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When an ensemble of particles interact hydrodynamically, they generically display large-scale transient structures such as swirls in sedimenting particles [1], or colloidal strings in sheared suspensions [2]. Understanding these…

Soft Condensed Matter · Physics 2013-01-24 Nicolas Desreumaux , Jean-Baptiste Caussin , Raphael Jeanneret , Eric Lauga , Denis Bartolo

Polyelectrolytes are commonly used to chelate multi-valent ions in aqueous solutions, playing a critical role in water softening and the prevention of mineralization. At sufficient ionic strength, ion-mediated…

Soft Condensed Matter · Physics 2023-11-21 Alec Glisman , Sriteja Mantha , Decai Yu , Eric Wasserman , Scott Backer , Zhen-Gang Wang

This paper presents a Bayesian parameter estimation approach and identifiability analysis for a lithium-ion battery model, to determine the uniqueness, evaluate the sensitivity and quantify the uncertainty of a subset of the model…

Systems and Control · Electrical Eng. & Systems 2023-09-04 Antti Aitio , Scott G. Marquis , Pedro Ascencio , David Howey

We study electrostatic mechanisms of destabilization of highly asymmetric electrolytes. For this purpose, we perform primitive model Monte Carlo simulations of charged macroions immersed in multivalent salt solution. At low salt…

Soft Condensed Matter · Physics 2007-06-20 Vladimir Lobaskin , Khawla Qamhieh

Organic electrochemical transistors are extensively studied for applications ranging from bioelectronics to analog and neuromorphic computing. Despite significant advances, the fundamental interactions between the polymer semiconductor…

Polymer electrolytes are critical for safe, high-energy-density solid-state batteries, yet discovering candidates that balance high ionic conductivity with high transference numbers remains a significant challenge. In this work, we develop…

Materials Science · Physics 2026-02-20 Antonia S. Kuhn , Jurğis Ruža , KyuJung Jun , Pablo Leon , Rafael Gómez-Bombarelli

This paper presents a thermodynamically consistent model for multicomponent electrolyte solutions. The first part of this paper derives the general governing equations for nonequilibrium systems within the theory of nonequilibrium…

Analysis of PDEs · Mathematics 2016-05-25 Matthias Herz , Peter Knabner

Water-in-Salt-Electrolytes (WiSEs) are a promising class of next-generation electrolytes. Unlike classical dilute electrolytes or more conventional battery electrolytes, WiSEs are characterised by their super-concentrated salt concentration…

The structure of an aqueous solution of sodium chloride at a planar electrode is investigated by integral equation techniques. With the central force water model the aqueous electrolyte is modelled as a mixture of sodium and chloride ions…

chem-ph · Physics 2009-10-28 M. Vossen , F. Forstmann

The decoherence of nonclassical motional states of a trapped $^9 {\rm Be^+}$ ion in a recent experiment is investigated theoretically. Sources of decoherence considered here destroy the characteristic coherent quantum dynamics of the system…

Quantum Physics · Physics 2011-08-04 M. Murao , P. L. Knight

Ion traps are a versatile tool to study nonequilibrium statistical physics, due to the tunability of dissipation and nonlinearity. We propose an experiment with a chain of trapped ions, where dissipation is provided by laser heating and…

Pattern Formation and Solitons · Physics 2011-04-06 Tony E. Lee , M. C. Cross

Ion transport measurements are widely used as an indirect probe for various properties of confined electrolytes. It is generally assumed that the ion concentration in a nanoscale channel is equal to the ion concentration in the macroscopic…

Soft Condensed Matter · Physics 2023-04-05 Paul Robin , Adrien Delahais , Lydéric Bocquet , Nikita Kavokine

Droplets of electrolyte solutions in an insulating medium are ubiquitous in nature. The net charges of these droplets are normally nonzero, and they fluctuate. However, a theory on the probability distribution function for the net charge of…

Chemical Physics · Physics 2025-08-20 Yuki Uematsu , Keiju Suda

The interaction between charged objects in an electrolyte solution is a fundamental question in soft matter physics. It is well-known that the electrostatic contribution to the interaction energy decays exponentially with object separation.…

Soft Condensed Matter · Physics 2017-08-02 Alpha A. Lee , Carla Perez-Martinez , Alexander M. Smith , Susan Perkin

A parallel plate capacitor containing an electrolytic solution is the simplest model of a supercapacitor, or electric double layer capacitor. Using both analytical and numerical techniques, we solve the Poisson-Nernst-Planck equations for…

Soft Condensed Matter · Physics 2025-10-02 Ivan Palaia , Adelchi J. Asta , Megh Dutta , Patrick B. Warren , Benjamin Rotenberg , Emmanuel Trizac

Detecting associations between microbial compositions and sample characteristics is one of the most important tasks in microbiome studies. Most of the existing methods apply univariate models to single microbial species separately, with…

The role of background in bosonic quantum statistics is discussed in the frame of a new approach in terms of coherent states. Bosons are indeed detected in different physical situations where they exhibit different and apparently…

Statistical Mechanics · Physics 2009-10-31 Enrico Celeghini , Mario Rasetti

We investigate the convergence of coupled-cluster correlation energies and related quantities with respect to the employed basis set size for the uniform electron gas to gain a better understanding of the basis set incompleteness error. To…

Materials Science · Physics 2024-02-27 Nikolaos Masios , Felix Hummel , Andreas Grüneis , Andreas Irmler

In this article we develop an algorithm for the efficient simulation of electrolytes in the presence of physical boundaries. In previous work the Discrete Ion Stochastic Continuum Overdamped Solvent (DISCOS) algorithm was derived for triply…

We derive a Debye-H\"uckel-like model of the electric ion-ion interaction for non-constant dielectric susceptibility, which does not depend on any kind of charging process due to its foundation in the general framework of non-equilibrium…

Chemical Physics · Physics 2025-02-24 Wolfgang Dreyer , Rüdiger Müller