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Related papers: Revisiting density-functional theory of the total …

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We argue in favour of developing a comprehensive dynamical theory for rationalizing, predicting, designing, and machine learning nonequilibrium phenomena that occur in soft matter. To give guidance for navigating the theoretical and…

Soft Condensed Matter · Physics 2024-02-28 Daniel de las Heras , Toni Zimmermann , Florian Sammüller , Sophie Hermann , Matthias Schmidt

The solution of complex many-body lattice models can often be found by defining an energy functional of the relevant density of the problem. For instance, in the case of the Hubbard model the spin-resolved site occupation is enough to…

Strongly Correlated Electrons · Physics 2019-02-20 James Nelson , Rajarshi Tiwari , Stefano Sanvito

Based on the variational field theory framework, we extend our previous mean-field formalism, taking into account the electrostatic correlations of the ions. We employ a general covariant approach and derive a total stress tensor that…

Soft Condensed Matter · Physics 2024-05-09 Yury A. Budkov , Petr E. Brandyshev

A rigorous formulation of time-dependent current density functional theory (TDCDFT) on a lattice is presented. The density-to-potential mapping and the ${\cal V}$-representability problems are reduced to a solution of a certain nonlinear…

Strongly Correlated Electrons · Physics 2011-09-19 I. V. Tokatly

Density functional theory, when applied to systems with $T\neq 0$, is based on the grand canonical extension of the Hohenberg-Kohn-Sham theorem due to Mermin (HKSM theorem). While a straightforward canonical ensemble generalization fails,…

Statistical Mechanics · Physics 2009-10-31 J. A. Hernando , L. Blum

The formalism of Kohn and Sham uses a specific (model) hamiltonian which highly simplifies the many-electron problem to that of noninteracting fermions. The theorem of Hohenberg and Kohn tells us that, for a given ground state density, this…

Materials Science · Physics 2007-07-05 Paola Gori-Giorgi , Julien Toulouse , Andreas Savin

The electron density $n(\rb,t)$, which is the central tool of time-dependent density functional theory, is presently considered to be derivable from a one-body time-dependent potential $V(\rb,t)$, via one-electron wave functions satisfying…

Quantum Physics · Physics 2009-04-28 Thomas A. Niehaus , Norman H. March

We present a microscopic theory for superconductivity in a magnetic field based on a local approximation approach. We derive an expression for free energy density $F$ as a function of temperature $T$ and vector potential {\bf a}, and two…

Superconductivity · Physics 2007-06-19 Zhidong Hao

A new approach to the concept of particles and their production in quantum field theory is developed. A local operator describing the current of particle density is constructed for scalar and spinor fields in arbitrary gravitational and…

High Energy Physics - Theory · Physics 2014-11-18 H. Nikolic

In the well-known Kohn-Sham theory in Density Functional Theory, a fictitious non-interacting system is introduced that has the same particle density as a system of $N$ electrons subjected to mutual Coulomb repulsion and an external…

Mathematical Physics · Physics 2014-04-14 Andre Laestadius

Most realistic calculations of moderately correlated materials begin with a ground-state density functional theory (DFT) calculation. While Kohn-Sham DFT is used in about 40,000 scientific papers each year, the fundamental underpinnings are…

Strongly Correlated Electrons · Physics 2022-09-26 Kieron Burke , John Kozlowski

We suggest to include the density of electron charge explicitly in the electron potential of density functional theory, rather than implicitly via exchange-correlation functionals. The advantages of the approach are conceptual and…

Materials Science · Physics 2007-05-23 Werner A. Hofer , Krisztian Palotas

We use time-dependent spin-density-functional theory to study dynamical magnetic phenomena. First, we recall that the local-spin-density approximation (LSDA) fails to account correctly for magnetic fluctuations in the paramagnetic state of…

Materials Science · Physics 2009-11-07 K. Capelle , B. L. Gyorffy

Density functional theory provides the most widespread framework for the realistic description of the electronic structure of solids, but the description of strongly-correlated systems has remained so far elusive. Here we consider a…

Strongly Correlated Electrons · Physics 2016-09-07 Zu-Jian Ying , Valentina Brosco , Giorgia Maria Lopez , Daniele Varsano , Paola Gori-Giorgi , José Lorenzana

Density functional theory has become the workhorse of quantum physics, chemistry, and materials science. Within these fields, a broad range of applications needs to be covered. These applications range from solids to molecular systems, from…

Chemical Physics · Physics 2025-01-20 Christof Holzer , Yannick J. Franzke

Understanding the behavior of quantum systems subject to magnetic fields is of fundamental importance and underpins quantum technologies. However, modeling these systems is a complex task, because of many-body interactions and because…

Quantum Physics · Physics 2016-12-28 P. M. Sharp , I. D'Amico

The effective action for the charge density and the photon field is proposed as a generalization of the density functional. A simple definition is given for the density functional, as the functional Legendre transform of the generator…

Strongly Correlated Electrons · Physics 2009-11-07 J. Polonyi , K. Sailer

Mobile charge in an electrolytic solution can in principle be represented as the divergence of ionic polarization. After adding explicit solvent polarization a finite volume of electrolyte can then be treated as a composite non-uniform…

Soft Condensed Matter · Physics 2021-03-03 Michiel Sprik

Exact density-functional theory is reconstructed here from its convex variational structure as two parallel exact ensemble hierarchies: an interacting hierarchy rooted in Lieb's ensemble formulation and a noninteracting hierarchy rooted in…

Chemical Physics · Physics 2026-05-01 Nan Sheng

A new formalism to describe steady-state electronic and thermal transport in the framework of density functional theory is presented. A one-to-one correspondence is proven between the three basic variables of the theory, i.e., the density…

Mesoscale and Nanoscale Physics · Physics 2022-04-26 Nahual Sobrino , Florian Eich , Gianluca Stefanucci , Roberto D'Agosta , Stefan Kurth