Physics 2016-06-22 Paolo E. Trevisanutto , Giovanni Vignale

The calculation of potential energy surfaces for quantum dynamics can be a time consuming task -- especially when a high level of theory for the electronic structure calculation is required. We propose an adaptive interpolation algorithm…

Chemical Physics · Physics 2016-08-24 Markus Kowalewski , Elisabeth Larsson , Alfa Heryudono

We present a real-space adaptive-coordinate method, which combines the advantages of the finite-difference approach with the accuracy and flexibility of the adaptive coordinate method. The discretized Kohn-Sham equations are written in…

mtrl-th · Physics 2009-10-28 Francois Gygi , Giulia Galli

In this paper, we first discuss the optimal convergence of the adaptive finite element methods for non-self-adjoint eigenvalue problems. We present new theoretical error estimators and computable error estimators for multiple and clustered…

Numerical Analysis · Mathematics 2026-03-16 Shixi Wang , Hai Bi , Yidu Yang

We provide a straightforward and efficient procedure to combine LDA+U total energy functional with the full potential linearized augmented plane wave method. A detailed derivation of the LDA+U Kohn-Sham type equations is presented for the…

Strongly Correlated Electrons · Physics 2009-10-31 A. B. Shick , A. I. Liechtenstein , W. E. Pickett

We construct a reference database of materials properties calculated using density-functional theory in the local or generalized-gradient approximation, and an all-electron or a projector augmented-wave (PAW) formulation, for verification…

Materials Science · Physics 2014-04-14 E. Kucukbenli , M. Monni , B. I. Adetunji , X. Ge , G. A. Adebayo , N. Marzari , S. de Gironcoli , A. Dal Corso

We present a set of efficient techniques in first-principles electronic-structure calculations utilizing the real-space finite-difference method. These techniques greatly reduce the overhead for performing integrals that involve…

Materials Science · Physics 2009-11-10 Tomoya Ono , Kikuji Hirose

Over the past decades, transformations between different classes of eigenvalue problems have played a central role in the development of numerical methods for eigenvalue computations. One of the most well-known and successful examples of…

Numerical Analysis · Mathematics 2025-09-05 Elias Jarlebring , Vilhelm P. Lithell

Representation learning for the electronic structure problem is a major challenge of machine learning in computational condensed matter and materials physics. Within quantum mechanical first principles approaches, Kohn-Sham density…

Materials Science · Physics 2024-04-24 Bowen Hou , Jinyuan Wu , Diana Y. Qiu

A new iterative solver is proposed to efficiently calculate the ground state electronic structure in Density Functional Theory calculations. This algorithm is particularly useful for simulating physical systems considered difficult to…

Computational Physics · Physics 2021-11-24 Jean-Luc Fattebert

In this paper, we study an adaptive finite element method for multiple eigenvalue problems of a class of second order elliptic equations. By using some eigenspace approximation technology and its crucial property which is also presented in…

Numerical Analysis · Mathematics 2013-09-18 Xiaoying Dai , Lianhua He , Aihui Zhou

An adaptive finite element method is presented for the elastic scattering of a time-harmonic plane wave by a periodic surface. First, the unbounded physical domain is truncated into a bounded computational domain by introducing the…

Numerical Analysis · Mathematics 2016-05-30 Xue Jiang , Peijun Li , Junliang Lv , Weiying Zheng

Solving the generalized eigenvalue problem is a useful method for finding energy eigenstates of large quantum systems. It uses projection onto a set of basis states which are typically not orthogonal. One needs to invert a matrix whose…

Nuclear Theory · Physics 2023-04-05 Caleb Hicks , Dean Lee