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Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…

Astrophysics of Galaxies · Physics 2020-12-02 Laurie E. U. Chu , Klaus W. Hodapp , A. C. Adwin Boogert

The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…

Astrophysics of Galaxies · Physics 2021-06-16 K. -J. Chuang , G. Fedoseev , C. Scirè , G. A. Baratta , C. Jäger , Th. Henning , H. Linnartz , M. E. Palumbo

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation…

Astrophysics of Galaxies · Physics 2017-01-25 Audrey Coutens , Jonathan M. C. Rawlings , Serena Viti , David A. Williams

Some protostellar systems show little or no millimetre line emission of complex organics. This can be interpreted as a low abundance of these molecules, alternatively they could be present in the system but are not seen in the gas. The goal…

Solar and Stellar Astrophysics · Physics 2022-07-20 P. Nazari , B. Tabone , G. P. Rosotti , M. L. van Gelder , R. Meshaka , E. F. van Dishoeck

Methanol-water liquid mixtures have been investigated by high-energy synchrotron X-ray and neutron diffraction at low temperatures. We are thus able to report the first complete sets of both X-ray and neutron weighted total scattering…

Ethanol (CH3CH2OH) has been detected in interstellar ices within regions associated with the early stages of star and planet formation. Its solid-phase pathways can lead to diverse conditions that can significantly influence its…

Astrophysics of Galaxies · Physics 2026-04-08 J. A. DeVine , J. Terwisscha van Scheltinga , S. Ioppolo , K. -J. Chuang , E. F. van Dishoeck , T. Lamberts

Complex organic molecules (COMs) in starless cores provide critical insights into the early stages of star formation and prebiotic chemistry. We present a chemical survey of 16 starless cores (including five prestellar cores) in the Orion A…

Methanol lines observations of a sample of low mass Class 0 protostars are presented. Using a 1D radiative transfer model, I show that several protostars have large abundance jumps in the inner hot and dense region of envelopes, probably…

Astrophysics · Physics 2007-05-23 S. Maret

Ethanolamine (NH2CH2CH2OH) has recently been identified in the molecular cloud G+0.693-0.027, situated in the SgrB2 complex in the Galactic center. However, its presence in other regions, and in particular in star-forming sites, is still…

Methanol masers at 6.7 GHz have been found exclusively towards high-mass star forming regions. Recently, some Class 0 protostars have been found to display conditions similar to what are found in hot cores that are associated with massive…

Astrophysics · Physics 2009-11-13 J. D. Pandian , S. Leurini , K. M. Menten , A. Belloche , P. F. Goldsmith

This study aims to elucidate a possible link between chemical properties of ices in star-forming regions and environmental characteristics of the host galaxy. We performed 3--4 micron spectroscopic observations toward nine embedded…

Astrophysics of Galaxies · Physics 2016-01-06 Takashi Shimonishi , Emmanuel Dartois , Takashi Onaka , François Boulanger

The occurrence of complex organic molecules (COMs) in the gas phase at low temperature in the dense phases of the ISM suggests that a non-thermal desorption mechanism is at work because otherwise, COMs should condense within a short…

Astrophysics of Galaxies · Physics 2019-07-17 E. Dartois , M. Chabot , T. Id Barkach , H. Rothard , B. Augé , A. N. Agnihotri , A. Domaracka , P. Boduch

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

The dependence of the proton-to-electron mass ratio, mu, on the local matter density was investigated using methanol emission in the dense dark cloud core L1498. Towards two different positions in L1498, five methanol transitions were…

Cosmology and Nongalactic Astrophysics · Physics 2017-10-18 M. Daprà , C. Henkel , S. A. Levshakov , K. M. Menten , S. Muller , H. L. Bethlem , S. Leurini , A. V. Lapinov , W. Ubachs

Observations are presented of emission lines from organic molecules at frequencies 32 - 50 GHz in the vicinity of Chamaeleon MMS1. This chemically-rich dense cloud core habours an extremely young, very low-luminosity protostellar object and…

Astrophysics of Galaxies · Physics 2015-05-30 Martin A. Cordiner , Steven B. Charnley , Eva S. Wirström , Robert G. Smith

Aims: The production of saturated organic molecules in hot cores and corinos is not well understood. The standard approach is to assume that, as temperatures heat up during star formation, methanol and other species evaporate from grain…

Astrophysics · Physics 2009-11-11 R. T. Garrod , E. Herbst

Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study…

Solar and Stellar Astrophysics · Physics 2015-05-13 Karin I. Oberg , Sandrine Bottinelli , Ewine F. van Dishoeck

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of…

Astrophysics of Galaxies · Physics 2015-04-24 Juris Kalvans

Aims: The gas-phase abundance of methanol in dark quiescent cores in the interstellar medium cannot be explained by gas-phase chemistry. In fact, the only possible synthesis of this species appears to be production on the surfaces of dust…

Astrophysics · Physics 2009-11-13 R. T. Garrod , V. Wakelam , E. Herbst