Related papers: Maximising Dynamic Nuclear Polarisation via Select…
We study a mechanism by which nuclear hyperpolarization due to the polarization transfer from a microwave-pulse-controlled electron spin is suppressed. From analytical and numerical calculations of the unitary dynamics of multiple nuclear…
For applications of solid state quantum computing and quantum simulations, high fidelity initialisation of thermally mixed electronic and nuclear spin qubits is essential. Whereas electronic spins can readily be initialised optically to…
Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…
After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…
NV-diamonds have attracted keen interest for nanoscale sensing and spin manipulation. In particular, the non-equilibrium electron spin polarization after optical excitation of single NV centers has successfully been transferred to nuclear…
Most of dynamic nuclear polarization (DNP) has been requiring helium cryogenics and strong magnetic fields for a high degree of polarization. In this work, we instead demonstrate an optical hyperpolarization of naturally abundant $^{13}$C…
Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…
We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate…
Low thermal polarization of nuclear spins is a primary sensitivity limitation for nuclear magnetic resonance. Here we demonstrate optically pumped (microwave-free) nuclear spin polarization of $^{13}\mathrm{C}$ and $^{15}\mathrm{N}$ in…
Hyper-polarization of nuclear spins is crucial for advancing nuclear magnetic resonance (NMR) and quantum information technologies, as nuclear spins typically exhibit extremely low polarization at room temperature due to their small…
The sensitivity of Magnetic Resonance Imaging (MRI) depends strongly on nuclear spin polarisation and, motivated by this observation, dynamical nuclear spin polarisation has recently been applied to enhance MRI protocols (Kurhanewicz, J.,…
Dynamic nuclear polarization (DNP) is a method of enhancing NMR signals via the transfer of polarization from electron spins to nuclear spins using on-resonance microwave (MW) irradiation. In most cases, monochromatic continuous-wave (MCW)…
Dynamic Nuclear Polarization (DNP) has revolutionized the field of solid-state NMR spectroscopy by significantly enhancing the sensitivity of nuclear magnetic resonance experiments. Conventionally, cross effect DNP relies on biradicals to…
Dynamic Nuclear Polarization (DNP) has enabled enormous gains in magnetic resonance signals and led to vastly accelerated NMR/MRI imaging and spectroscopy. Unlike conventional cw-techniques, DNP methods that exploit the full electron…
The hyperpolarization of nuclear spins can enable powerful imaging and sensing techniques provided the hyperpolarization is sufficiently long-lived. Recent experiments on nanodiamond $^{13}$C nuclear spins demonstrate that relaxation times…
We report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field nuclear magnetic resonance (NMR). The hyperpolarization is achieved by optical pumping (OP) of nitrogen vacancy defect centers in diamond…
Dynamic nuclear polarization (DNP) enhances the intensity of NMR signals by transferring polarization from electron spins to nuclei via microwave irradiation. Pulsed DNP methods offer more control on the spin dynamics than conventional…
We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy…
We report achieving enhanced nuclear magnetization in a magnetic resonance force microscope experiment at 0.6 tesla and 4.2 kelvin using the dynamic nuclear polarization (DNP) effect. In our experiments a microwire coplanar waveguide…
Dynamic nuclear polarization via contact with electronic spins has emerged as an attractive route to enhance the sensitivity of nuclear magnetic resonance (NMR) beyond the traditional limits imposed by magnetic field strength and…