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We present the first systematic study of the stability of the structure and electrical properties of FeCl$_3$ intercalated few-layer graphene to high levels of humidity and high temperature. Complementary experimental techniques such as…

Materials Science · Physics 2015-06-17 D. J. Wehenkel , T. H. Bointon , T. Booth , P. Boggild , M. F. Craciun , S. Russo

The 2D Fermi surface of 1st stage PdAl2Cl8 acceptor-type graphite intercalation compounds (GICs) has been investigated using the Shubnikov-de Haas (SdH) effect. One fundamental frequency is observed, the angular variation of which confirms…

Materials Science · Physics 2007-05-23 R. T. F. van Schaijk , A. de Visser , E. McRae , B. Sundqvist , T. Wagberg , R. Vangelisti

A systematic review is made for the AA-, AB- and ABC-stacked graphites. The generalized tight-binding model, accompanied with the effective-mass approximation and the Kubo formula, is developed to investigate electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2017-05-09 Chiun-Yan Lin , Rong-Bin Chen , Yen-Hung Ho , Ming-Fa Lin

Two dimensional van der Waals heterostructures (2D are of significant interest due to their intriguing physical properties that are critically defined by the constituent monolayers and their interlayer coupling . However, typical inorganic…

This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the…

Chemical Physics · Physics 2017-02-14 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Chiun-Yan Lin , Ming-Fa Lin

Chemical bondings of graphene oxides with oxygen concentration from 1\% to 50\% are investigated using first-principle calculations. Energy gaps are mainly determined by the competition of orbital hybridizations in C-C, O-O, and C-O bonds.…

Materials Science · Physics 2015-12-31 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Olga E. Glukhova , Ming-Fa Lin

Combining the electronic structures of two-dimensional monolayers in ultrathin hybrid nanocomposites is expected to display new properties beyond their simplex components. Here, first-principles calculations are performed to study the…

Materials Science · Physics 2015-05-15 Wei Hu , Tian Wang , Jinlong Yang

The interlayer gallery between two adjacent sheets of van der Waals materials is expected to modify properties of atoms and molecules confined at the atomic interfaces. Here, we directly image individual hydrogen atom intercalated between…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 Wen-Xiao Wang , Yi-Wen Wei , Si-Yu Li , Xinqi Li , Xiaosong Wu , Ji Feng , Lin He

We report the emergence of altermagnetism, a magnetic phase characterized by the coexistence of compensated spin ordering and momentum-dependent spin splitting, in graphite intercalation compounds (GICs), a prototypical material system long…

Materials Science · Physics 2025-11-21 Weida Fu , Guo-Dong Zhao , Tao Hu , Wencai Yi , Hui Zhang , Alessandro Stroppa , Wei Ren , Zhongming Ren

V$_2$O$_5$ is a promising battery electrode material that can intercalate not only Li, but also more abundant alkaline metals such as Na and K, and even multivalent ions such as Al, Ca, Cu, Mg, and Zn. V$_2$O$_5$ exhibits several different…

Materials Science · Physics 2026-03-05 Sakthi Kasthurirengan , Hartwin Peelaers

Potassium intercalation in graphite is investigated by first-principles theory. The bonding in the potassium-graphite compound is reasonably well accounted for by traditional semilocal density functional theory (DFT) calculations. However,…

Soft Condensed Matter · Physics 2009-11-13 Eleni Ziambaras , Jesper Kleis , Elsebeth Schroder , Per Hyldgaard

: We study the effect of hydrogen on the electronic, magnetic and hyperfine structures of an iron-vanadium superlattice consisting of three Fe monolayers and nine V monolayers. The contact charge density ({\rho}), the contact hyperfine…

Materials Science · Physics 2015-05-30 M. Elzain , M. Al-Barwani , A. Gismelseed , A. Al-Rawas , A. Yousif , H. Widatallah , K. Bouziane , I. Al-Omari

We investigate a well defined heterostructure constituted by magnetic Fe layers sandwiched between graphene (Gr) and Ir(111). The challenging task to avoid Fe-C solubility and Fe-Ir intermixing has been achieved with atomic controlled Fe…

We present detailed multi frequency resonant Raman measurements of potassium graphite intercalation compounds (GICs). From a well controlled and consecutive in-situ intercalation and high temperature de-intercalation approach the response…

Materials Science · Physics 2013-10-25 J. C. Chacon-Torres , L. Wirtz , T. Pichler

Li2GeO3, a ternary electrolyte compound of Li+-based battery, presents the unusual essential properties. The main features are thoroughly explored from the first-principles calculations. The concise pictures, the critical orbital…

We perform a density functional theory study of the effects of oxygen adsorption on the structural and electronic properties of Gr/Co(0001) and Gr/Co/Ir(111) interfaces. In both interfaces, the graphene-Co distance increases with increasing…

Materials Science · Physics 2022-08-05 Dario A. Leon , Andrea Ferretti , Daniele Varsano , Elisa Molinari , Claudia Cardoso

We demonstrate a new method to control the Fermi level around the van Hove singularity (VHS) in Li-intercalated graphene on the SiC substrate. By angle-resolved photoemission spectroscopy, we observed a clear Lifshitz transition in the…

Mesoscale and Nanoscale Physics · Physics 2022-07-13 S. Ichinokura , M. Toyoda , M. Hashizume , K. Horii , S. Kusaka , S. Ideta , K. Tanaka , R. Shimizu , T. Hitosugi , S. Saito , T. Hirahara

Intercalation of magnetic atoms into van der Waals materials provides a versatile platform for tailoring unconventional magnetic properties. However, its impact on electronic dimensionality and exchange mechanisms remains poorly understood.…

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

Superconductivity in graphite intercalated compounds has been studied for more than 40 years and it is still not fully understood, despite the recent progress and the discovery of relatively high Tc superconductivity in CaC6 and YbC6.…

Superconductivity · Physics 2009-04-14 T. Valla , J. Camacho , Z-H. Pan , A. V. Fedorov , A. C. Walters , C. A. Howard , M. Ellerby