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We present a theory for the two kinds of dynamical quantum phase transitions, termed DPT-I and DPT-II, based on a minimal set of symmetry assumptions. In the special case of collective systems with infinite-range interactions, both are…

Statistical Mechanics · Physics 2023-03-10 Ángel L. Corps , Armando Relaño

Nonlocal correlations play an essential role in correlated electron systems, especially in the vicinity of phase transitions and crossovers, where two-particle correlation functions display a distinct momentum dependence. In nonequilibrium…

Strongly Correlated Electrons · Physics 2023-06-29 Olivier Simard , Philipp Werner

Core-level X-ray Photoelectron Spectroscopy (XPS) is often used to study the surfaces of heterogeneous copper-based catalysts, but the interpretation of measured spectra, in particular the assignment of peaks to adsorbed species, can be…

Materials Science · Physics 2018-12-26 J. Matthias Kahk , Johannes Lischner

Using an advanced version of the renormalized mean-field theory (RMFT) for the t-J model, we examine spin-singlet superconducting (SC) state of $d_{x^2 - y^2}$-symmetry. Overall doping dependence of the SC gap magnitude is in good agreement…

Strongly Correlated Electrons · Physics 2016-08-14 Jakub Jȩdrak , Jozef Spałek

We present an investigation of the performance of the relativistic multi-reference Fock-space coupled cluster (FSCC) method for predicting molecular hyperfine structure (HFS) constants, including a thorough computational study to estimate…

We have calculated several low-lying Charge Transfer (CT) excited-state energies for four non-covalently bound dyads composed of a sulfonated-ZnPc coupled to C60. Our results show that the di- and tri-sulfonated systems yield a CT state as…

Materials Science · Physics 2013-08-12 Marco Olguin , Luis Basurto , Rajendra R. Zope , Tunna Baruah

We propose a new self-consistent field (SCF) algorithm based on an iterative, partially stochastic \textit{``Divide \& Conquer''}-type approach. This new SCF algorithm is a simple variant of the usual SCF procedure and can be easily…

Chemical Physics · Physics 2021-08-04 Pierre-François Loos , Jean-Louis Rivail , Xavier Assfeld

Theoretical calculations of core electron binding energies are important for aiding the interpretation of experimental core level photoelectron spectra. In previous work, the $\Delta$-Self-Consistent-Field ($\Delta$-SCF) method based on…

The computation of excited states within the Complete Active Space Self-Consistent Field (CASSCF) framework remains a significant challenge in quantum chemistry, both theoretically and algorithmically. In this work, we extend the K\"ahler…

Chemical Physics · Physics 2026-04-16 Laura Grazioli , Yukuan Hu , Tommaso Nottoli , Filippo Lipparini , Eric Cancès

Variational calculations of excited electronic states are carried out by finding saddle points on the surface that describes how the energy of the system varies as a function of the electronic degrees of freedom. This approach has several…

Chemical Physics · Physics 2023-02-15 Yorick L. A. Schmerwitz , Gianluca Levi , Hannes Jónsson

We study phase transitions and critical phenomena in nonequilibrium steady states controlled by an electric field. We employ the D3/D7 model in the presence of a charge density and electric field at finite temperatures. The system undergoes…

High Energy Physics - Theory · Physics 2023-03-28 Daisuke Endo , Yuichi Fukazawa , Masataka Matsumoto , Shin Nakamura

We introduce and benchmark a systematically improvable route for excited-state calculations, state-specific configuration interaction ($\Delta$CI), \alert{which is a particular realization of multiconfigurational self-consistent field and…

Chemical Physics · Physics 2023-08-31 Fábris Kossoski , Pierre-François Loos

The computational design of heteroatom-doped organic dyes for dye-sensitized solar cells (DSSCs) remains challenging, as predictive methods must accurately describe long-range charge-transfer (CT) excitations while remaining computationally…

Chemical Physics · Physics 2026-05-22 Aditi Singh , Ram Dhari Pandey , Subrata Jana , Prasanjit Samal , Paweł Tecmer , Szymon Śmiga

Our general interest is in self-consistent-field (scf) theories of disordered fermions. They generate physically relevant sub-ensembles ("scf-ensembles") within a given Altland-Zirnbauer class. We are motivated to investigate such ensembles…

Disordered Systems and Neural Networks · Physics 2020-04-22 Matthias Stosiek , Bruno Lang , Ferdinand Evers

We investigate the time an electronic excitation travels in a supermolecular setup using a measurement process in an open quantum-system framework. The approach is based on the stochastic Schr\"odinger equation and uses a Hamiltonian from…

Materials Science · Physics 2013-12-09 Dirk Hofmann , Heiko Appel , Massimiliano Di Ventra , Stephan Kümmel

We present excited states density functional theory (DFT) to calculate band gap for semiconductors and insulators. For the excited states exchange-correlation functional, we use a simple local density approximation (LDA) like functional and…

We develop a method of computing the excited state energies in Integrable Quantum Field Theories (IQFT) in finite geometry, with spatial coordinate compactified on a circle of circumference R. The IQFT ``commuting transfer-matrices''…

High Energy Physics - Theory · Physics 2011-02-11 V. V. Bazhanov , S. L. Lukyanov , A. B. Zamolodchikov

A systematic diagrammatic expansion for Gutzwiller-wave functions (DE-GWF) proposed very recently is used for the description of superconducting (SC) ground state in the two-dimensional square-lattice $t$-$J$ model with the hopping electron…

Strongly Correlated Electrons · Physics 2014-07-22 J. Kaczmarczyk , J. Bünemann , J. Spałek

We investigate the variation of concurrence in a spin-1/2 transverse field XY chain system in an excited state. Initially, we precisely solve the eigenvalue problem of the system Hamiltonian using the fermionization technique. Subsequently,…

Quantum Physics · Physics 2024-01-29 S. Mahdavifar , Z. Balador , M. R. Soltani

Conformal field theories (CFTs) feature prominently in high-energy physics, statistical mechanics, and condensed matter. For example, CFTs govern emergent universal properties of systems tuned to quantum phase transitions, including their…